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    • 3. 发明申请
    • STYRENE-ISOPRENE-STYRENE TRI BLOCK COPOLYMERS WITH ADAPTED DIBLOCK COPOLYMERS
    • 苯乙烯 - 苯乙烯 - 苯乙烯三嵌段共聚物与适应的二嵌段共聚物
    • WO1997039076A1
    • 1997-10-23
    • PCT/EP1997001906
    • 1997-04-15
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
    • SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.GERARD, Eric-JackDE KEYZER, Noël, Raymond, MauriceMENSEN-VEURINK, Jacqueline, MargarethaVAN DE VLIET, Birgitte, Maria, Ludovica, Christine
    • C09J153/02
    • C09J153/02C08L2666/02Y02P20/582
    • Hot melt adhesive compositions comprising: (a,1) from 75-90 parts by weight of a triblock copolymer A1B1A2 where A1 and A2 represent predominantly poly(monovinyl aromatic) blocks of the same or different peak molecular weight in the range of from 5,000 to 20,000 g/mol, wherein B1 represents a predominantly poly(isoprene) block while the average apparent molecular weight of the total triblock copolymer is in the range of from 160,000 to 250,000 g/mol, and the monovinyl aromatic monomer content is in the range of from 15 to 25 wt.%; (a,2) from 10 to 25 parts by weight of a diblock copolymer A3B2, wherein A3 represents a predominantly poly(monovinyl aromatic) block having a peak molecular weight in the range of from 5,000 to 20,000 g/mol, and wherein B2 represents a poly(isoprene) block having an average apparent molecular weight calculated from GPC measurements which is from 80 to 110 % of the average molecular weight calculated from GPC measurements of block B1, and wherein the monovinyl aromatic monomer content is in the range of from 5 to 17 %; (b) from 50 to 400 parts by weight of a tackifying resin; (c) from 0 to 100 parts by weight of a plasticiser and/or softening agent.
    • 热熔粘合剂组合物,其包含:(a,1)75-90重量份的三嵌段共聚物A1B1A2,其中A1和A2主要表示具有相同或不同峰分子量的聚(单乙烯基芳族)嵌段,其范围为5,000至 20,000g / mol,其中B1表示主要是聚(异戊二烯)嵌段,而总三嵌段共聚物的平均表观分子量在160,000至250,000g / mol的范围内,单乙烯基芳族单体含量在 15至25重量%; (a,2)10〜25重量份的二嵌段共聚物A3B2,其中A3表示主要为聚(单乙烯基芳族)嵌段,其峰分子量为5,000〜20,000g / mol,其中B2表示 由GPC测量得到的平均表观分子量为根据块B1的GPC测量计算的平均分子量的80至110%的聚(异戊二烯)嵌段,其中单乙烯基芳族单体含量为5 至17%; (b)50〜400重量份的增粘树脂; (c)0至100重量份的增塑剂和/或软化剂。