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1. 发明申请

WO2006125801A1 PROCESS FOR THE PREPARATION OF ADIPIC ACID FROM N-PENTENOIC ACID 审中-公开
标题翻译：从N-硝基酸制备丙二酸的方法
公开(公告)号：WO2006125801A1
公开(公告)日：2006-11-30
申请号：PCT/EP2006/062590
申请日：2006-05-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , ERNST, Rene , JAGER, Willem Wabe , KROM, Cornelia Alida , NISBET, Timothy Michael , VAN BROEKHOVEN, Johannes Adrianus Maria
发明人： DRENT, Eit , ERNST, Rene , JAGER, Willem Wabe , KROM, Cornelia Alida , NISBET, Timothy Michael , VAN BROEKHOVEN, Johannes Adrianus Maria
IPC分类号： C07C51/14 , C07C51/42 , C07C51/43 , C07C55/14 , B01J23/44
CPC分类号： B01J31/2404 , B01J2231/321 , B01J2531/0238 , B01J2531/824 , C07C51/14 , C07C51/43 , C07C55/14
摘要： A process for the preparation of adipic acid from n-pentenoic acid, comprising the steps of (a) contacting the n-pentenoic acid with carbon monoxide and water in the presence of a catalyst system including a source of palladium and a bidentate diphosphine ligand, to obtain a reaction mixture comprising adipic acid, n-pentenoic acid, and catalyst system; and (b) subjecting the reaction mixture to conditions under which adipic acid precipitates from the reaction mixture to obtain precipitated adipic acid and remaining liquid reaction mixture comprising at least part of the n-pentenoic acid in admixture with the catalyst system; and (c) separating the precipitated adipic acid from the remaining liquid reaction mixture comprising at least part of the n-pentenoic acid in admixture with the catalyst system to obtain separated off adipic acid; and (d) washing the separated off adipic acid with n-pentenoic acid and/or water.
摘要翻译：一种从正戊烯酸制备己二酸的方法，包括以下步骤：（a）在包括钯源和二齿二膦配体的催化剂体系的存在下使正戊烯酸与一氧化碳和水接触，得到包含己二酸，正戊烯酸和催化剂体系的反应混合物; 和（b）使反应混合物经历从反应混合物中沉淀己二酸的条件，以获得沉淀的己二酸和包含至少部分正戊烯酸的剩余液体反应混合物与催化剂体系的混合物; 和（c）将沉淀的己二酸与包含至少部分正戊烯酸的剩余液体反应混合物与催化剂体系混合分离以获得分离的己二酸; 和（d）用正戊烯酸和/或水洗涤分离的己二酸。

2. 发明申请

WO2006084890A2 PROCESS FOR THE PREPARATION OF A DICARBOXYLIC ACID 审中-公开
标题翻译：制备二羧酸的方法
公开(公告)号：WO2006084890A2
公开(公告)日：2006-08-17
申请号：PCT/EP2006/050824
申请日：2006-02-10
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , ERNST, Rene , JAGER, Willem Wabe , KROM, Cornelia Alida
发明人： DRENT, Eit , ERNST, Rene , JAGER, Willem Wabe , KROM, Cornelia Alida
IPC分类号： C07C51/14 , C07C55/14 , C07C51/43
CPC分类号： C08G69/28 , C07C51/14 , C07C51/43 , Y02P20/584 , C07C55/14
摘要： A process for the preparation of a dicarboxylic acid, comprising the steps of (a) contacting a conjugated diene with carbon monoxide and water in the presence of a catalyst system including a source of palladium, a source of an anion and a bidentate phosphine ligand, to obtain a mixture comprising an ethylenically unsaturated acid product; (b) reacting the mixture obtained in step (a) further with carbon monoxide and water to obtain the dicarboxylic acid in admixture with the ethylenically unsaturated acid; (c) separating the dicarboxylic acid from a liquid filtrate comprising the catalyst system; and (d) recycling at least part of the obtained liquid filtrate to step (a).
摘要翻译：一种制备二羧酸的方法，包括以下步骤：（a）在包括钯源，阴离子源和二齿膦配体的催化剂体系的存在下，使共轭二烯与一氧化碳和水接触，以获得包含烯属不饱和酸产物的混合物; （b）使步骤（a）中得到的混合物进一步与一氧化碳和水反应，得到与烯属不饱和酸混合的二羧酸; （c）从包含催化剂体系的液体滤液中分离二羧酸; 和（d）将至少部分获得的液体滤液再循环到步骤（a）。

3. 发明申请

WO2004103942A1 PROCESS FOR THE HYDROCARBOXYLATION OF ETHYLENICALLY UNSATURATED CARBOXYLIC ACIDS 审中-公开
标题翻译：乙酰化不饱和羧酸的碳氢化合物的方法
公开(公告)号：WO2004103942A1
公开(公告)日：2004-12-02
申请号：PCT/EP2004/050820
申请日：2004-05-17
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN GINKEL, Roelof , JAGER, Willem Wabe
发明人： DRENT, Eit , VAN GINKEL, Roelof , JAGER, Willem Wabe
IPC分类号： C07C51/14
CPC分类号： C07C51/14 , C07C55/14
摘要： A process for the hydrocarboxylation of an ethylenically unsaturated carboxylic acid, by reacting it with carbon monoxide and a co-reactant selected from the group of water and carboxylic acids in the presence of a catalyst system including: (a) a source of palladium; (b) a bidentate diphosphine of formula (I), R 1 R 2 > P - R 3 - R - R 4 - P 5 R 6 (I) wherein P represents a phosphorus atom; R 1 , R 2 , R 5 and R 6 independently represent the same or different optionally substituted organic groups containing a tertiary carbon atom through which the group is linked to the phosphorus atom; R 3 and R 4 independently represent optionally substituted alkylene groups and R represents an optionally substituted aromatic group; (c) a source of anions derived from an acid having a pKa of less than 3, as measured at 18 °C in an aqueous solution.
摘要翻译：在催化剂体系存在下，通过使其与一氧化碳和选自水和羧酸的共反应物反应，使烯属不饱和羧酸的氢化羧化的方法包括：（a）钯源; （b）式（I）的二齿二膦，R 1 R 2 P-R 3 -R-R 4 - P

4. 发明申请

WO2008034894A1 PROCESS FOR PRODUCING OLEFINS 审中-公开
标题翻译：生产油脂的方法
公开(公告)号：WO2008034894A1
公开(公告)日：2008-03-27
申请号：PCT/EP2007/060030
申请日：2007-09-21
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , VAN GINKEL, Roelof , JAGER, Willem Wabe
发明人： DRENT, Eit , VAN GINKEL, Roelof , JAGER, Willem Wabe
IPC分类号： C07C1/24 , C07C29/16 , B01J31/24
CPC分类号： C07F9/65683 , B01J31/2419 , B01J2231/321 , B01J2531/845 , C07C1/24 , C07C29/16 , C07C11/02 , C07C31/125
摘要： Process for converting an olefin having x carbon atoms into an olefin having x+1 carbon atoms wherein the process comprises the steps of : (i) reacting an olefin having x carbon atoms with carbon monoxide and hydrogen in the presence of a hydrof ormylation catalyst to produce an alcohol having x+1 carbon atoms, and (ii) dehydrating the alcohol produced in step (i) in the presence of a dehydration catalyst to produce an olefin having x+1 carbon atoms characterised in that the the hydrof ormylation catalyst used in step (i) is based on: (a) a source of cobalt, and (b) a ligand selected from: (i) a ligand of general formula (I) : R 1 R 2 P-R 3 (I) wherein R 1 and R 2 are independently a hydrocarbyl group with C 1 -C 12 carbon atoms or together with the phosphorus atom P represent an optionally substituted cyclic group with at least 5 ring atoms; and wherein R 3 is a monovalent radical of general formula: -R 4 -C (O) NR 5 R 6 (II) wherein R 4 is an alkylene group and R 5 and R 6 independently represent an alkyl, cycloalkyl, aryl, alkaryl or heteroaryl group; (ii) a ligand of general formula (III) : R 1 R 2 P-R 4 -C(O)N(R 7 ) -R 8 -N(R 7 ) C(O) -R 4 PR 1 R 2 (III) wherein R 1 , R 2 and R 4 are as defined above, wherein R 7 independently represents an alkyl, cycloalkyl, aryl, alkaryl or heteroaryl group, and wherein R 8 represents an alkylene, cycloalkylene, arylene or alkarylene group; and (iii) a ligand of general formula (IV) : R 1 R 2 P-R 4 -C (O) N- (R 8 ) 2 -NC (O) -R 4 -PR 1 R 2 (IV) wherein R 1 , R 2 , R 4 and R 8 are as defined above; and mixtures thereof.
摘要翻译：将具有x个碳原子的烯烃转化为具有x + 1个碳原子的烯烃的方法，其中该方法包括以下步骤：（i）在氢化甲酰化催化剂存在下使具有x个碳原子的烯烃与一氧化碳和氢气反应，产生具有x + 1个碳原子的醇，和（ii）在脱水催化剂存在下使步骤（i）中产生的醇脱水以产生具有x + 1个碳原子的烯烃，其特征在于所用的氢化甲酰化催化剂步骤（i）基于：（a）钴源，和（b）选自以下的配体：（i）通式（I）的配体：R 1，其中R 1和R 2独立地是具有C 1〜C的烃基，其中R 1，R 2， C 1 -C 12碳原子或与磷原子一起P表示具有至少5个环原子的任选取代的环状基团; 并且其中R 3是通式的一价基团：-R 4 -S（O）NR 5 R 6，其中R 4为亚烷基且R 5和R 6独立地代表烷基，环烷基，芳基，烷芳基或杂芳基; （ii）通式（III）的配体：R 1，R 2，R 4，C（O）N（R） 7（R 7）-R 8 - （R 7）C（O）-R 4 PR 1，其中R 1，R 2和R 4如上所定义，其中R 1，R 2，R 2， R 7独立地表示烷基，环烷基，芳基，烷芳基或杂芳基，其中R 8表示亚烷基，亚环烷基，亚芳基或亚烷基; 和（iii）通式（IV）的配体：R 1，R 2，R 4，-C（O） SUP> 8）2 -NO（O）-R 4 - PR 1 R 2 - （Ⅳ）其中R 1，R 2，R 4和R 8如上所定义; 及其混合物。

5. 发明申请

WO2005082830A1 PROCESS FOR THE CARBONYLATION OF ETHYLENICALLY OR ACETYLENICALLY UNSATURATED COMPOUNDS 审中-公开
标题翻译：亚乙基或乙酰化不饱和化合物的羰基化方法
公开(公告)号：WO2005082830A1
公开(公告)日：2005-09-09
申请号：PCT/EP2005/050803
申请日：2005-02-25
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , ERNST, René , JAGER, Willem Wabe , PUGH, Robert Ian
发明人： DRENT, Eit , ERNST, René , JAGER, Willem Wabe , PUGH, Robert Ian
IPC分类号： C07C67/38
CPC分类号： B01J31/2409 , B01J2231/321 , B01J2531/824 , B01J2531/828 , C07C51/14 , C07C67/38 , C07F9/65522 , C07F9/65683 , C07C55/14 , C07C69/24
摘要： A process for the carbonylation of unsaturated compounds by contacting the unsaturated compound with carbon monoxide in the presence of a catalyst system comprising: (a) a source of palladium and/or platinum; and (e) an unsymmetrical bidentate diphosphine ligand of formula (I), R 1 R 2 > P 1 - R 3 - P 2 4 R 5 (I) wherein P 1 andp P 2 represent phosphorus atoms; R 3 represents a divalent organic bridging group; and R 1 , R 2 , R 4 and R 5 each individually, or R l and R 2 jointly, and/or R 4 and R 5 jointly represent organic groups that are covalently linked to the phosphorus; and wherein R 1 , R 2 , R 4 and R 5 are chosen in such way, that the phosphino group R 1 R 2 > P 1 differs from the phosphino group P 2 4 R 5 .
摘要翻译：在催化剂体系存在下使不饱和化合物与一氧化碳接触，使不饱和化合物羰基化的方法包括：（a）钯和/或铂的来源; 和（e）式（I）的不对称二齿二膦配体，R 1 R 2，P 1 -R 3，P 2，R 4 R 5（I）其中P 1和P 2表示磷原子; R 3表示二价有机桥基; R 1，R 2，R 4和R 5各自独立地为R 1和R 2共同表示，和/或R 4和R 5共同表示有机与磷共价连接的基团; 并且其中R 1，R 2，R 4和R 5以这样的方式选择，即膦基R 1，R 2，P 1不同于膦基P <2>

6. 发明申请

WO2005082829A1 PROCESS FOR THE CARBONYLATION OF A CONJUGATED DIENE 审中-公开
标题翻译：联合二烯的羰基化方法
公开(公告)号：WO2005082829A1
公开(公告)日：2005-09-09
申请号：PCT/EP2005/050790
申请日：2005-02-24
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. , DRENT, Eit , JAGER, Willem Wabe , PRINGLE, Paul Gerard
发明人： DRENT, Eit , JAGER, Willem Wabe , PRINGLE, Paul Gerard
IPC分类号： C07C67/38
CPC分类号： C07C67/38 , C07C69/533
摘要： A process for the carbonylation of a conjugated diene, comprising reacting the conjugated diene with carbon monoxide and a co-reactant having an active hydrogen atom in the presence of a catalyst system including: (a) a source of palladium; and (b) a bidentate diphosphine ligand of formula (II): R 1 > P 1 -R- P 2 2 R 3 wherein P 1 and p2 represent phosphorus atoms; R 1 represents an optionally substituted divalent organic group linked to the phosphorus atom by two tertiary carbon atoms; and R 2 and R 3 independently represent univalent groups of from 1 to 20 atoms containing a tertiary carbon atom through which each group is linked to the phosphorus atom, or R 2 and R 3 jointly form an optionally substituted divalent organic group containing at least 2 tertiary carbon atoms through which the group is linked to the phosphorus atom; and R represents a divalent bridging group comprising 3 atoms through which P 1 is linearly connected to P 2 ;and (c) a source of an anion.
摘要翻译：一种共轭二烯的羰基化方法，包括使共轭二烯与一氧化碳和具有活性氢原子的共反应物在催化剂体系存在下反应，所述催化剂体系包括：（a）钯源; 和（b）式（II）的二齿二膦配体：R 1，P 1 -R 2，P 2，R 2 R 3，其中P 1和P 2表示磷原子; R 1表示通过两个叔碳原子与磷原子连接的任选取代的二价有机基团; R 2和R 3独立地表示含有每个基团与磷原子连接的叔碳原子的1至20个原子的一价基团，或者R 2和R 3共同形成任选的含有至少2个叔碳原子的取代的二价有机基团，该基团通过其与磷原子连接; 并且R表示包含3个原子的二价桥连基团，P 1与P 2线性连接;和（c）阴离子源。

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