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    • 3. 发明申请
    • NITROGEN-CONTAINING HARD SINTERED ALLOY
    • 含氮硬质合金
    • WO1994018351A1
    • 1994-08-18
    • PCT/JP1994000158
    • 1994-02-03
    • SUMITOMO ELECTRIC INDUSTRIES, LTD.ISOBE, KazutakaTSUDA, KeiichiKITAGAWA, NobuyukiNOMURA, Toshio
    • SUMITOMO ELECTRIC INDUSTRIES, LTD.
    • C22C29/02
    • C22C29/02B22F2998/00C22C29/04B22F2207/01B22F2207/03
    • A nitrogen-containing hard sintered alloy having high thermal impact resistance, abrasion resistance and tenacity and suitably used as a material for cutting tools. This alloy is formed so that it consists of a hard phase composed of a carbide of at least two kinds of transition metals selected from the 4a, 5a and 6a groups on the periodic table, and a combined phase of Ni and Co, in which a maximum combined metal phase quantity portion exists in a range of depth from an outer surface of not less than 3 mu m and not more than 500 mu m. Regarding the hard phase, in which TixWyMc represents the metal composition forming the same phase, x &cir& _ of a surface portion is not less than 1.01 times as large as an average value x &cir& _ of those of the alloy, y &cir& _ of the same portion being not less than 0.1 and not more than 0.9 times as large as an average value y &cir& _ of those of the alloy, x &cir& _ and y &cir& _ of the hard phase returning to average values x &cir& _ and y &cir& _ of those of the alloy as a whole before a depth of 800 mu m is reached, the surface portion not containing WC particles at all, or containing, if any, not more than 0.1 volume % of WC particles, compressive residual stress of not lower than 40 kg/mm being applied to the portion of an NaCl type hard phase which is in the vicinity of an outer surface thereof.
    • 具有高耐热冲击性,耐磨性和强度的含氮硬质烧结合金,适用于切削工具的材料。 该合金形成为由包含选自元素周期表中的4a,5a和6a族中的至少两种过渡金属的碳化物构成的硬质相和Ni和Co的组合相,其中, 最大组合金属相量部分存在于从不小于3μm至不小于500μm的外表面的深度范围内。 关于硬质相,其中TixWyMc表示形成相同相的金属组成,表面部分的x'和x'不小于合金的平均值x&cir的>的1.01倍 相同部分不低于合金的平均值y&cir的0.1并且不大于0.9倍,硬相的x&cir和_和y&cir&_返回平均值x&cir&_和y&cir& 在达到800μm深度之前的合金整体上,完全不含有WC颗粒的表面部分,或者含有不大于0.1体积%的WC颗粒,压缩残余应力不低于 比其外表面附近的NaCl型硬质相的部分施加40kg / mm 2以上。
    • 8. 发明申请
    • COATED CUTTING TOOL AND METHOD FOR PRODUCING THE SAME
    • 涂层切割工具及其制造方法
    • WO1994028191A1
    • 1994-12-08
    • PCT/JP1994000882
    • 1994-05-31
    • SUMITOMO ELECTRIC INDUSTRIES, LTD.UCHINO, KatsuyaNOMURA, ToshioOHARA, HisanoriCHUDO, MasuoKOBAYASHI, Mitsunori
    • SUMITOMO ELECTRIC INDUSTRIES, LTD.
    • C23C16/30
    • C23C16/34C23C16/32C23C16/36C23C30/005Y10T428/12049Y10T428/12576
    • A coated cutting tool suitable for high speed cutting process and a method for producing the same, the tool comprising a base material formed of tungsten-carbide-based cemented carbide and a coating layer on the base material comprising in turn an internal layer and an external layer, wherein the internal layer consists of a single layer of titanium carbonitride in contact with the base material, a double layer consisting of a 0.1 to 2 mu m thick titanium nitride layer in contact with the base material and a titanium carbonitride layer directly thereon, and a multi-layer prepared by applying another coating of titanium carbide to the titanium carbonitride layer, the tool being characterized in that the chlorine content of the internal layer is 0.05 atomic % or less on average, the peak strength ratio of a specific plane falls within a specific range when the titanium carbonitride is X-ray diffracted, or the internal layer constituting the coating layer consists of a first layer of titanium nitride that contacts the base material and a second layer, placed on the first one, has a hardness ranging from 1600 to 2400 kg/mm . The realized coating has high wear-resistance, and the coating film and the base material are strongly bonded to each other, thereby providing superior peeling resistance during cutting.
    • 一种适用于高速切削加工的涂层切削工具及其制造方法,该工具包括由碳化钨基硬质合金形成的基体材料和基材上的涂层,该涂层依次包括内层和外层 层,其中所述内层由与所述基材接触的单层碳氮化钛组成,由与所述基材接触的0.1至2μm厚的氮化钛层和直接在其上的碳氮化钛层组成的双层, 以及通过将另一碳化钛涂层应用于碳氮化钛层而制备的多层,其特征在于,内层的氯含量平均为0.05原子%以下,特定面的峰值强度比下降 在碳氮化钛为X射线衍射的特定范围内,或构成被覆层的内层由第一层钛 与基材接触的氮化铟和置于第一层上的第二层具有1600至2400kg / mm 2的硬度。 实现的涂层具有高耐磨性,并且涂膜和基材彼此牢固地结合,从而在切割期间提供优异的抗剥离性。