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    • 4. 发明申请
    • METHODS OF PEST CONTROL IN SOYBEAN
    • 大豆病虫害防治方法
    • WO2014019950A1
    • 2014-02-06
    • PCT/EP2013/065785
    • 2013-07-26
    • SYNGENTA PARTICIPATIONS AG
    • EL QACEMI, MyriemCASSAYRE, Jérôme, Yves
    • A01N43/80A01P7/00
    • A01N43/80G06Q30/018
    • The present invention relates to methods, preferably for controlling and/or preventing infestation of stinkbugs in soybean,comprising applying to a crop of soybean plants, the locus thereof, or propagation material thereof, a compound of formula (I) wherein -B 1 -B 2 -B 3 -is -C=N-O-, -C=N-CH 2 -, -C=CH 2 -O-or -N-CH 2 -CH 2 -; L is a direct bond or methylene; A 1 and A 2 are C-H, or one of A 1 and A 2 is C-H and the other is N; X 1 is group X R 1 is C 1 -C 4 alkyl, C 1 -C 4 haloalkyl or C 3 -C 6 cycloalkyl; R 2 is chlorodifluoromethyl or trifluoromethyl; each R 3 is independently bromo, chloro, fluoro or trifluoromethyl; R 4 is hydrogen, halogen, methyl, halomethyl or cyano; R 5 is hydrogen; or R 4 and R 5 together form a bridging 1,3-butadiene group; p is 2 or 3.
    • 本发明涉及优选用于控制和/或预防大豆中臭虫的侵染的方法,其包括向大豆植物作物的基因座或其繁殖材料施用式(I)化合物,其中-B1-B2 -B3-是-C = NO-,-C = N-CH2-,-C = CH2-O-或-N-CH2-CH2-; L是直接键或亚甲基; A1和A2是C-H,A1和A2之一是C-H,另一个是N; X1是基团XR1是C1-C4烷基,C1-C4卤代烷基或C3-C6环烷基; R2是氯二氟甲基或三氟甲基; 每个R 3独立地是溴,氯,氟或三氟甲基; R4是氢,卤素,甲基,卤代甲基或氰基; R5是氢; 或R4和R5一起形成桥连1,3-丁二烯基团; p是2或3。
    • 5. 发明申请
    • ISOXAZOLINE DERIVATIVES AS INSECTICIDAL COMPOUNDS
    • 异辛唑衍生物作为杀虫剂化合物
    • WO2013050302A1
    • 2013-04-11
    • PCT/EP2012/069173
    • 2012-09-28
    • SYNGENTA PARTICIPATIONS AGEL QACEMI, MyriemCASSAYRE, Jérôme, Yves
    • EL QACEMI, MyriemCASSAYRE, Jérôme, Yves
    • C07D261/04C07D413/14A01N43/80
    • A01N43/80C07D261/04C07D413/14A01N2300/00
    • The present invention provides compounds of formula I wherein G 1 is oxygen; R 1 is hydrogen; R 2 is group P L is a bond, methylene or ethylene; R 3 is hydrogen; R 4 is independently hydrogen, cyano, cyano-C 1 -C 8 alkyl, C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 3 -C 8 cycloalkyl, C 3 -C 8 cycloalkyl where one carbon atom is replaced by O, S, S(O) or SO 2 , or C 3 - Cgcycloalkyl-C 1 -C 8 alkyl, C 3 -C 8 cycloalkyl-C 1 -C 8 alkyl where one carbon atom in the cycloalkyl group is replaced by O, S, S(O) or SO 2 , or C 3 -C 8 cycloalkyl-C 1 -C 8 haloalkyl, C 1 -C 8 hydroxyalkyl, C 1 -C 8 alkoxy-C 1 -C 8 alkyl, C 2 -C 8 alkenyl, C 2 -C 8 haloalkenyl, C 2 -C 8 alkynyl, C 2 -C 8 haloalkynyl, phenyl, phenyl substituted by one to three R 6 , phenyl-C 1 -C 4 alkyl, phenyl-C 1 -C 4 alkyl wherein the phenyl moiety is substituted by one to three R 6 , 5-6 membered heteroaryl-C 1 -C 4 alkyl or 5-6 membered heteroaryl-C 1 -C 4 alkyl wherein the heteroaryl moiety is substituted by one to three R6, or C 1 -C 4 alkyl-(C 1 -C 4 alkyl-O-N=)C-CH 2 -; each R 6 is independently halogen, cyano, nitro, C 1 -C 8 alkyl, C 1 -C 8 haloalkyl, C 1 -C 8 alkoxy, or C 1 - C 8 haloalkoxy; Y 1 , Y 2 and Y 3 are independently CH or nitrogen; wherein no more than two of Y 1 , Y 2 and Y 3 are nitrogen and wherein Y 2 and Y 3 are not both nitrogen; R 5 is hydrogen, halogen, cyano, nitro, NH 2 , C 1 -C 2 alkyl, C 1 -C 2 haloalkyl, C 3 -C 5 cycloalkyl, C 1 - C 2 halocycloalkyl, C 1 -C 2 alkoxy, C 1 -C 2 haloalkoxy; or Y 1 is CR 7 , and R 5 and R 7 together form a - CH=CH-CH=CH- bridge or a -N=CH-CH=CH- bridge; X 2 is C-X 6 or nitrogen; X 1 ,X 3 and X 6 are independently hydrogen, halogen or trihalomethyl, wherein at least two of X 1 , X 3 and X 6 are not hydrogen; X 4 is trifluoromethyl, difhioromethyl or chlorodifluoromethyl. or a salt or N-oxide thereof. The invention also provides intermediates useful for the preparation of compounds of formula I, as well as methods of controlling insects, acarines, nematodes or molluscs using the compounds of formula I.
    • 本发明提供其中G1是氧的式I化合物; R1是氢; R2是基团P L是键,亚甲基或亚乙基; R3是氢; R 4独立地是氢,氰基,氰基-C 1 -C 8烷基,C 1 -C 8烷基,C 1 -C 8卤代烷基,C 3 -C 8环烷基,C 3 -C 8环烷基,其中一个碳原子被O,S,S(O)或SO 2或C 3 -C 8环烷基 C 1 -C 8烷基,C 3 -C 8环烷基-C 1 -C 8烷基,其中环烷基中的一个碳原子被O,S,S(O)或SO 2,或C 3 -C 8环烷基-C 1 -C 8卤代烷基,C 1 -C 8羟烷基,C 1 -C 8烷氧基 C 1 -C 8烷基,C 2 -C 8烯基,C 2 -C 8卤代烯基,C 2 -C 8炔基,C 2 -C 8卤代炔基,苯基,被1至3个R 6取代的苯基,苯基-C 1 -C 4烷基,苯基-C 1 -C 4烷基,其中苯基部分被一个 至三个R 6,5-6元杂芳基-C 1 -C 4烷基或5-6元杂芳基-C 1 -C 4烷基,其中杂芳基部分被一至三个R 6取代,或C 1 -C 4烷基 - (C 1 -C 4烷基-ON =)C- CH2-; 每个R 6独立地是卤素,氰基,硝基,C 1 -C 8烷基,C 1 -C 8卤代烷基,C 1 -C 8烷氧基或C 1 -C 8卤代烷氧基; Y1,Y2和Y3独立地为CH或氮; 其中Y1,Y2和Y3中不超过两个是氮,并且其中Y2和Y3不都是氮; R5是氢,卤素,氰基,硝基,NH2,C1-C2烷基,C1-C2卤代烷基,C3-C5环烷基,C1-2卤代环烷基,C1-C2烷氧基,C1-C2卤代烷氧基; 或Y1是CR7,R5和R7一起形成-CH = CH-CH = CH-桥或-N = CH-CH = CH-桥; X2是C-X6或氮; X1,X3和X6独立地为氢,卤素或三卤代甲基,其中X 1,X 3和X 6中的至少两个不是氢; X4是三氟甲基,二低甲基或氯二氟甲基。 或其盐或N-氧化物。 本发明还提供了可用于制备式I化合物的中间体,以及使用式I化合物控制昆虫,螨虫,线虫或软体动物的方法。