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1. 发明申请

WO2011000792A2 PROCESS TO PREPARE A HYDROGEN RICH GAS MIXTURE 审中-公开
标题翻译：制备氢气混合物的方法
公开(公告)号：WO2011000792A2
公开(公告)日：2011-01-06
申请号：PCT/EP2010/059111
申请日：2010-06-28
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , FLEYS, Matthieu Simon Henri , GEUZEBROEK, Frank Haiko , PRINS, Mark Jan
发明人： VAN DEN BERG, Robert , FLEYS, Matthieu Simon Henri , GEUZEBROEK, Frank Haiko , PRINS, Mark Jan
IPC分类号： C10K3/04 , C01B3/16 , C10J3/48
CPC分类号： C01B3/32 , C01B3/16 , C01B3/52 , C01B2203/0294 , C01B2203/0415 , C01B2203/0465 , C01B2203/0475 , C01B2203/0485 , C01B2203/1041 , C01B2203/1052 , C01B2203/1076 , C01B2203/84 , C10J3/06 , C10J3/466 , C10J2300/093 , C10J2300/0956 , C10J2300/0959 , C10K3/04 , Y02E20/18
摘要： The invention is directed to a process to prepare a hydrogen rich gas mixture from a solid sulphur-and halogen-containing carbonaceous feedstock. The process involves the following steps. Step (a): gasification of the solid carbonaceous feedstock with an oxygen- containing gas to obtain a gas mixture comprising halogen compounds, sulphur compounds, hydrogen and at least 50vol.% carbon monoxide, on a dry basis. Step (b): contacting the gas mixture with a quench gas or quench liquid to reduce the temperature of the gas mixture to below 900°C. Step (c) contacting the gas mixture with water having a temperature of between 150 and 250°C to obtain a gas mixture comprising between 50 and 1000ppm halogen and having a steam to carbon monoxide molar ratio of between 0.2:1 and 0.9:1. Step (d): subjecting the gas mixture obtained in step (c) to a water gas shift reaction wherein part or all of the carbon monoxide is converted with the steam to hydrogen and carbon dioxide in the presence of a catalyst as present in one fixed bed reactor or in a series of more than one fixed bed reactors and wherein the temperature of the gas mixture as it enters the reactor or reactors is between 190 and 230°C. Step (e): carbon dioxide and sulphur compounds are separated from the shifted gas mixture obtained in step (d) by contacting the shifted gas mixture with a solvent comprising dialkyl ethers of polyethylene glycol.
摘要翻译：本发明涉及从固体含硫和含卤素的碳质原料制备富氢气体混合物的方法。该过程涉及以下步骤。步骤（a）：用含氧气体气化固体碳质原料，以干燥的方式获得包含卤素化合物，硫化合物，氢气和至少50体积％一氧化碳的气体混合物。步骤（b）：使气体混合物与骤冷气体或骤冷液体接触，以将气体混合物的温度降至900℃以下。步骤（c）使气体混合物与温度为150-250℃的水接触，得到含有50-1000ppm卤素且蒸汽与一氧化碳摩尔比在0.2:1至0.9:1之间的气体混合物。步骤（d）：将步骤（c）中获得的气体混合物进行水煤气变换反应，其中部分或全部一氧化碳在蒸汽存在下以蒸汽转化为氢气和二氧化碳，存在于一个固定的床反应器或一系列多于一个的固定床反应器，并且其中气体混合物进入反应器或反应器时的温度为190-230℃。步骤（e）：通过使转移的气体混合物与包含聚乙二醇的二烷基醚的溶剂接触，将二氧化碳和硫化合物与步骤（d）中获得的转移气体混合物分离。

2. 发明申请

WO2010112500A1 PROCESS FOR PRODUCING A PURIFIED SYNTHESIS GAS STREAM 审中-公开
标题翻译：生产纯化合成气流的方法
公开(公告)号：WO2010112500A1
公开(公告)日：2010-10-07
申请号：PCT/EP2010/054185
申请日：2010-03-30
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , FLEYS, Matthieu Simon Henri , PRINS, Mark Jan , SMIT, Cornelis Jacobus , WOLDHUIS, Alex Frederik
发明人： VAN DEN BERG, Robert , FLEYS, Matthieu Simon Henri , PRINS, Mark Jan , SMIT, Cornelis Jacobus , WOLDHUIS, Alex Frederik
IPC分类号： C01B3/16 , C01B3/52 , C01B3/50 , C01B3/58 , C01B17/04 , C01B31/20
CPC分类号： C01B3/58 , B01D53/002 , B01D53/1462 , B01D53/1493 , B01D53/22 , B01D53/228 , B01D53/75 , B01D53/8668 , B01D71/028 , B01D71/52 , B01D71/56 , B01D71/64 , B01D71/80 , B01D2251/206 , B01D2251/80 , B01D2256/16 , B01D2256/20 , B01D2257/304 , B01D2257/308 , B01D2257/408 , B01D2257/504 , C01B3/16 , C01B3/501 , C01B3/506 , C01B3/52 , C01B2203/0415 , C01B2203/0435 , C01B2203/0475 , C01B2203/0485 , Y02C10/06 , Y02C10/10 , Y02P20/13 , Y02P20/152
摘要： A process for producing a purified synthesis gas stream from a feed synthesis gas stream comprising besides the main constituents carbon monoxide and hydrogen also hydrogen sulphide, HCN and/or COS, the process comprising the steps of : (a) removing HCN and/or COS by contacting the feed synthesis gas stream with a catalyst in a HCN/COS reactor in the presence of steam/water, to obtain a synthesis gas stream depleted in HCN and/or in COS; (b) converting hydrogen sulphide in the synthesis gas stream depleted in HCN and/or in COS to elemental sulphur, by contacting the synthesis gas stream with an aqueous reactant solution containing solubilized Fe(III) chelate of an organic acid, at a temperature below the melting point of sulphur, and at a sufficient solution to gas ratio and conditions effective to convert H 2 S to sulphur and inhibit sulphur deposition, to obtain a synthesis gas stream depleted in hydrogen sulphide; (c) removing carbon dioxide from the synthesis gas stream depleted in hydrogen sulphide, to obtain the purified synthesis gas stream and a gas stream enriched in CO 2 .
摘要翻译：一种从原料合成气流生产纯化的合成气流的方法，除了主要成分一氧化碳和氢气外，还包括硫化氢，HCN和/或COS，该方法包括以下步骤：（a）除去HCN和/或COS 通过在蒸汽/水存在下，使HCN / COS反应器中的原料合成气流与催化剂接触，得到消耗在HCN和/或COS中的合成气流; （b）通过使合成气流与含有有机酸的可溶性Fe（III）螯合物的水性反应物溶液接触，将低于HCN和/或COS中的合成气流中的硫化氢转化成元素硫，温度低于硫的熔点，并且具有足够的气体比和有效将H 2 S转化成硫并抑制硫沉积的条件，以获得耗尽硫化氢的合成气流; （c）从贫硫化氢的合成气流中除去二氧化碳，以获得纯化的合成气流和富含CO 2的气流。

3. 发明申请

WO2010106148A1 PROCESS TO PREPARE A HYDROGEN RICH GAS MIXTURE 审中-公开
标题翻译：制备氢气混合物的方法
公开(公告)号：WO2010106148A1
公开(公告)日：2010-09-23
申请号：PCT/EP2010/053560
申请日：2010-03-18
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , PRINS, Mark Jan , FLEYS, Matthieu Simon Henri
发明人： VAN DEN BERG, Robert , PRINS, Mark Jan , FLEYS, Matthieu Simon Henri
IPC分类号： C01B3/16 , C01B3/52
CPC分类号： C01B3/16 , C01B3/52 , C01B2203/0283 , C01B2203/0288 , C01B2203/0415 , C01B2203/0465 , C10J3/466 , C10J2300/093 , C10K1/003 , C10K1/101 , C10K3/04 , Y02P20/52
摘要： Process to prepare a hydrogen rich gas mixture from a halogen containing gas mixture comprising hydrogen and at least 50 vol.% carbon monoxide, on a dry basis, by contacting the halogen containing gas mixture with water having a temperature of between 150 and 250°C to obtain a gas mixture poor in halogen and having a steam to carbon monoxide molar ratio of between 0.2:1 and 0.9:1 and subjecting said gas mixture poor in halogen to a water gas shift reaction wherein part or all of the carbon monoxide is converted with the steam to hydrogen and carbon dioxide in the presence of a catalyst as present in one fixed bed reactor or in a series of more than one fixed bed reactors and wherein the temperature of the gas mixture as it enters the reactor or reactors is between 190 and 230°C.
摘要翻译：通过使含卤素的气体混合物与温度为150-250℃的水接触，从含有氢气和至少50体积％一氧化碳的含卤素气体混合物中制备富氢气体混合物的方法，以获得不良卤素的气体混合物，其蒸汽与一氧化碳的摩尔比为0.2:1至0.9:1，并使所述不良卤素气体混合物进行水煤气变换反应，其中部分或全部一氧化碳转化在一个固定床反应器或一系列多于一个固定床反应器中存在的催化剂存在下，蒸汽进入氢气和二氧化碳，其中气体混合物进入反应器或反应器时的温度为190 和230℃。

4. 发明申请

WO2009130292A2 PROCESS TO PREPARE AN OLEFIN-CONTAINING PRODUCT OR A GASOLINE PRODUCT 审中-公开
标题翻译：制备含烯烃的产品或汽油产品的方法
公开(公告)号：WO2009130292A2
公开(公告)日：2009-10-29
申请号：PCT/EP2009/054920
申请日：2009-04-23
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , VAN WESTRENEN, Jeroen , CHEWTER, Leslie, Andrew , WINTER, Ferry
发明人： VAN DEN BERG, Robert , VAN WESTRENEN, Jeroen , CHEWTER, Leslie, Andrew , WINTER, Ferry
IPC分类号： C07C1/20 , C07C11/02 , C10G3/00
CPC分类号： C07C1/20 , C01B3/12 , C01B3/52 , C01B2203/0415 , C01B2203/047 , C01B2203/0475 , C01B2203/048 , C01B2203/0485 , C01B2203/0495 , C07C11/02 , C07C29/1518 , C07C41/09 , C07C2529/06 , C10G3/49 , C10G2300/1022 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10J3/485 , C10J3/84 , C10J2300/0916 , C10J2300/092 , C10J2300/093 , C10J2300/0959 , C10J2300/0973 , C10J2300/1659 , C10J2300/1665 , C10K1/002 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/007 , C10K1/04 , C10K1/10 , C10K1/101 , C10K1/143 , C10K1/16 , C10K3/04 , Y02E50/18 , Y02P20/145 , Y02P30/42 , C07C31/04 , C07C43/043
摘要： Process to prepare an olef in-containing product or a gasoline product from a solid carbonaceous feedstock by performing the steps of (a) feeding an oxygen comprising gas and the carbonaceous feedstock to a burner firing into a reactor vessel, which burner is preferably positioned horizontal, (b) performing a partial oxidation of the carbonaceous feedstock in said burner to obtain a stream of hot synthesis gas and a liquid slag, (c) cooling the hot synthesis gas by direct contacting with a liquid water- containing cooling medium, (e) performing a water shift reaction on at least part of the synthesis gas, to obtain a synthesis gas effluent, (g) performing an oxygenate synthesis using the synthesis gas effluent of step (e), to obtain a methanol and/or dimethylether containing oxygenate effluent and a first liquid water-rich by-product, (h) converting the oxygenate effluent to an olefin- containing product or a gasoline product and a second liquid water-rich by-product, wherein at least part of the first and/or second liquid water-rich by-product is used in step c), forming at least part of the liquid water-containing cooling medium.
摘要翻译：通过执行以下步骤来制备含烯烃产品或来自固体碳质原料的汽油产品的方法：（a）将包含气体和含碳原料的氧气输送到燃烧器中，将其燃烧到反应器容器中，该燃烧器优选地位于水平（b）在所述燃烧器中进行碳质原料的部分氧化，得到热合成气和液态渣的流，（c）通过与液态含水冷却介质直接接触来冷却热合成气，（e ）在合成气的至少一部分上进行水位转移反应，以获得合成气流出物，（g）使用步骤（e）的合成气流出物进行含氧化合物合成，得到含有含氧化合物的甲醇和/或二甲醚流出物和第一液体富含水的副产物，（h）将含氧化合物流出物转化为含烯烃的产物或汽油产物和第二液体富含水的副产物，其中至少在步骤c）中使用部分第一和/或第二液体富含水的副产物，形成至少部分含液体的含水冷却介质。

5. 发明申请

WO2009030675A1 SPRAY NOZZLE MANIFOLD AND PROCESS FOR QUENCHING A HOT GAS USING SUCH AN ARRANGEMENT 审中-公开
标题翻译：喷雾喷嘴喷嘴和使用这种安排排出热气的过程
公开(公告)号：WO2009030675A1
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061526
申请日：2008-09-02
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , HARTEVELD, Wouter Koen , HEINEN, Hans Joachim , VON KOSSAK-GLOWCZEWSKI, Thomas Paul
发明人： VAN DEN BERG, Robert , HARTEVELD, Wouter Koen , HEINEN, Hans Joachim , VON KOSSAK-GLOWCZEWSKI, Thomas Paul
IPC分类号： B01D47/06 , B05B7/04 , B05B15/02 , B05B15/04 , F28C3/08
CPC分类号： B05B7/0466 , B05B7/0475 , B05B12/18 , B05B12/36 , B05B15/55 , F28C3/08 , Y02E20/18
摘要： Spray nozzle manifold (25) comprising a first co-axial passage (26) for supply of an atomisation gas, a second coaxial passage (27) present in said first passage for supply of a liquid, more than one laterally spaced nozzles (16) for atomisation and spraying liquid in a direction away from the longitudinal axis of the manifold (25) the nozzle is attached to the first passage, said nozzles having an inlet for liquid fluidly connected to said second passage (27), an inlet for atomisation gas fluidly connected to the first passage (26), a mixing chamber (37) wherein atomisation gas and liquid mix and an outlet (24) for a mixture of atomisation gas and liquid, wherein the nozzle has an opening (33) for discharge of atomisation gas which opening is in fluid communication with the first passage at a position upstream of the mixing chamber (37) and wherein a shield (32) is fixed to the first passage (26) surrounding the nozzle.
摘要翻译：喷嘴歧管（25）包括用于供应雾化气体的第一同轴通道（26），存在于所述第一通道中的用于供应液体的多个横向间隔开的喷嘴（16）的第二同轴通道（27）用于在远离所述歧管（25）的纵向轴线的方向上雾化和喷射液体，所述喷嘴附接到所述第一通道，所述喷嘴具有流体连接到所述第二通道（27）的液体入口，用于雾化气体流体连接到第一通道（26），其中雾化气体和液体混合的混合室（37）和用于雾化气体和液体的混合物的出口（24），其中喷嘴具有用于排放雾化的开口（33）气体，其在所述混合室（37）的上游位置处与所述第一通道流体连通，并且其中，围绕所述喷嘴的所述第一通道（26）固定有屏蔽件（32）。

6. 发明申请

WO2010072424A1 PROCESS TO PREPARE METHANOL AND/OR DIMETHYLETHER 审中-公开
标题翻译：制备甲醇和/或二甲醚的方法
公开(公告)号：WO2010072424A1
公开(公告)日：2010-07-01
申请号：PCT/EP2009/050424
申请日：2009-01-15
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , CHEWTER, Leslie Andrew , VAN WESTRENEN, Jeroen , WINTER, Ferry
发明人： VAN DEN BERG, Robert , CHEWTER, Leslie Andrew , VAN WESTRENEN, Jeroen , WINTER, Ferry
IPC分类号： C07C29/151 , C07C41/01 , C07C1/20 , C07C11/02 , C10J3/48 , C10J3/82
CPC分类号： C07C29/1518 , C01B3/12 , C01B3/52 , C01B2203/0415 , C01B2203/047 , C01B2203/0475 , C01B2203/0485 , C01B2203/0495 , C07C1/20 , C07C11/02 , C07C41/01 , C10G3/49 , C10G2300/202 , C10G2300/4081 , C10G2400/02 , C10G2400/20 , C10G2400/22 , C10J3/485 , C10J3/526 , C10J3/84 , C10J3/845 , C10J2200/09 , C10J2200/152 , C10J2300/0959 , C10J2300/1634 , C10J2300/1665 , C10J2300/1678 , C10J2300/1846 , C10K1/002 , C10K1/004 , C10K1/005 , C10K1/006 , C10K1/10 , C10K1/101 , C10K1/143 , C10K1/16 , C07C31/04 , C07C43/043
摘要： Process to prepare methanol and/or dimethylether from a solid carbonaceous feedstock by performing the steps of (a) feeding an oxygen comprising gas and the carbonaceous feedstock to a burner firing into a reactor vessel, (b) performing a partial oxidation of the carbonaceous feedstock in said burner to obtain a stream of hot synthesis gas and a liquid slag whereby both gas and slag flow downwardly relative to the burner, (c) cooling the hot synthesis gas by direct contacting with a liquid water-containing cooling medium, (d) performing a water shift reaction on at least part of the synthesis gas, to obtain a synthesis gas effluent, (e) performing an oxygenate synthesis using the synthesis gas effluent of step (d), to obtain a methanol and/or dimethylether containing oxygenate effluent and a first liquid water-rich by-product, wherein at least part of the first liquid water-rich by-product is used in step c), forming at least part of the liquid water-containing cooling medium.
摘要翻译：由固体碳质原料制备甲醇和/或二甲醚的方法，该方法是通过以下步骤进行：（a）将含氧气体和含碳原料进料到燃烧器中进行烧成反应器，（b）进行含碳原料的部分氧化在所述燃烧器中获得热合成气流和液体渣，由此气体和炉渣相对于燃烧器向下流动，（c）通过与含液体水的冷却介质直接接触来冷却热合成气，（d）在至少部分合成气体上进行水位转换反应，以获得合成气流出物，（e）使用步骤（d）的合成气流出物进行含氧化合物合成，得到含有氧化合物流出物的甲醇和/或二甲醚和第一液体富水副产物，其中在步骤c）中使用至少部分第一液体富含水的副产物，形成至少部分含液体的含水冷却介质。

7. 发明申请

WO2009030674A2 QUENCHING VESSEL 审中-公开
公开(公告)号：WO2009030674A2
公开(公告)日：2009-03-12
申请号：PCT/EP2008/061524
申请日：2008-09-04
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , VAN DEN BERG, Robert , HARTEVELD, Wouter Koen , HEINEN, Hans Joachim , VON KOSSAK-GLOWCZEWSKI, Thomas Paul
发明人： VAN DEN BERG, Robert , HARTEVELD, Wouter Koen , HEINEN, Hans Joachim , VON KOSSAK-GLOWCZEWSKI, Thomas Paul
IPC分类号： C10J3/84 , B01D47/06 , B01D53/00
CPC分类号： F28C3/08 , C10J3/526 , C10J3/84 , C10J3/845 , C10J2200/152 , C10K1/06 , C10K1/10 , C10K1/101 , C10K1/16 , F28G1/00 , Y02E20/18 , Y10T428/23986 , Y10T442/2672
摘要： Quenching vessel being, in use, vertically elongated and provided with an inlet for gas at its upper end, an outlet for cooled gas at its lower end defining a pathway for a gas flow directed downwardly, the vessel being provided at its upper end with a first internal tubular wall part which wall part has an opening fluidly connected to the inlet for gas and wherein tubular wall part is connected at its lower end with a divergent conical part having walls which are inclined outwardly in the direction of the pathway for gas, wherein an arrangement of more than one nozzles for atomisation and spraying a liquid quench medium in a downward direction into the pathway for the gas flow are present in the space enclosed by the divergent conical part.
摘要翻译：淬火容器在使用中垂直伸长并在其上端设置有气体入口，其下端处的冷却气体出口限定用于向下指向的气流的路径，该容器在其上端设置有第一内部管状壁部分，该壁部分具有与气体入口流体连接的开口，并且其中管状壁部分在其下端与分开的圆锥形部分连接，该锥形部分具有沿气体通路的方向向外倾斜的壁，其中在由发散锥形部分包围的空间中存在用于雾化的多于一个喷嘴和向下方向喷射液体骤冷介质用于气流的路径的布置。

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