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1. 发明申请

WO2018046652A1 MULTIMODAL POLYETHYLENE THIN FILM 审中-公开
标题翻译：多模聚乙烯薄膜
公开(公告)号：WO2018046652A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072567
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： MATTAYAN, Arunsri , TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , KLOMKAMOL, Warachad
IPC分类号： C08F2/00 , B01J19/00 , C08F2/01 , C08F2/12 , C08F2/18 , C08J5/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising; (a) a first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination, thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100 - 200 kPa (abs); (c) the second reactor; and. (d) a third reactor and the use of a film thereof.
摘要翻译：本发明涉及用于多峰聚乙烯聚合方法的反应器系统，其包括：（a）第一反应器; （b）布置在第一反应器与第二反应器之间的除氢单元，所述第二反应器包含至少一个与优选选自真空泵，压缩机，鼓风机，喷射器或其组合的减压设备连接的容器，所述减压设备允许调节工作压力在100-200千帕（绝对压力）的范围内; （c）第二反应器; 和。（d）第三反应器和使用其膜。

2. 发明申请

WO2018046712A1 HIGH PERFORMANCES MULTIMODAL ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE 审中-公开
标题翻译：高性能多模超高分子量聚乙烯
公开(公告)号：WO2018046712A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072685
申请日：2017-09-11
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： JARUMANEEROJ, Chatchai , TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , TIYAPIBOONCHAIYA, Piyawan
IPC分类号： C08F2/00 , B01J19/00 , C08F2/01 , C08F2/12 , C08F2/18 , C08J5/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising; (a) a first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100 - 200 kPa (abs); (c) the second reactor; and (d) a third reactor and use thereof as a sheet.
摘要翻译：本发明涉及用于多峰聚乙烯聚合方法的反应器系统，其包括：（a）第一反应器; （b）布置在第一反应器和第二反应器之间的除氢单元，所述第二反应器包括至少一个与优选地选自真空泵，压缩机，鼓风机，喷射器或其组合的减压设备连接的容器，所述减压设备允许调节操作压力达到100-200kPa（绝对）的压力; （c）第二反应器; 和（d）第三反应器及其用作片材。

3. 发明申请

WO2018046656A1 MULTIMODAL POLYETHYLENE COMPOSITION AND A FILM COMPRISING THE SAME 审中-公开
标题翻译：多模聚乙烯组合物和包含该组合物的膜
公开(公告)号：WO2018046656A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072571
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： MATTAYAN, Arunsri , TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , KLOMKAMOL, Warachad
IPC分类号： C08F2/00 , B01J19/00 , C08F2/01 , C08F2/12 , C08F2/18 , C08J5/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a multimodal polyethylene composition comprising: (A) 40 to 65 parts by weight, preferably 43 to 52 parts by weight, most preferred 44 to 50 parts by weight, of the low molecular weight polyethylene, the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol and having a MFRa from 500 to 1.000 g/10 min according to ASTM D 1238; (B) 8 to 20 parts by weight, preferably 10 to 18 parts by weight, most preferred 10 to 15 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000g/mol; and (C) 30 to 50 parts by weight, preferably 37 to 47 parts by weight, most preferred 39 to 45 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000g/mol, wherein the density of the first high molecular weight polyethylene or the first ultra high molecular weight polyethylene and the second high molecular weight polyethylene or the second ultra high molecular weight polyethylene are in the range from 0.920 to 0.950 g/cm3, and wherein the molecular weight distribution of the multimodal polyethylene composition is from 20 to 28, preferably from 24 to 28, measured by gel permeation chromatography, and a film comprising the multimodal plolyethylene composition and the use thereof.
摘要翻译：本发明涉及一种多峰态聚乙烯组合物，其包含：（A）40至65重量份，优选43至52重量份，最优选44至50重量份的低分子量重均聚乙烯，重均分子量（Mw）为20,000至90,000g / mol且根据ASTM D 1238具有500至1.000g / 10min的MFRa的低分子量聚乙烯; （B）重均分子量（Mw）超过150,000〜1,000,000g的第1高分子量聚乙烯8〜20重量份，优选10〜18重量份，最优选10〜15重量份 / mol或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第一超高分子量聚乙烯; 和（C）30-50重量份，优选37-47重量份，最优选39-45重量份的重均分子量（Mw）大于150,000-1,000,000的第二高分子量聚乙烯 g或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第二超高分子量聚乙烯，其中第一高分子量聚乙烯或第一超高分子量聚乙烯和第二高分子量聚乙烯或第二超高分子量聚乙烯在0.920至0.950g / cm 3的范围内，并且其中多峰聚乙烯组合物的分子量分布为20至28，优选24至28，其通过凝胶渗透色谱法和包含多峰态聚乙烯组合物的薄膜及其用途。

4. 发明申请

WO2020064380A1 POLYOLEFIN RESIN BLENDS FOR HIGH STRESS CRACKING RESISTANCE AND GOOD PROCESSABILITY 审中-公开
公开(公告)号：WO2020064380A1
公开(公告)日：2020-04-02
申请号：PCT/EP2019/074614
申请日：2019-09-16
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： TRAISILANUN, Saranya , NANTASETPHONG, Wiroj , CHEEVASRIRUNGRUANG, Watcharee
IPC分类号： C08L23/06 , C08L23/08
摘要： Polyethylene composition comprising a melt blend, the melt blend comprising: a) a first multimodal polyethylene, the first multimodal polyethylene having a medium weight average molecular weight of a high weight average molecular weight, a density of more than 0,950 to 0,965 g/cm 3 according to ISO 1183 and a MFR 2 of 0.3 to 2,0 g/10 min according to ISO 1133; and b) a second multimodal polyethylene, the second multimodal polyethylene having a high weight average molecular weight, a density of 0.940 to 0.950 g/cm 3 according to ISO 1183 and a MFR 2 of 0.03 to 0.15 g/10 min according to ISO 1133; wherein the polymer composition has a Full Notch Creep Test (FNCT) according to ISO 16770 of at least 58 hours and a Charpy impact strength at a temperature of 23°C of at least 4 kJ/m 2 according to ISO 179.

5. 发明申请

WO2018046713A1 HIGH PERFORMANCES MULTIMODAL ULTRA HIGH MOLECULAR WEIGHT POLYETHYLENE 审中-公开
标题翻译：高性能多模超高分子量聚乙烯
公开(公告)号：WO2018046713A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072686
申请日：2017-09-11
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： JARUMANEEROJ, Chatchai , TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , TIYAPIBOONCHAIYA, Piyawan
IPC分类号： C08J5/18 , C08L23/04 , C08L23/06
摘要： The present inventions relates to a multimodal polyethylene composition comprising; (A) 30 to 65 parts by weight, preferably 30 to 50 parts by weight, most preferred 30 to 40 parts by weight of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol or medium molecular weight polyethylene having a weight average molecular weight (Mw) of more than 90,000 to 150,000 g/mol; (B) 5 to 40 parts by weight, preferably 10 to 35 parts by weight, most preferred 15 to 35 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000 g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol; and (C) 10 to 60 parts by weight, preferably 15 to 60 parts by weight, most preferred 20 to 60 parts by weight of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000 g/mol, wherein a MI 21 of the multimodal polyethylene composition is less than 2.0 g/10 min, and a Charpy impact strength at 23 °C the of multimodal polyethylene composition is at least 70 kJ/m 2 , preferably 70 to 120 kJ/m 2 , measured by ISO 179, a sheet comprising the multimodal polyethylene composition as well as the use of the sheet.
摘要翻译：本发明涉及一种多峰态聚乙烯组合物，其包含：（A）30至65重量份，优选30至50重量份，最优选30至40重量份的重均分子量（Mw）为20,000至90,000g / mol的低分子量聚乙烯或介质重均分子量（Mw）大于90,000至150,000g / mol的低分子量聚乙烯; （B）重均分子量（Mw）超过150,000〜1,000,000g的第一高分子量聚乙烯5〜40重量份，优选10〜35重量份，最优选15〜35重量份 / mol或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第一超高分子量聚乙烯; 和（C）重均分子量（Mw）超过150,000至1,000,000g的第二高分子量聚乙烯10至60重量份，优选15至60重量份，最优选20至60重量份 / mol的第一超高分子量聚乙烯或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第二超高分子量聚乙烯，其中多峰聚乙烯组合物的MI 21小于2.0g / 10分钟，多峰态聚乙烯组合物在23℃下的却贝冲击强度为至少70kJ / m 2，优选70至120kJ / m 2，，由ISO 179测量，包含多峰态聚乙烯组合物的片材以及该片材的用途。

6. 发明申请

WO2018046665A1 MULTIMODAL POLYETHYLENE SCREW CAP 审中-公开
标题翻译：多式聚乙烯螺丝帽
公开(公告)号：WO2018046665A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072588
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , KLOMKAMOL, Warachad
IPC分类号： C08F2/00 , B01J19/00 , B65D41/04 , C08F2/01 , C08F2/12 , C08F2/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a reactor system for a multimodal polyethylene composition comprising; (a) first reactor; (b) hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100 — 200 kPa (abs); (c) the second reactor; and (d) a third reactor, a multimodal, polyethylene composition obtainable this way and a screw cap comprising the same.
摘要翻译：本发明涉及用于多峰聚乙烯组合物的反应器系统，其包含：（a）第一反应器; （b）布置在第一反应器和第二反应器之间的除氢单元，其包括至少一个与优选选自真空泵，压缩机，鼓风机，喷射器或其组合的减压设备连接的容器，所述减压设备允许调节操作压力升至100-200千帕（绝对压力）范围内的压力; （c）第二反应器; 和（d）第三反应器，可通过这种方式获得的多峰聚乙烯组合物和包含其的螺帽。

7. 发明申请

WO2018046664A1 MULTIMODAL POLYETHYLENE FILM 审中-公开
标题翻译：多模聚乙烯薄膜
公开(公告)号：WO2018046664A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072587
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： MATTAYAN, Arunsri , CHEEVASRIRUNGRUANG, Watcharee , TRAISILANUN, Saranya , KLOMKAMOL, Warachad
IPC分类号： C08J5/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a multimodal polyethylene composition comprising: (A) 40 to 65 parts by weight, preferably 43 to 52 parts by weight, most preferred 44 to 50 parts by' weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol, wherein the low molecular weight polyethylene has a MI2 of 500 to 1,000 g/10 min according to ASTM D 1238; (B) 5 to 17 parts by weight, preferably 10 to 17 parts by weight, most preferred 10 to 15 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000g/mol; and (C) 30 to 50 parts by weight, preferably 37 to 47 party by weight, most preferably 39 to 45 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000g/mol, wherein the density of the first high molecular weight polyethylene or the first ultra high molecular weight polyethylene and the second high molecular weight polyethylene or the second ultra high molecular weight polyethylene is in the same range and both densities are in the range from 0.910 to 0.940 g/cm3; and the molecular weight distribution of the multimodal polyethylene composition is from 18 to 30, preferably 20 to 28, measured by gel permeation chromatography., film comprising the multimodal plolyethylene composition and the use thereof.
摘要翻译：本发明涉及一种多峰态聚乙烯组合物，其包含：（A）40-65重量份，优选43-52重量份，最优选44-50重量份的低所述低分子量聚乙烯具有20,000至90,000g / mol的重均分子量（Mw），其中根据ASTM D 1238，所述低分子量聚乙烯具有500至1,000g / 10min的MI 2; （B）重均分子量（Mw）超过150,000〜1,000,000g的第1高分子量聚乙烯5〜17重量份，优选10〜17重量份，最优选10〜15重量份 / mol或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第一超高分子量聚乙烯; 和（C）30-50重量份，优选37-47重量份，最优选39-45重量份的重均分子量（Mw）大于150,000-1,000,000的第二高分子量聚乙烯 g或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第二超高分子量聚乙烯，其中第一高分子量聚乙烯或第一超高分子量聚乙烯和第二高分子量聚乙烯或第二超高分子量聚乙烯在相同的范围内并且两种密度在0.910至0.940g / cm 3的范围内; 并且通过凝胶渗透色谱法测量，多峰态聚乙烯组合物的分子量分布为18至30，优选20至28，包含多峰态聚乙烯组合物的薄膜及其用途。

8. 发明申请

WO2018046667A1 MULTIMODAL POLYETHYLENE SCREW CAP 审中-公开
标题翻译：多式聚乙烯螺丝帽
公开(公告)号：WO2018046667A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072593
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , KLOMKAMOL, Warachad
IPC分类号： C08F2/00 , B01J19/00 , B65D41/04 , C08F2/01 , C08F2/12 , C08F2/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a multimodal polyethylene composition comprising: (A)35 to 65 parts by weight, preferably 45 to 65 parts by weight, most preferred 50 to 60 parts by weight, of the low molecular weight polyethylene having a weight average molecular weight (Mw) of 20,000 to 90,000 g/mol; (B) 5 to 40 parts by weight, preferably 5 to 30 parts by weight, most preferred 5 to 20 parts by weight, of the first high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to 1,000,000g/mol or the first ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000g/mol; and (C) 20 to 60 parts by weight, preferably 25 to 60 parts by weight, most preferred 35 to 55 parts by weight, of the second high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 150,000 to l,000,000g/mol or the second ultra high molecular weight polyethylene having a weight average molecular weight (Mw) of more than 1,000,000 to 5,000,000g/mol, wherein the molecular weight distribution of the multimodal polyethylene composition is from 10 to 25, preferably 10 to 20, determined by Gel Permeation Chromatography; the isothermal crystallization half-time of the multimodal polyethylene composition at a temperature of 123°C is 7 min or less, preferably 6 min or less, preferably 2- 6 min, according to Differential Scanning Calorimetry; and a spiral flow length at a temperature of 220°C is at least 200 mm, preferably 250-400 mm and a screw cap comprising the same.
摘要翻译：本发明涉及一种多峰态聚乙烯组合物，其包含：（A）35至65重量份，优选45至65重量份，最优选50至60重量份的低分子量具有20,000至90,000g / mol的重均分子量（Mw）的重量聚乙烯; （B）重均分子量（Mw）超过150,000〜1,000,000g的第一高分子量聚乙烯5〜40重量份，优选5〜30重量份，最优选5〜20重量份 / mol或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第一超高分子量聚乙烯; 和（C）20-60重量份，优选25-60重量份，最优选35-55重量份的重均分子量（Mw）大于150,000-1的第二高分子量聚乙烯，或重均分子量（Mw）大于1,000,000至5,000,000g / mol的第二超高分子量聚乙烯，其中所述多峰聚乙烯组合物的分子量分布为10至25，优选10至100,000g / mol。通过凝胶渗透色谱法测定为20; 根据差示扫描量热法，在123℃的温度下多峰态聚乙烯组合物的等温结晶半衰期为7分钟或更少，优选6分钟或更少，优选2-6分钟; 并且在220℃的温度下的螺旋流动长度至少为200mm，优选为250-400mm，并且螺旋帽包含该螺旋帽。

9. 发明申请

WO2018046663A1 MULTIMODAL POLYETHYLENE FILM 审中-公开
标题翻译：多模聚乙烯薄膜
公开(公告)号：WO2018046663A1
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072586
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： MATTAYAN, Arunsri , CHEEVASRIRUNGRUANG, Watcharee , TRAISILANUN, Saranya , KLOMKAMOL, Warachad
IPC分类号： C08F2/00 , B01J19/00 , C08F2/01 , C08F2/12 , C08F2/18 , C08J5/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising; (a) a first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure ie a range of 100 - 200 kPa (abs); (c) the second reactor; and (d) a third reactor and the use of a film thereof.
摘要翻译：本发明涉及用于多峰聚乙烯聚合方法的反应器系统，其包括：（a）第一反应器; （b）布置在第一反应器和第二反应器之间的除氢单元，所述第二反应器包括至少一个与优选地选自真空泵，压缩机，鼓风机，喷射器或其组合的减压设备连接的容器，所述减压设备允许调节操作压力至100-200kPa（绝对）的压力; （c）第二反应器; 和（d）第三反应器及其膜的用途。

10. 发明申请

WO2018046652A9 MULTIMODAL POLYETHYLENE THIN FILM 审中-公开
公开(公告)号：WO2018046652A9
公开(公告)日：2018-03-15
申请号：PCT/EP2017/072567
申请日：2017-09-08
申请人： THAI POLYETHYLENE CO., LTD. , SCG CHEMICALS CO., LTD.
发明人： MATTAYAN, Arunsri , TRAISILANUN, Saranya , CHEEVASRIRUNGRUANG, Watcharee , KLOMKAMOL, Warachad
IPC分类号： C08F2/00 , B01J19/00 , C08F2/01 , C08F2/12 , C08F2/18 , C08J5/18 , C08L23/04 , C08L23/06
摘要： The present invention relates to a reactor system for a multimodal polyethylene polymerization process, comprising; (a) a first reactor; (b) a hydrogen removal unit arranged between the first reactor and a second reactor comprising at least one vessel connected with a depressurization equipment, preferably selected from vacuum pump, compressor, blower, ejector or a combination, thereof, the depressurization equipment allowing to adjust an operating pressure to a pressure in a range of 100 - 200 kPa (abs); (c) the second reactor; and. (d) a third reactor and the use of a film thereof.

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