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    • 4. 发明申请
    • TEXTILES CONTAINING AT LEAST ONE LAYER OF POLYMERIC NANOFIBRES AND METHOD OF PRODUCTION OF THE LAYER OF POLYMERIC NANOFIBRES FROM THE POLYMER SOLUTION THROUGH ELECTROSTATIC SPINNING
    • 含有至少一层聚合物纳米纤维的纺织品和通过静电纺丝从聚合物溶液中制备聚合物纳米薄膜的方法
    • WO2006108364A1
    • 2006-10-19
    • PCT/CZ2006/000018
    • 2006-04-10
    • ELMARCO, S.R.OJIRSAK, OldrichSANETRNIK, FilipMARES, LadislavPETRAS, David
    • JIRSAK, OldrichSANETRNIK, FilipMARES, LadislavPETRAS, David
    • D01D5/00D01F1/10
    • D01D5/0038D01F1/103Y10T442/607Y10T442/614Y10T442/658
    • The invention relates to the textile containing at least one layer of polymeric nanofibres having diameter to 600 nanometres produced through electrostatic spinning of the polymer solution. The polymeric nanofibres contain particles of low-molecular substance dissolved or dispersed in solution of polymer which is subject to electrostatic spinning, possibly particles of low molecular substance which was created through a consequent chemical reaction of the original low molecular substance dissolved or dispersed in solution subjected to electrostatic spinning. The invention also relates to the production method of the layer of nanofibres from the polymer solution through electrostatic spinning in electric field created by difference of potentials between the charged electrode and the counterelectrode, at which the solution of polymer is brought into the electric field for spinning through the surface of the rotating charged electrode, at the same time the nanofibres created in this electric field are carried to the counterelectrode and they deposit on the surface designated to it. Polymer solution for spinning contains the particles of low-molecular substance, which are at spinning seized together with polymer into the nanofibres being created.
    • 本发明涉及包含通过聚合物溶液的静电纺丝产生的直径至600纳米的至少一层聚合物纳米纤维的织物。 聚合物纳米纤维含有溶解或分散在受静电纺丝的聚合物溶液中的低分子物质颗粒,可能是通过溶解或分散在溶液中的原始低分子物质的化学反应而产生的低分子量的颗粒 静电纺丝。 本发明还涉及由聚合物溶液通过静电纺丝在电场中产生的纳米纤维的制造方法,所述电场由带电电极和反电极之间的电位差产生,其中聚合物溶液进入用于纺丝的电场 通过旋转充电电极的表面,同时在该电场中产生的纳米纤维被传送到反电极,并且它们沉积在指定的电表面上。 用于纺丝的聚合物溶液含有低分子物质的颗粒,它们与聚合物一起旋转到被形成的纳米纤维中。
    • 9. 发明申请
    • A METHOD AND DEVICE FOR PRODUCTION OF NANOFIBRES FROM THE POLYMERIC SOLUTION THROUGH ELECTROSTATIC SPINNING
    • 通过静电纺丝从聚合物溶液中生产纳米纤维的方法和装置
    • WO2006131081A1
    • 2006-12-14
    • PCT/CZ2006/000037
    • 2006-06-01
    • ELMARCO, s.r.o.PETRÁS, DavidMARES, LadislavSTRÁNSKÁ, Denisa
    • PETRÁS, DavidMARES, LadislavSTRÁNSKÁ, Denisa
    • D01D5/00
    • D01D5/0069
    • Production method of nanofibres from the polymeric solution through electrostatic spinning in electric field created by a difference of potentials between the collecting electrode (4) and pivoted spinning electrode (1) of an oblong shape touching by a part of its circuit the polymeric solution (3), while by rotation of the spinning electrode (1) the polymeric solution (3), at least by a portion of its surface, is carried out into the electric field in which on the surface of the collecting electrode (4) the nanofibres are created which are carried to the collecting electrode (4) and deposited on the surface of a basic material (5) guided between the spinning electrode (1) and the collecting electrode (4) in vicinity of the collecting electrode (4). The polymeric solution (3), on surface of the spinning electrode (1) in a place of intersection of surface of the spinning electrode (1) with the plane interlaid by the axis of the spinning electrode (1) and being perpendicular to the plane of the base material (5), along the whole length of the spinning electrode (1), is subject to the electric field of a maximum and equal intensity, through which a high and even spinning effect is achieved along the whole length of the spinning electrode (1). The invention also relates to the device for production of nanofibres from polymeric solution through electrostatic spinning.
    • 由聚合物溶液通过电场中的静电纺丝制成的纳米纤维的制造方法是由收集电极(4)和长丝形的旋转纺丝电极(1)之间的电位差与电极的一部分接触的聚合物溶液(3 ),而通过旋转电极(1)的旋转,聚合物溶液(3)至少在其表面的一部分被进行到其中纳米纤维在集电电极(4)的表面上的电场 产生的,被送到集电电极(4)上并沉积在引导在收集电极(4)附近的纺丝电极(1)和集电电极(4)之间的基材(5)的表面上。 聚合物溶液(3)在纺丝电极(1)的表面上,在纺丝电极(1)的表面与由纺丝电极(1)的轴线相交并垂直于平面 沿着纺丝电极(1)的整个长度的基材(5)的长度受到最大等强度的电场,通过该电场沿着纺丝的整个长度实现高均匀的纺丝效果 电极(1)。 本发明还涉及通过静电纺丝从聚合物溶液制备纳米纤维的装置。
    • 10. 发明申请
    • METHOD AND DEVICE FOR PRODUCTION OF A LAYER OF NANOPARTICLES OR A LAYER OF NANOFIBRES FROM SOLUTIONS OR MELTS OF POLYMERS
    • 用于生产纳米颗粒层或由聚合物溶液或熔融物形成的纳米层的方法和装置
    • WO2008098526A2
    • 2008-08-21
    • PCT/CZ2008/000015
    • 2008-01-30
    • ELMARCO S.R.O.MALY, MiroslavPETRAS, DavidMARES, Ladislav
    • MALY, MiroslavPETRAS, DavidMARES, Ladislav
    • D01D5/00B05D1/04
    • D01D5/0076B05D1/007B05D1/28B05D3/142B05D2401/32
    • Method for production of deposit or layer of nanoparticles or a layer of nanofibres from solutions or melts of polymers in electrostatic field of a high intensity, during which the produced nanoparticles or the produced nanofibres deposit on a substrate material (3) passing through the active chamber (1), in which is positioned the active electrode (2). The electrostatic field for production, transfer and depositing of nanoparticles or production, transfer and depositing of nanofibres is induced between the active electrode (2) and the substrate material (3), on which in the direction of its movement in front of and/or opposite to the active electrode (2) there is applied an electric charge of opposite polarity than that of the active electrode (2), while an electric charge applied on the substrate material (3) is being partially or totally consumed through depositing of nanoparticles or nanofibres on the moving substrate material (3). In the production device there are one opposite to another positioned the active electrode (2) connected to a high voltage source and the substrate material (3) coupled with means for initiating its forward motion. The substrate material (3) is positioned in the active chamber (1) without contact with any charged and/or grounded means while it contains quantity of electrical charge sufficient to induce electrostatic field of a high intensity between the active electrode (2) and substrate material (3).
    • 用于在高强度静电场中由聚合物溶液或熔体制备纳米颗粒或纳米纤维层的方法,其中所制备的纳米颗粒或所制备的纳米纤维沉积在穿过活性室的基底材料(3)上, (1),其中定位有源电极(2)。 在有源电极(2)和衬底材料(3)之间诱导纳米颗粒的生产,转移和沉积或纳米纤维的生产,转移和沉积的静电场,其在其前方的运动方向和/或 与有源电极(2)相对,施加与有源电极(2)相反极性的电荷,而施加在衬底材料(3)上的电荷通过沉积纳米颗粒而被部分或全部消耗 在移动的基底材料(3)上的纳米纤维。 在制造装置中,与另一个相反的方法是将有源电极(2)连接到高电压源,而衬底材料(3)与用于启动其向前运动的装置相连。 衬底材料(3)位于活性室(1)中,而不与任何带电和/或接地装置接触,同时其含有足以在有源电极(2)和衬底之间引起高强度静电场的电荷量 材料(3)。