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    • 7. 发明申请
    • ARYLALKYLSULFONIC ACIDS AND METHODS FOR PRODUCING SAME
    • ARYLALKYLSULFONIC酸及其生产方法
    • WO2003014070A1
    • 2003-02-20
    • PCT/US2002/024562
    • 2002-08-02
    • STEPAN COMPANYDADO, Gregory, P.BERNHARDT, Randal, H.
    • DADO, Gregory, P.BERNHARDT, Randal, H.
    • C07C309/01
    • C11D1/22C07C303/22C07C309/24
    • This invention relates new and improved processes for the preparation of arylalkylsulfonic acids derived from aromatic or substituted aromatic molecules and AOS acid (generally a mixture of alkenesulfonic acid and sultones, produced from the sulfonation of alpha olefins) and to cleaning compositions comprising said arylalkylsulfonic acids. The invention involves the use of a superacid catalyst to effectuate the conversion of AOS acid and aromatic reactants to arylalkylsulfonic acid under substantially anhydrous conditions, whereby a substantial improvement in the rate of conversion of the reactants to arylalkylsulfonic acid and/or improvement in mono-alkylation selectivity is realized, as compared to methods of preparation previously disclosed. Also useful as an alkylation promoter is the arylalkylsulfonic acid reaction product itself, produced in situ or from a previous reaction (i.e., a self-catalyst heel). The new processes generally afford arylalkylsulfonic acids with substantially improved conversion yields, highly desirable lighter color, and reduced odor, as compared to previously known methods. The acids produced by the inventive process may be neutralized to form arylalkylsulfonates (i.e., a neutralized form of the acid) which are useful in a variety of end use applications as surfactants and/or emulsifiers.
    • 本发明涉及制备衍生自芳族或取代的芳族分子和AOS酸(通常是由α-烯烃的磺化产生的烯烃磺酸和磺内酯的混合物)的芳基烷基磺酸的新方法和改进方法以及包含所述芳基烷基磺酸的清洗组合物。 本发明涉及使用超强酸催化剂来实现在基本无水条件下将AOS酸和芳族反应物转化为芳基烷基磺酸,从而使反应物转化为芳基烷基磺酸和/或单烷基化改进的实质性改善 与以前公开的制备方法相比,实现了选择性。 也可用作烷基化促进剂的是芳基烷基磺酸反应产物本身,其原位产生或由先前的反应(即,自催化剂尾料)产生。 与先前已知的方法相比,新方法通常提供芳基烷基磺酸,具有显着提高的转化率,高度理想的较浅的颜色和降低的气味。 本发明方法生产的酸可以被中和以形成芳基烷基磺酸盐(即中和形式的酸),其可用作多种最终用途的表面活性剂和/或乳化剂。
    • 9. 发明申请
    • STEAM FOAM METHODS FOR STEAM-ASSISTED GRAVITY DRAINAGE
    • 用于蒸汽辅助排放的蒸汽泡沫方法
    • WO2016028464A1
    • 2016-02-25
    • PCT/US2015/043051
    • 2015-07-31
    • STEPAN COMPANY
    • SANDERS, AaronDADO, Gregory, P.HOLLAND, BrianDONG, Xue, MinROJAS, E., Carolina
    • E21B43/24
    • E21B43/2408
    • Methods for making efficient use of steam in a steam-assisted gravity drainage (SAGD) process for recovering heavy oils from tar sands and similar petroleum deposits are disclosed. The methods utilize a surfactant to generate steam foam in ways that maximize efficient use of steam. In some aspects, steam foam is used in water layers or gas caps that reside above steam chambers 4 to prevent loss of steam 6 from the steam chamber 4. The predominant use of relatively dry steam in SAGD processes makes it challenging to find ways to introduce surfactants 5 and generate steam foam 8. However, decreasing the mobility of the steam 6 by converting at least some of it to foam 8 allows the wellbore and steam chambers 4 above the injection site to be more fully developed, provides for more effective heat transfer to the heavy oil and rock, improves production, and allows recovery of the heavy oil with a minimum amount of steam usage.
    • 公开了在用于从焦油砂和类似的石油沉积物中回收重油的蒸汽辅助重力排水(SAGD)方法中有效利用蒸汽的方法。 该方法利用表面活性剂产生蒸汽泡沫,以最大限度地有效利用蒸汽。 在一些方面,蒸气泡沫被用在位于蒸汽室4上方的水层或气帽中,以防止蒸汽室6蒸汽6的损失。在SAGD工艺中主要使用相对干燥的蒸汽使得探索如何引入 表面活性剂5并产生蒸汽泡沫8.然而,通过将其中的至少一些转化为泡沫8来降低蒸汽6的迁移率,允许更充分地开发注射部位上方的井筒和蒸汽室4,从而提供更有效的热传递 对重油和岩石,改善生产,并允许以最少量的蒸汽使用回收重油。
    • 10. 发明申请
    • PROCESS FOR PREPARING N-ACYL AMINO ACID SALTS
    • 制备N-乙酰氨基酸的方法
    • WO2014008103A1
    • 2014-01-09
    • PCT/US2013/048341
    • 2013-06-27
    • STEPAN COMPANY
    • WANG, BingDADO, Gregory, P.
    • C07C231/02
    • C07C233/91C07C231/02C07C231/10C07C233/47
    • Improved processes for making an N-acyl amino acid salt from a fatty alkyl ester or a polyol ester are disclosed. Each process uses a polyol selected from glycerin or propylene glycol in an amount effective to keep the reaction mixture fluid until conversion to the N-acyl amino acid salt reaches the desired level of completion. In one process, a fatty alkyl ester reacts with an amino acid salt in the presence of glycerin or propylene glycol to produce an N-acyl amino acid salt. In another process, a polyol ester reacts with the amino acid salt in the presence of added glycerin or propylene glycol to produce the N-acyl amino acid salt. We surprisingly found that an effective amount of glycerin or propylene glycol minimizes or eliminates reaction mixture solidification or foaming, reduces color, and minimizes the level of di- and tripeptide by- products. In a related process, water is added when conversion of the amino acid salt to the N-acyl amino acid salt is in the range of 50 to 90 mole %. Water addition improves processability, advances conversion without producing excessive soap, and helps to ensure that the N-acyl amino acid salt will have low color and a small proportion of by-products.
    • 公开了从脂肪烷基酯或多元醇酯制备N-酰基氨基酸盐的改进方法。 每个方法使用选自甘油或丙二醇的多元醇,其量可以有效地保持反应混合物流体,直到转化成N-酰基氨基酸盐达到所需的完成水平。 在一个过程中,脂肪烷基酯在甘油或丙二醇的存在下与氨基酸盐反应以产生N-酰基氨基酸盐。 在另一方法中,多元醇酯在加入的甘油或丙二醇的存在下与氨基酸盐反应以产生N-酰基氨基酸盐。 我们惊奇地发现,有效量的甘油或丙二醇使反应混合物固化或发泡最小化或消除,降低颜色,并使二肽和三肽副产物的水平最小化。 在相关方法中,当氨基酸盐转化为N-酰基氨基酸盐时,加入水是在50至90摩尔%的范围内。 添加水可改善加工性能,不会产生过量的肥皂进行转化,有助于确保N-酰基氨基酸盐具有低颜色和少量的副产物。