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    • 2. 发明申请
    • PERFLUOROELASTOMER COMPOSITION
    • 全氟聚合物组合物
    • WO2016012339A1
    • 2016-01-28
    • PCT/EP2015/066269
    • 2015-07-16
    • SOLVAY SPECIALTY POLYMERS ITALY S.P.A.
    • FANTONI, MatteoARRIGONI, StefanoBOSSOLO, StefanoAVATANEO, Marco
    • C08F214/26C08K5/00C08K5/14C08K5/17C08K5/20
    • C08J3/24C08F214/26C08J2327/16C08J2327/18C08J2329/10C08K5/14C08K5/17C08K5/20C08K5/3465C08L27/18C08F216/1408C08F236/20
    • The invention pertains to a perfluoroelastomer composition comprising: - at least one perfluoroelastomer comprising iodine and/or bromine atoms [perfluoroelastomer (A)]; - from 0.5 to 5 weight parts, per 100 parts by weight of said perfluoroelastomer (A), of at least one bis-olefin [bis-olefin (OF)] having general formula (1) wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , equal or different from each other, are H, a halogen, or a C 1 -C 5 optionally halogenated group, possibly comprising one or more oxygen group; Z is a linear or branched C 1 -C 18 optionally halogenated alkylene or cycloalkylene radical, optionally containing oxygen atoms, or a (per)fluoropolyoxyalkylene radical; - from 0.1 to 3 weight parts, per 100 parts by weight of said perfluoroelastomer (A), of at least one organic peroxide; - from 0.1 to 3 weight parts, per 100 parts by weight of said perfluoroelastomer (A), of at least one organic base [base (B)] selected from the group consisting of: (i) non-aromatic primary amines or amides complying with general formula (B1m) or (Bid): R bm -[C(0)] t -NH 2 (B1m) H 2 N-[C(O) ]t' -R dm -[C(O) ]t" -NH 2 (Bid) wherein: - each of t, t' and t", equal to or different from each other and at each occurrence is zero or 1; - Rbm is a monovalent hydrocarbon non-aromatic group having 12 to 30 carbon atoms; - Rdm is a divalent hydrocarbon non-aromatic group having 6 to 30 carbon atoms; and (ii) cycloaliphatic secondary or tertiary amines complying with general formula (II) (B2m) or (B2d) wherein: - Cy represents a divalent aliphatic group comprising at least 4 carbon atoms, optionally comprising one or more than one ethylenically unsaturated double bond, and optionally comprising one or more catenary nitrogen atoms, forming a cycle with the nitrogen atom which is connected thereto; - Cy' represent a trivalent aliphatic group comprising at least 5 carbon atoms, optionally comprising one or more than one ethylenically unsaturated double bond, and optionally comprising one or more catenary nitrogen atoms, forming a cycle with the nitrogen atom which is connected thereto.
    • 本发明涉及全氟弹性体组合物,其包含:至少一种包含碘和/或溴原子的全氟弹性体[全氟弹性体(A)]; - 每100重量份所述全氟弹性体(A)0.5至5重量份至少一种具有通式(1)的至少一种双烯烃[双烯烃(OF)],其中R1,R2,R3,R4, R 5和R 6彼此相同或不同,是H,卤素或可以包含一个或多个氧基的C 1 -C 5任选卤代基; Z是任选含有氧原子的直链或支链C1-C18任选卤代亚烷基或亚环烷基,或(全)氟聚氧亚烷基; - 每100重量份所述全氟弹性体(A)0.1至3重量份的至少一种有机过氧化物; - 每100重量份所述全氟弹性体(A)0.1至3重量份至少一种选自以下的有机碱[碱(B)]:(i)非芳族伯胺或酰胺符合 具有通式(B1m)或(Bid):Rbm- [C(0)] t-NH2(B1m)H2N- [C(O)] t'-Rdm- [C(O)] t“-NH2 )其中: - t,t'和t“中的每一个彼此等于或不同,并且在每次出现时为零或1; -Rbm是碳原子数12〜30的一价烃类非芳香族基团, Rdm是碳原子数为6〜30的二价烃非芳香族基团。 和(ii)符合通式(II)(B2m)或(B2d)的脂环族仲胺或叔胺其中:-Cy表示包含至少4个碳原子的二价脂族基团,任选地包含一个或多于一个烯属不饱和双键 并且任选地包含一个或多个悬链氮原子,与与其连接的氮原子形成一个循环; -Ci'代表包含至少5个碳原子,任选地包含一个或多于一个烯属不饱和双键的三价脂族基团,并且任选地包含一个或多个链状氮原子,与连接有氮原子的氮原子形成一个循环。
    • 8. 发明申请
    • HYPERBRANCHED FLUOROELASTOMER ADDITIVE
    • 超滤荧光增容剂添加剂
    • WO2012168351A1
    • 2012-12-13
    • PCT/EP2012/060786
    • 2012-06-07
    • SOLVAY SPECIALTY POLYMERS ITALY S.P.A.FANTONI, MatteoCOMINO, GiovanniAPOSTOLO, Marco
    • FANTONI, MatteoCOMINO, GiovanniAPOSTOLO, Marco
    • C08F214/26
    • C08F14/26C08F214/26C08F214/262C08F214/265
    • The invention pertains to a hyperbranched (per)fluoroelastomer [fluoroelastomer (B)] comprising recurring units derived from a bis-olefin [bis-olefin (OF)] having general formula (I): wherein R 1 , R 2 , R 3 , R 4 , R 5 and R 6 , equal or different from each other, are H or C 1 -C 5 alkyl; Z is a linear or branched C 1 -C 18 alkylene or cycloalkylene radical, optionally containing oxygen atoms, preferably at least partially fluorinated, or a (per)fluoropolyoxyalkylene radical, said fluoroelastomer (B) having a slope in G' curve such that the ratio: G' 100 /G' 0.01 is of less than 10, when determined at 260°C according to ASTM D4440 standard, wherein G'100 is the storage modulus at a shear rate of 100 rad/sec and G' 0.01 is the storage modulus at a shear rate of 0.01 rad/sec, to compositions comprising the same, and to a process for their manufacture.
    • 本发明涉及含有通式(I)的双烯烃[双烯烃(OF)]的重复单元的超支化(全)含氟弹性体(含氟弹性体(B)):其中R1,R2,R3,R4,R5 和R 6相同或不同,为H或C 1 -C 5烷基; Z是直链或支链的C 1 -C 18亚烷基或亚环烷基,任选地含有氧原子,优选至少部分氟化的,或(全)氟聚氧亚烷基,所述含氟弹性体(B)具有G'曲线的斜率, 当根据ASTM D4440标准在260℃下测定时,G'100 / G'0.01小于10,其中G'100是剪切速率为100rad / sec的储能模量,G'0.01为储能模量 以0.01rad / sec的剪切速率加入包含该组合物的组合物,以及其制备方法。