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1. 发明申请

WO2020126975A1 FLUOROPOLYMER HYBRID COMPOSITE 审中-公开
公开(公告)号：WO2020126975A1
公开(公告)日：2020-06-25
申请号：PCT/EP2019/085246
申请日：2019-12-16
申请人： SOLVAY SA , POLITECNICO DI TORINO
发明人： FRACHE, Alberto , SANTANGELETTA, Silvia , BATTEGAZZORE, Daniele , ABUSLEME, Julio A. , HAMON, Christine , BESANA, Giambattista , BRUSSEAU, Ségolène
IPC分类号： H01M10/0565 , H01M14/00
摘要： The invention pertains to a process for the manufacture of a polymer electrolyte based on a fluoropolymer hybrid organic/inorganic composite, to a polymer electrolyte obtained thereof and to uses of said polymer electrolyte and membranes obtained therefrom in various applications, especially in electrochemical and in photo-electrochemical applications.

2. 发明申请

WO2021069469A1 FLUOROPOLYMER HYBRID COMPOSITE 审中-公开
公开(公告)号：WO2021069469A1
公开(公告)日：2021-04-15
申请号：PCT/EP2020/078056
申请日：2020-10-07
申请人： SOLVAY SA , POLITECNICO DI TORINO
发明人： BATTEGAZZORE, Daniele , FRACHE, Alberto , ABUSLEME, Julio A. , BESANA, Giambattista
IPC分类号： C08F214/22 , C09D127/16 , C08J5/22 , H01M8/10
摘要： The invention pertains to a process for the manufacture of a polymer electrolyte membrane based on a fluoropolymer hybrid organic/inorganic composite, to a polymer electrolyte obtained thereof and to uses of said polymer electrolyte and membranes obtained therefrom in various applications, especially in electrochemical and in photo-electrochemical applications.

3. 发明申请

WO2018206612A1 FLUOROPOLYMER HYBRID COMPOSITE 审中-公开
公开(公告)号：WO2018206612A1
公开(公告)日：2018-11-15
申请号：PCT/EP2018/061937
申请日：2018-05-08
申请人： SOLVAY SA
发明人： FRACHE, Alberto , ABUSLEME, Julio, A. , CISTERNINO, Alberto , HAMON, Christine , BESANA, Giambattista , BRUSSEAU, Ségolène , LAVASELLI, Matteo , CAMINO, Giovanni
IPC分类号： C08J5/22 , B01D71/34 , C08L27/16 , C08L71/02 , H01M10/0525 , H01M10/0565
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a film comprising said fluoropolymer hybrid organic/inorganic composite and to uses of said film in various applications, especially in electrochemical and in photo-electrochemical applications.

4. 发明申请

WO2015007706A1 FLUOROPOLYMER FIBRE 审中-公开
标题翻译：荧光纤维
公开(公告)号：WO2015007706A1
公开(公告)日：2015-01-22
申请号：PCT/EP2014/065080
申请日：2014-07-15
申请人： SOLVAY SA
发明人： ABUSLEME, Julio A. , BESANA, Giambattista , BASSI, Mattia , HAMON, Christine , GUALANDI, Chiara , FOCARETE, Maria Letizia , ZUCCHELLI, Andrea
IPC分类号： D01F6/32 , D01F6/48 , D01D5/00 , D04H1/728 , D04H1/4318 , D01F1/10 , C08G83/00 , C08F214/18
CPC分类号： D01F6/32 , B01D67/0079 , B01D71/32 , B01D71/76 , C08F214/18 , D01D5/003 , D01D5/0038 , D01F1/10 , D01F6/48 , D02J1/00 , D04H1/4318 , D04H1/728 , D10B2321/042 , D10B2321/08 , D10B2401/06 , D10B2401/061 , D10B2401/16 , D10B2505/00 , D10B2505/04 , H01M2/162 , H01M2/1686 , H01M10/052 , H01M10/0525
摘要： The present invention pertains to a process for manufacturing one or more fluoropolymer fibres, said process comprising the following steps: (i) providing a liquid composition [composition (C1)] comprising: - at least one fluoropolymer comprising at least one hydroxyl end group [polymer (F OH )L and - a liquid medium comprising at least one organic solvent [solvent (S)]; (ii) contacting the composition (C1) provided in step (i) with at least one metal compound [compound (M)] of formula (I) here below: X 4-m AY m (I) wherein X is a hydrocarbon group, optionally comprising one or more functional groups, m is an integer from 1 to 4, A is a metal selected from the group consisting of Si, Ti and Zr, and Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, thereby providing a liquid composition [composition (C2)]; (iii) submitting to at least partial hydrolysis and/or polycondensation the composition (C2) provided in step (ii) thereby providing a liquid composition [composition (C3)] comprising at least one fluoropolymer hybrid organic/inorganic composite; (iv) processing the composition (C3) provided in step (iii) by electrospinning thereby providing one or more fluoropolymer fibres; (v) drying the fluoropolymer fibre(s) provided in step (iv); and (vi) optionally, submitting to compression the fluoropolymer fibre(s) provided in step (v) at a temperature comprised between 50°C and 300°C. The invention also pertains to a process for the manufacture of said fluoropolymer fibre(s) and to uses of said fluoropolymer fibre(s) in various applications.
摘要翻译：本发明涉及制备一种或多种含氟聚合物纤维的方法，所述方法包括以下步骤：（i）提供液体组合物[组合物（C1）]，其包含：至少一种包含至少一个羟基端基的含氟聚合物[ 聚合物（FOH）L和 - 包含至少一种有机溶剂[溶剂（S）]的液体介质; （ⅱ）将步骤（ⅰ）中提供的组合物（C1）与下式的式（I）的至少一种金属化合物[化合物（M））接触：X4-mAYm（I）其中X是烃基，任选包括一个或多个官能团，m是1至4的整数，A是选自Si，Ti和Zr的金属，Y是选自烷氧基，酰氧基的可水解基团和羟基，从而提供液体组合物[组合物（C2）]; （iii）使步骤（ii）中提供的组合物（C2）至少部分水解和/或缩聚，从而提供包含至少一种含氟聚合物杂化有机/无机复合材料的液体组合物[组合物（C3）]; （iv）通过静电纺丝处理步骤（iii）中提供的组合物（C3），从而提供一种或多种含氟聚合物纤维; （v）干燥步骤（iv）中提供的含氟聚合物纤维; 和（vi）任选地，在50℃和300℃之间的温度下压缩步骤（v）中提供的含氟聚合物纤维。本发明还涉及制造所述含氟聚合物纤维的方法以及所述含氟聚合物纤维在各种应用中的用途。

5. 发明申请

WO2017085101A1 FLUOROPOLYMER HYBRID COMPOSITE 审中-公开
标题翻译：含氟聚合物混杂复合材料
公开(公告)号：WO2017085101A1
公开(公告)日：2017-05-26
申请号：PCT/EP2016/077822
申请日：2016-11-16
申请人： SOLVAY SA
发明人： ABUSLEME, Julio A. , LAVASELLI, Matteo , HAMON, Christine , FRACHE, Alberto , BESANA, Giambattista , CAMINO, Giovanni , BRUSSEAU, Ségolène
IPC分类号： C08J5/22 , C08L27/16 , C08L71/02 , C08L83/12 , H01M8/1048 , C08K5/5415
CPC分类号： C08L27/16 , C08J5/22 , C08K5/5415 , C08L71/02 , H01M2/145 , H01M2/1646 , H01M2/1653 , H01M2/166 , H01M10/052 , H01M2300/0068 , H01M2300/0082 , H01M2300/0091 , C08L83/12
摘要： The present invention pertains to a fluoropolymer hybrid organic/inorganic composite, to a film comprising said fluoropolymer hybrid organic/inorganic composite and to uses of said film in various applications, in particular in electrochemical and in photo-electrochemical applications.
摘要翻译：本发明涉及含氟聚合物杂化有机/无机复合材料，涉及包含所述含氟聚合物杂化有机/无机复合材料的膜以及所述膜在各种应用中的用途，特别是用于电化学和光 - 电化学应用。

6. 发明申请

WO2014067816A1 PROCESS FOR MANUFACTURING FLUOROPOLYMER HYBRID COMPOSITES 审中-公开
标题翻译：制造氟聚合物混合复合材料的方法
公开(公告)号：WO2014067816A1
公开(公告)日：2014-05-08
申请号：PCT/EP2013/072067
申请日：2013-10-22
申请人： SOLVAY SA
发明人： FRACHE, Alberto , TATA, Jennifer Katty , CAMINO, Giovanni , BESANA, Giambattista , ABUSLEME, Julio A.
IPC分类号： C08J3/20 , C08J3/205 , B32B27/08 , B32B27/36 , B32B27/30
CPC分类号： C08J5/00 , C08J3/201 , C08J3/2056 , C08J2327/16 , C08J2327/18 , C08K5/05
摘要： The invention pertains to a process for manufacturing a fluoropolymer hybrid organic/inorganic composite comprising: (i) partially hydrolysing and/or polycondensing, in the presence of an aqueous medium, a metal compound of formula (I): X4-mAYim, wherein X is a hydrocarbon group, Y is a hydrolysable group selected from the group consisting of an alkoxy group, an acyloxy group and a hydroxyl group, A is a metal selected from the group consisting of Si, Ti and Zr, and m is an integer from 1 to 4, so as to obtain an aqueous medium comprising a pre-gelled metal compound comprising one or more inorganic domains consisting of≡A-O-A≡ bonds and one or more residual hydrolysable groups Y [compound (M)], and then (ii) reacting in the molten state at least a fraction of hydroxyl groups of a functional fluoropolymer [polymer (F)] with at least a fraction of hydrolysable groups Y of said pre-gelled metal compound [compound (M)], so as to obtain a fluoropolymer hybrid organic/inorganic composite. The invention also pertains to uses of said fluoropolymer hybrid organic/inorganic composite in several applications.
摘要翻译：本发明涉及一种制备含氟聚合物杂化有机/无机复合材料的方法，包括：（i）在含水介质存在下部分水解和/或缩聚式（I）的金属化合物：X4-mayim，其中X 是烃基，Y是选自烷氧基，酰氧基和羟基的可水解基团，A是选自Si，Ti和Zr的金属，m是从 1至4，以获得包含预先凝胶化的金属化合物的水性介质，所述预凝胶化金属化合物包含一个或多个由以下组成的无机区域：AOA≡键和一个或多个残余可水解基团Y [化合物（M）]，然后（ii）在熔融状态下使至少一部分所述预胶化金属化合物[化合物（M）]的可水解基团Y的官能含氟聚合物[聚合物（F）]的羟基的至少一部分反应，以获得氟聚合物杂化有机/无机复合材料。本发明还涉及在几种应用中所述含氟聚合物杂化有机/无机复合材料的用途。

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