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1. 发明申请

WO2006123804A1 CARBOXYL GROUP-CONTAINING POLYURETHANE, HEAT-CURABLE RESIN COMPOSITION AND USES THEREOF 审中-公开
标题翻译：含羧基的聚氨酯，可固化树脂组合物及其用途
公开(公告)号：WO2006123804A1
公开(公告)日：2006-11-23
申请号：PCT/JP2006/310084
申请日：2006-05-16
申请人： SHOWA DENKO K.K. , UCHIDA, Hiroshi , HIRAKAWA, Ritsuko , MIYAJIMA, Yoshio , INOUE, Hirofumi , KIMURA, Kazuya , AZUMA, Yukihiko
发明人： UCHIDA, Hiroshi , HIRAKAWA, Ritsuko , MIYAJIMA, Yoshio , INOUE, Hirofumi , KIMURA, Kazuya , AZUMA, Yukihiko
IPC分类号： C08G18/65 , C08G18/34 , C08G18/62 , C08G18/08
CPC分类号： H05K3/285 , C08G18/0823 , C08G18/348 , C08G18/44 , C08G18/6576 , C08G18/6659 , C08G18/69 , C08G18/698 , C09D11/106 , C09D175/04 , H05K1/0393
摘要： Disclosed is a carboxyl group-containing polyurethane (A) produced from a polyol (b) containing at least 10 mol% (relative to the total (100 mol%) of the polyol (b)) of a polyol (b1) which: (i) has a number-average molecular weight of 500 to 50,000; (ii) has 1 to 10 hydroxyl groups per molecule; and (iii) is one or a combination of two or more polyols selected from the group consisting of polybutadiene polyol, polyisoprene polyol, hydrogenated polybutadiene polyol and hydrogenated polyisoprene polyol. The carboxyl group-containing polyurethane (A) is suitable as materials of cured products, for example cured films, that are excellent in adhesion with substrates, low warpage, flexibility, plating resistance, soldering heat resistance and long-term reliability.
摘要翻译：公开了由多元醇（b）生成的含有羧基的聚氨酯（A），该多元醇（b）含有多元醇（b1）的至少10摩尔％（相对于多元醇（b）的总量（100摩尔％））为：（ i）数均分子量为500〜50,000; （ii）每分子具有1至10个羟基; 和（iii）是选自聚丁二烯多元醇，聚异戊二烯多元醇，氢化聚丁二烯多元醇和氢化聚异戊二烯多元醇的一种或两种以上的多元醇的组合。含羧基的聚氨酯（A）适合作为与基材的粘合性优异，翘曲翘曲，柔韧性，耐电镀性，焊接耐热性，长期可靠性等固化物例如固化膜的材料。

2. 发明申请

WO2005103822A2 PHOTOSENSITIVE RESIN COMPOSITION, CURED PRODUCT THEREOF AND PRODUCTION METHOD OF PRINTED CIRCUIT BOARD USING THE SAME 审中-公开
标题翻译：光敏树脂组合物，其固化产物及其印刷电路板的制造方法
公开(公告)号：WO2005103822A2
公开(公告)日：2005-11-03
申请号：PCT/JP2005/008100
申请日：2005-04-21
申请人： SHOWA DENKO K.K. , ISHIGAKI, Satoru , UCHIDA, Hiroshi , MIYAJIMA, Yoshio , MORINAKA, Katsutoshi
发明人： ISHIGAKI, Satoru , UCHIDA, Hiroshi , MIYAJIMA, Yoshio , MORINAKA, Katsutoshi
IPC分类号： G03F7/00
CPC分类号： G03F7/027 , C08G18/0823 , C08G18/4854 , C08G18/672 , C08G18/755 , C09D175/16 , G03F7/032 , G03F7/033 , G03F7/035 , G03F7/038 , G03F7/0388 , H05K3/287 , Y10T428/31855 , C08G18/6692
摘要： There are provided a novel photosensitive resin composition, a cured film of which has ample flexibility, and which yields an insulating protective coating having superior soldering heat resistance, thermal degradation resistance and electroless gold plating resistance. The photosensitive resin composition as claimed in the present invention comprises: a photopolymerizeable component containing a urethane acrylate compound (A) and a compound (B) having an ethylenic unsaturated group other than said urethane acrylate compound (A), a thermosetting resin (C), a photopolymerization initiator (D) and a thermal polymerization catalyst (E); wherein, said urethane acrylate compound (A) is the reaction product of an isocyanate compound (a-1) of the following general formula (1): CH2=CH-COO-R-NCO (1) (wherein, R represents a hydrocarbon group having 1 to 30 carbon atoms) with a polyhydroxy compound (a-2).
摘要翻译：提供了一种新颖的感光性树脂组合物，其固化膜具有充分的柔软性，并且产生具有优异的耐焊接耐热性，耐热劣化性和无电镀金电镀性的绝缘保护涂层。本发明的感光性树脂组合物包含：含有氨基甲酸酯丙烯酸酯化合物（A）和除所述氨基甲酸酯丙烯酸酯化合物（A）以外具有乙烯性不饱和基团的化合物（B）的光聚合性成分，热固性树脂（C），光聚合引发剂（D）和热聚合催化剂（E）; 其中所述氨基甲酸酯丙烯酸酯化合物（A）是以下通式（1）的异氰酸酯化合物（a-1）：CH 2 = CH-COO-R-NCO（1）（其中R表示烃具有1至30个碳原子的基团）与多羟基化合物（a-2）反应。

3. 发明申请

WO2006106892A1 FLAME-RETARDANT COMPOSITION FOR SOLDER RESIST AND CURED PRODUCT THEREOF 审中-公开
标题翻译：用于焊接电阻的阻燃组合物及其固化产品
公开(公告)号：WO2006106892A1
公开(公告)日：2006-10-12
申请号：PCT/JP2006/306767
申请日：2006-03-24
申请人： SHOWA DENKO K.K. , MIYAJIMA, Yoshio
发明人： MIYAJIMA, Yoshio
IPC分类号： G03F7/038 , G03F7/035 , G03F7/032
CPC分类号： G03F7/032 , G03F7/0047 , G03F7/035 , G03F7/038 , G03F7/0388 , H05K3/287 , Y10T428/31511
摘要： There is provided a flame retardant composition for a solder resist which is halogen-free and has a high level of flame retardance and flexibility, while exhibiting excellent heat resistance, moisture resistance and high-temperature reliability. The flame retardant composition for a solder resist according to the invention comprises (A) an alkali-soluble resin comprising either or both (A1) a carboxyl group-containing epoxy (meth)acrylate or (A2) a carboxyl group-containing urethane (meth)acrylate obtained by reacting an epoxy resin with two or more epoxy groups in the molecule (a), an unsaturated group-containing monocarboxylic acid (b) and a polybasic acid anhydride (c), (B) a compound having an ethylenic unsaturated group in the molecule, (C) a photopolymerization initiator, (D) a phosphorus-containing epoxy resin having a specific structure and (E) a hydrated metal compound. The composition of the invention can be suitably used as a solder resist or cover lay film for an FPC.
摘要翻译：本发明提供阻燃剂的阻燃剂组合物，其为无卤素且具有高水平的阻燃性和柔韧性，同时具有优异的耐热性，耐湿性和高温可靠性。根据本发明的阻焊剂用阻燃剂组合物包含（A）包含（A1）含羧基的环氧（甲基）丙烯酸酯或（A2）含羧基的氨基甲酸酯（甲基）丙烯酸酯中的任一种或两者的碱溶性树脂）丙烯酸酯通过环氧树脂与分子（a）中的两个或更多个环氧基反应获得，不饱和基团的一元羧酸（b）和多元酸酐（c），（B）具有烯属不饱和基团在分子中，（C）光聚合引发剂，（D）具有特定结构的含磷环氧树脂和（E）水合金属化合物。本发明的组合物可以适合用作FPC的阻焊层或覆盖膜。

4. 发明申请

WO2006088230A1 THERMOSETTING COMPOSITION FOR SOLDER RESIST AND CURED PRODUCT THEREOF 审中-公开
标题翻译：耐火材料的热固化组合物及其固化产品
公开(公告)号：WO2006088230A1
公开(公告)日：2006-08-24
申请号：PCT/JP2006/303210
申请日：2006-02-16
申请人： SHOWA DENKO K.K. , MIYAJIMA, Yoshio , WADA, Tetsuo , NAKAMURA, Ayako
发明人： MIYAJIMA, Yoshio , WADA, Tetsuo , NAKAMURA, Ayako
IPC分类号： C08G59/42 , C08G59/20 , H01L23/00 , C08L63/00
CPC分类号： C08G59/4207 , C08G59/20 , C08L63/00 , H05K3/285 , H05K2201/0239 , H05K2203/124
摘要： There is provided a novel thermosetting composition for a solder resist with excellent flexibility, low warping upon curing, soldering heat resistance, PCT resistance and HHBT resistance, which is suitable as a thermosetting solder resist ink for printed circuit boards and particularly FPC boards. The thermosetting composition for a solder resist according to the invention comprises as essential components: (A) an epoxy resin having two or more epoxy groups in the molecule, (B) a polyacid anhydride represented by general formula (I) as defined in claims, wherein R represents a divalent organic group and n represents an integer of 2-30, and (C) a coupling agent.
摘要翻译：提供了一种用于阻焊剂的新型热固性组合物，其具有优异的柔韧性，固化时的翘曲性，耐焊接性，PCT电阻和HHBT电阻，其适用于印刷电路板，特别是FPC基板的热固性阻焊油墨。根据本发明的阻焊剂用热固性组合物包含作为必要成分的（A）分子中具有2个以上环氧基的环氧树脂，（B）权利要求1所述的通式（I）表示的多酸酐，其中R表示二价有机基团，n表示2-30的整数，和（C）偶联剂。

5. 发明申请

WO2006085494A1 FLAME-RETARDANT COMPOSITION FOR SOLDER RESIST AND USE THEREOF 审中-公开
标题翻译：用于焊接电阻的阻燃组合物及其用途
公开(公告)号：WO2006085494A1
公开(公告)日：2006-08-17
申请号：PCT/JP2006/301915
申请日：2006-01-30
申请人： SHOWA DENKO K.K. , MIYAJIMA, Yoshio , OOGA, Kazuhiko , ISHIGAKI, Satoru
发明人： MIYAJIMA, Yoshio , OOGA, Kazuhiko , ISHIGAKI, Satoru
IPC分类号： C08K5/00
CPC分类号： H05K3/287 , C08G59/066 , C08G59/30 , C08G59/42 , C08G59/4292 , C08K3/22 , C08K5/523 , G03F7/038 , H05K2201/012 , H05K2201/0209
摘要： A flame-retarding composition for a solder resist as claimed in the present invention comprises an unsaturated group-containing polycarboxylic acid resin (A), wherein a polybasic acid anhydride (c) is added to the reaction product of a bisphenol epoxy resin (a) represented with the following general formula (I): (wherein, n represents an integer of 1 to 10, X is selected from a methylene group, ethylidene group, isopropylidene group, sulfonyl group and single bond, and Y represents a hydrogen atom or a 2,3-epoxypropyl group) with an unsaturated group-containing monocarboxylic acid (b), a photoinitiator (B), an epoxy resin (C), a flame retardant (D) and a metal hydrate compound (E), and has superior low tack, flexibility and PCT resistance.
摘要翻译：本发明的阻焊剂用阻燃性组合物包含含有不饱和基团的多元羧酸树脂（A），其中在双酚环氧树脂（a）的反应产物中加入多元酸酐（c）由以下通式（I）表示：（其中，n表示1〜10的整数，X选自亚甲基，亚乙基，异亚丙基，磺酰基和单键，Y表示氢原子或（b），环氧树脂（C），阻燃剂（D）和金属水合物化合物（E）的光引发剂（B），光引发剂（B），金属水合物化合物（E）低粘性，柔韧性和PCT耐药性。

6. 发明申请

WO2003062296A1 PHOSPHORUS-CONTAINING URETHANE (METH)ACRYLATE COMPOUNDS AND PHOTOSENSITIVE COMPOSITIONS 审中-公开
标题翻译：含有磷酸盐（甲基）丙烯酸酯化合物和光敏组合物
公开(公告)号：WO2003062296A1
公开(公告)日：2003-07-31
申请号：PCT/JP2003/000490
申请日：2003-01-21
申请人： SHOWA DENKO K. K. , TAMURA, Kenji , MIYAJIMA, Yoshio , HIRATA, Motoyuki
发明人： TAMURA, Kenji , MIYAJIMA, Yoshio , HIRATA, Motoyuki
IPC分类号： C08G18/67
CPC分类号： C08G18/755 , C08G18/0823 , C08G18/348 , C08G18/388 , C08G18/3885 , C08G18/3889 , C08G18/4854 , C08G18/5084 , C08G18/6461 , C08G18/672 , C09D175/16 , H05K3/287 , Y10S528/905 , Y10S528/906 , C08G18/64
摘要： A phosphorus-containing urethane (meth)acrylate compound obtained by reacting (A) a polyol compound comprising (A1) a phosphorus-containing polyol having a phosphorus atom, with (B) a bifunctional or greater polyisocyanate and (C) a hydroxyl group-containing (meth)acrylate.
摘要翻译：（A）含有磷原子的含磷多元醇的多元醇化合物与（B）双官能以上的多异氰酸酯和（C）羟基 - （甲基）丙烯酸酯。

7. 发明申请

WO2002093255A2 PHOTOSENSITIVE COLORING COMPOSITON, COLOR FILTER USING THE COMPOSITON AND METHOD OF PRODUCING THE SAME 审中-公开
标题翻译：感光颜料组合物，使用组合物的颜色过滤器及其生产方法
公开(公告)号：WO2002093255A2
公开(公告)日：2002-11-21
申请号：PCT/JP2002/004645
申请日：2002-05-14
申请人： SHOWA DENKO K. K. , KAMATA, Hirotoshi , ONISHI, Mina , KATOH, Tsuyoshi , MIYAJIMA, Yoshio , MUROFUSHI, Katsumi
发明人： KAMATA, Hirotoshi , ONISHI, Mina , KATOH, Tsuyoshi , MIYAJIMA, Yoshio , MUROFUSHI, Katsumi
IPC分类号： G03C
CPC分类号： G03F7/0007 , G03F7/033 , G03F7/0388
摘要： A photosensitive coloring composition for color filters using coloring compositons containd (A) a binder resin having an amido group and a carboxyl group and (B) a coloring material has excellent photosensitivity and has improved dispersibility upon producing in particular a coloring composition containing a black pigment such as a carbon black. Use of (A') an epoxy(meth)acrylate resin can further improve the photosensitivity and from a black matrix having sufficient film strenght and low reflectivity. Furhter, use of a modified carbon black treated with a compound having a isocyanate group and an ethylenically unsaturaged bond in a molecule as the coloring material can give rise to a photosensitive resin composition excellent in optically opaque property, photosensitivity and dispersion stability.
摘要翻译：使用着色组合物的滤色剂用感光性着色组合物含有（A）具有酰胺基和羧基的粘合剂树脂和（B）着色材料，具有优异的光敏性，并且特别是制备含有黑色颜料的着色组合物时具有改善的分散性例如炭黑。（A'）环氧（甲基）丙烯酸酯树脂的使用可以进一步提高光敏性和具有足够的膜强度和低反射率的黑色基质。另外，使用在分子中用异氰酸酯基和烯属不饱和键化合物处理的改性炭黑作为着色材料可以产生光学不透明性，光敏性和分散稳定性优异的感光性树脂组合物。

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