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    • 2. 发明申请
    • THERMOPLASTIC FORMULATION WITH IMPROVED ADHESION
    • 具有改善粘合性的热塑性配方
    • WO2017137454A1
    • 2017-08-17
    • PCT/EP2017/052786
    • 2017-02-08
    • SIKA TECHNOLOGY AG
    • FRICK, KarstenKRÜGER, ChristianCIL, Engin
    • C08J9/00C08J9/10C08G18/00C08G59/02C08G59/18C08G18/10C08L75/04
    • C08J9/103C08G18/2845C08G18/4854C08G18/581C08G18/69C08G18/755C08G59/02C08J9/0023C08J9/0061C08J9/105C08J2201/026C08J2203/04C08J2323/08C08J2423/08C08J2475/04
    • Disclosed is a thermally expandable composition, comprising at least one polymer P, cross-linkable by peroxide, furthermore at least one peroxide, preferably at least one acrylate, at least one blowing agent B, preferably at least one activator for the blowing agent, and at least one epoxide group terminated polymer of the formula (I), wherein Y represents a n-valent radical of a linear or branched polyurethane polymer terminated with isocyanate groups after the removal of the n terminal isocyanate groups, Z represents a (1 + m)-valent radical of an aliphatic, cycloaliphatic, aromatic or araliphatic epoxide containing a primary or secondary hydroxyl group after the removal of the hydroxyl group and m epoxide groups, m represents an integer with a value of 1, 2, or 3, and n represents an integer with a value from 2 to 4. The thermally expandable composition shows superior adhesion properties, especially on metallic substrates and in particular on oily surfaces, can be expanded volumetrically by at least 1000% and is especially suitable for baffle and/or reinforcement elements, e.g. in automotive manufacturing.
    • 公开了一种可热膨胀组合物,其包含至少一种可由过氧化物交联的聚合物P,此外还有至少一种过氧化物,优选至少一种丙烯酸酯,至少一种发泡剂B,优选至少一种 一种用于发泡剂的活化剂和至少一种式(I)的环氧基封端的聚合物,其中Y表示在除去n端异氰酸酯基之后用异氰酸酯基封端的线性或支化聚氨酯聚合物的n价基团 Z表示在除去羟基和环氧基之后含有伯羟基或仲羟基的脂族,脂环族,芳族或芳脂族环氧化物的(1 + m)价基团,m表示值为1的整数 ,2或3,并且n表示值为2至4的整数。热膨胀性组合物显示出优异的粘合性,特别是在金属基材上,特别是在油性表面上,可以被膨胀 体积至少为1000%,特别适用于挡板和/或增强元件,例如, 在汽车制造业。