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    • 1. 发明申请
    • CONDENSATION PRODUCTS BASED ON AMINO-S-TRIAZINES AND THE USE OF THE SAID PRODUCTS
    • 依据氨基酸-S三嗪以及它们的使用缩合产物
    • WO1996030423A1
    • 1996-10-03
    • PCT/EP1996001403
    • 1996-03-29
    • SKW TROSTBERG AKTIENGESELLSCHAFTWEICHMANN, JosefSTADLER, AloisiaKERN, Alfred
    • SKW TROSTBERG AKTIENGESELLSCHAFT
    • C08G12/40
    • C04B24/223C04B2103/30C08G12/40
    • In the proposed condensation product based on amino-s -triazines with at least two amino groups, formaldehyde and sulphite, the molar ratio of amino-s-triazine, formaldehyde and sulphite is 1 : 2.5 - 6.0 : 1.51 - 2.0 and the formiate content is less than 0.3 wt %. The condensation product is obtained by a) heating amino-s-triazine, formaldehyde and a sulphite in the molar ratio 1 : 2.5 - 6.0 : 1.51 - 2.0 in an aqueous solution at a temperature of 60-90 DEG C and a pH level of between 9.0 and 13.0 until the sulphite can no longer be detected; b) continuing the condensation at a pH level of between 3.0 and 6.5 and a temperature of 60-80 DEG C until the condensation product has a viscosity of 5-50 mm/s at 80 DEG C; and c) adjusting the pH level of the condensation product to 7.5-12.0 or carrying out thermal secondary treatment at a pH level of >/= 10.0 and a temperature of 60-100 DEG C. The product can be used as an additive for inorganic binders such as cement.
    • 基于氨基-s-三嗪与至少两个氨基基团,甲醛和亚硫酸盐的缩合产物,氨基-s-三嗪与甲醛的摩尔比为亚硫酸盐1:2.5〜6.0,1.51〜2.0, 和甲酸含量小于0.3重量%。 其制备是加热一)氨基-s-三嗪,甲醛和的摩尔比1亚硫酸盐:在60℃至90℃,的温度下在水溶液中1.51〜2.0:2.5〜6.0 pH为9.0〜13.0,直至亚硫酸盐是不再可检测,b)然后将在pH 3.0和6.5和60至80℃的温度之间,缩合的 为只要直到在80℃下5至50毫米/秒,并具有C)然后缩合产物调节到7.5的pH值到12.0或热后处理在pH进行粘度的缩合产物 值> / = 10.0和60〜100℃的温度下 该产品适于作为无机粘合剂的添加剂,特别是水泥。
    • 4. 发明申请
    • METHOD OF PREPARING N-PHOSPHONOMETHYLGLYCINE
    • 工艺生产N-膦
    • WO1998003517A1
    • 1998-01-29
    • PCT/EP1997003955
    • 1997-07-22
    • SKW TROSTBERG AKTIENGESELLSCHAFTNEUMANN, ThomasFLEISCHER, FrankGRAEFE, JürgenHAMMER, Benedikt
    • SKW TROSTBERG AKTIENGESELLSCHAFT
    • C07F09/38
    • C07F9/3813
    • To prepare N-phosphonomethylglycine, (a) react aminomethylphosphonic acid or one of its salts in water, optionally adding alkaline lyes, with an alkali carbonate and/or alkali hydrogen carbonate or with carbon dioxide and an alkaline lye, (b) hydroxymethylate the resulting alkali salt of the N-phosphonomethylcarbamic acid with formaldehyde, (c) react the resulting salts of the N-hydromethyl-N-phosphonomethylcarbamic acid, optionally adding an alkaline lye, with hydrocyanic acid and/or a cyanide, and (d) adding acids, convert the resulting salts of the N-carboxy-N-phosphonomethylformaldehyde cyanhydrine into N-phosphonomethylglycine through hydrolysis and decarboxylation. This method gives excellent yields and a high degree of purity of N-phosphonomethylglycine.
    • 对于N-膦的制备中所采用的)氨基甲基膦酸或在水中它的盐,任选地加入的碱金属氢氧化物溶液与碱金属碳酸盐和/或碳酸氢盐,或与二氧化碳,并且为了碱金属氢氧化物溶液,B)羟甲基化的N-如此形成的碱金属盐 下面与甲醛phosphonomethylcarbamidsäure,c)设置在这样得到的N-羟甲基-N-phosphonomethylcarbamidsäure的盐任选地添加有转移限制为氰化氢和/或氰化物和d)中,N-羧基 - N-的盐,从而形成的碱液的 用加入酸通过水解和脱羧N-膦phosphonomethylglyconitrils。 以这种方式,N-膦可以以优异的收率和高纯度来制备。
    • 6. 发明申请
    • PROCESS FOR FRACTIONATING VISCOUS SILICONES
    • 方法进行分馏硅胶VISCOSER
    • WO1998029474A1
    • 1998-07-09
    • PCT/EP1997007301
    • 1997-12-24
    • SKW TROSTBERG AKTIENGESELLSCHAFTHEIDLAS, JürgenVON SEYERL, Joachim
    • SKW TROSTBERG AKTIENGESELLSCHAFT
    • C08G77/36
    • C08G77/36
    • In order to fractionate viscous silicones, oily or polymer diorganosilicones with a chain length from 2 to 10.000 are continuously separated with condensed hydrocarbons such as ethane, propane and n- or i-butane or their mixtures into a head and a bottom product, preferably in an extraction column, at temperatures between 25 and 250 DEG C, pressures between 20 and 500 bars and a gas density > 160 kg/m . In order to avoid viscosity-caused problems, an organic solvent in the form of a C5-8-alkane or up to 85 % by weight of the condensed gas (mixture) can be added to the starting materials before the fractionation. This process enables high-grade viscous silicone fractions to be obtained, with a chain length from 200 to 10,000 and/or a viscosity from 100 to 500,000 mPas, as well as a total D4 to D20 oligomer content below 0.05 % by weight.
    • 对于具有链长2-10000状油或聚合物分馏viscoser硅Diorganosilicone与压缩烃如乙烷,丙烷和正 - 或异丁烷或它们的混合物,在25和250℃,20至500巴之间的压力和温度之间的其 的>160公斤/ m的气体密度<3>优选连续在萃取塔分离成顶部和底部产物。 为了规避粘度问题,它可以被添加到到分馏在C 5-8 - 烷的形式是有机溶剂,或至多85重量压缩气体(混合物)的%之前的起始原料。 与获得高品质的粘胶硅氧烷组分,其具有200至10,000和/或100至500000毫帕·秒,并且它们Gesamtoligomerengehalt D4到D20的粘度的链长度的方法是小于0.05重量%。
    • 9. 发明申请
    • GRAFT POLYMERS OF KETO-ALDEHYDE CONDENSATION OR CO-CONDENSATION PRODUCTS
    • 酮醛缩合的接枝聚合物或 共缩合产物
    • WO1995001315A1
    • 1995-01-12
    • PCT/EP1994002160
    • 1994-07-01
    • SKW TROSTBERG AKTIENGESELLSCHAFTFELIXBERGER, JosefPLANK, Johann
    • SKW TROSTBERG AKTIENGESELLSCHAFT
    • C04B24/30
    • C09K3/00B01F17/005C04B24/16C04B24/166C04B24/30C08F283/00C08F283/06C08F289/00C09K8/12C09K8/24C09K8/607
    • Described are graft polymers of keto-aldehyde condensation or co-condensation products and/or compounds thereof with monovalent or polyvalent metals, the condensation products consisting of (a) symmetrical or unsymmetrical ketones containing aliphatic, arylaliphatic, cyclic or aromatic hydrocarbon groups including at least one non-aromatic group, (b) an aldehyde of the formula R-(CHO)n in which n = 1 or 2 and R = hydrogen or an aliphatic, arylaliphatic, aromatic or heterocyclic group and, optionally, (c) carboxy, sulpho, sulphamido, sulphoxy, sulphoalkylamino or sulphoalkyloxy groups, anionic and/or non-ionic and/or cationic unsaturated monomers being grafted to the condensation products. These graft polymers are eminently suitable for use as dispersants in inorganic-binder suspensions and solutions, aqueous clay suspensions and solutions and charcoal-in-water suspensions, as retention agents, as thickeners, in particular for aqueous systems, and as agents for preventing the swelling of clay in aqueous systems.
    • 有的酮醛缩合或共缩合产物和/或它们的单或描述的多价金属化合物的接枝聚合物,其中所述缩合产物:a)与脂族,芳脂族,环状或芳族烃基对称或不对称酮的具有至少一个非芳族基团 ,(b)式R-CHO的醛)n,其中n可以是1至2和R =氢,脂族,芳脂族,芳族或杂环基团,和c)任选从羧基,磺基,磺氨基 - ,亚砜,或Sulfoalkylamin- sulphoalkyloxy基团包括,已被移植到其中的阴离子和/或非离子和/或阳离子不饱和单体。 这些接枝聚合物是特别适合作为分散剂用于无机粘结剂的悬浮液和溶液,含水粘土悬浮液和溶液或煤 - 水悬浮液,作为助留剂,增稠剂,特别是用于含水体系,以及装置,用于防止Anquellens粘土的水性体系中。