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1. 发明申请

WO2011119778A3 METHOD FOR IN-SITU FORMATION OF METATHESIS CATALYSTS 审中-公开
公开(公告)号：WO2011119778A3
公开(公告)日：2011-09-29
申请号：PCT/US2011/029690
申请日：2011-03-24
申请人： SCHRODI, Yann
发明人： SCHRODI, Yann
IPC分类号： C07F15/00 , C07F19/00 , B01J31/16 , C07C6/04
摘要： Synthetic methods for the in-situ formation of olefin metathesis catalysts are disclosed, as well as the use of such catalysts in metathesis reactions of olefins and olefin compounds. In one aspect, a method is provided for synthesizing an organometallic compound of the formula (I); comprising contacting a precursor compound of the formula (X 1 X 2 ML j L 1 k L 3 m ) i with an acetylenic compound of the formula comprising a chelating moiety, optionally, in the presence of a neutral electron donor, wherein M is a Group 8 transition metal, L, L 1 , L 2 , and L 3 are neutral electron donors, X 1 and X 2 are anionic ligands, j is 1, 2, or 3; k is zero, 1, or 2; m is zero or 1; n is 1 or 2; and i is an integer; with the proviso that k is zero when the precursor compound is contacted with the acetylenic compound in the presence of the neutral electron donor, and R 1 and R 2 are independently selected from hydrocarbyl, substituted hydrocarbyl, heteroatom-containing hydrocarbyl, substituted heteroatom-containing hydrocarbyl, and functional groups, wherein R1 and R2 are linked and together form one or more cyclic groups, R 2 and L 2 are linked and together form one or more cyclic groups, and any other two or more of X 1 , X 2 , L 1 , L 2 , L 3 , R 1 , and R 2 can be taken together to form one or more cyclic groups. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and industrial and fine chemicals chemistry.

2. 发明申请

WO2008048522A1 METHODS OF MAKING MONOUNSATURATED FUNCTIONALIZED ALKENE COMPOUNDS BY METATHESIS 审中-公开
标题翻译：通过METATHESIS制备单烷基官能化亚烷基化合物的方法
公开(公告)号：WO2008048522A1
公开(公告)日：2008-04-24
申请号：PCT/US2007/021939
申请日：2007-10-15
申请人： CARGILL, INCORPORATED , MATERIA, INCORPORATED , ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard, L. , SCHRODI, Yann , TUPY, Michael, John
发明人： ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard, L. , SCHRODI, Yann , TUPY, Michael, John
IPC分类号： C07C11/02 , C07C11/00
CPC分类号： C07C6/04 , C07C51/353 , C07C67/333 , C07C2531/22 , C07C2531/24 , Y02P20/127 , C07C11/08 , C07C57/03 , C07C69/533
摘要： Described is a method of chemically modifying a starting composition comprising polyunsaturated alkene compounds in order to convert at least a portion of the polyunsaturated alkene compounds into functionalized monounsaturated alkene compounds. The separated monounsaturated alkene compounds may be useful, for example, as a starting material in the synthesis of organic chemicals such as diacids, diesters, and the like.
摘要翻译：描述了一种化学改性包含多不饱和烯烃化合物的起始组合物以将至少一部分多不饱和烯烃化合物转化为官能化单不饱和烯烃化合物的方法。分离的单不饱和烯烃化合物可用作例如合成有机化学品如二酸，二酯等的起始原料。

3. 发明申请

WO2008046106A2 SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES VIA OLEFIN METATHESIS 审中-公开
标题翻译：通过烯醇化合物从内部碱基合成终端碱
公开(公告)号：WO2008046106A2
公开(公告)日：2008-04-17
申请号：PCT/US2007/081427
申请日：2007-10-15
申请人： MATERIA, INC. , SCHRODI, Yann , PEDERSON, Richard, L. , KAIDO, Hiroki , TUPY, Michael, J.
发明人： SCHRODI, Yann , PEDERSON, Richard, L. , KAIDO, Hiroki , TUPY, Michael, J.
IPC分类号： C07C67/347
CPC分类号： B01J31/2278 , B01J2231/54 , B01J2531/821 , C07C6/04 , C07C67/333 , C07C67/475 , C07C2531/22 , C07C2531/24 , C07C11/02 , C07C69/533 , C07C69/73
摘要： This disclosure relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by an olefin metathesis catalyst. According to one aspect, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting, in the presence of a ruthenium alkylidene metathesis catalyst, an olefinic substrate comprised of at least one internal olefin with a cross metathesis partner comprised of an alpha olefinic reactant, under reaction conditions effective to allow cross-metathesis to occur, wherein the reaction conditions include a reaction temperature of at least 35 °C. The methods, compositions, reactions and reaction systems herein disclosed have utility in the fields of catalysis, organic synthesis, and industrial chemistry.
摘要翻译：本公开一般涉及烯烃复分解，更具体地涉及使用由烯烃复分解催化剂催化的交叉复分解反应从内部烯烃合成末端烯烃。根据一个方面，例如，提供了一种用于合成末端烯烃的方法，所述方法包括在钌亚烷基复分解催化剂存在下使由至少一种内烯烃组成的烯属基材与由在有效允许发生交叉复分解的反应条件下，α烯烃反应物，其中反应条件包括至少35℃的反应温度。本文公开的方法，组合物，反应和反应体系可用于催化，有机合成和工业化学领域。

4. 发明申请

WO2008048520A2 METHODS OF MAKING ORGANIC COMPOUNDS BY METATHESIS AND HYDROCYANATION 审中-公开
标题翻译：通过元素分解和氢化作用制备有机化合物的方法
公开(公告)号：WO2008048520A2
公开(公告)日：2008-04-24
申请号：PCT/US2007/021931
申请日：2007-10-15
申请人： CARGILL, INCORPORATED , MATERIA, INCORPORATED , PLETNEV, Alexandre, A. , ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard, L. , SCHRODI, Yann , TUPY, Michael, John
发明人： ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard, L. , SCHRODI, Yann , TUPY, Michael, John
IPC分类号： C07C55/00 , C07C55/02 , C07C51/00 , C07C67/00
CPC分类号： C07C253/10 , B01J31/2265 , B01J31/2278 , B01J2231/54 , B01J2531/821 , C07C6/04 , C07C45/44 , C07C51/08 , C07C51/353 , C07C67/08 , C07C67/31 , C07C67/313 , C07C67/333 , C07C67/347 , C07C227/04 , C07C227/10 , C07C2531/24 , C11C3/04 , Y02P20/127 , C07C57/03 , C07C57/42 , C07C59/01 , C07C59/325 , C07C69/533 , C07C229/08 , C07C255/19
摘要： The invention is directed to methods of making organic compounds by metathesis and hydrocyanation. The method of the invention may be used, for example, to make industrial important organic compounds such as diacids, diesters, acid-amines, acid-alcohols, acid-nitriles, ester-amines, ester-alcohols, and ester-nitriles.
摘要翻译：本发明涉及通过复分解和氢氰化制备有机化合物的方法。例如，可以使用本发明的方法来制备工业上重要的有机化合物，例如二酸，二酯，酸胺，酸 - 醇，酸 - 腈，酯 - 胺，酯 - 醇和酯 - 腈。 / p>

5. 发明申请

WO2008010961A2 SYNTHESIS OF TERMINAL ALKENES FROM INTERNAL ALKENES AND ETHYLENE VIA OLEFIN METATHESIS 审中-公开
标题翻译：通过烯烃组合从内部烯烃和乙烯合成终端碱
公开(公告)号：WO2008010961A2
公开(公告)日：2008-01-24
申请号：PCT/US2007/016010
申请日：2007-07-13
申请人： MATERIA, INC. , SCHRODI, Yann
发明人： SCHRODI, Yann
IPC分类号： H04N7/14 , H04N7/16 , H04N7/167 , H04N7/173
CPC分类号： C07C6/04 , B01J31/12 , B01J31/2265 , B01J2231/543 , B01J2531/821 , C07C67/333 , C07C2531/18 , C07C2531/22 , C07C2531/24 , C07C2531/28 , C07F15/0046 , C07C11/02 , C07C69/533
摘要： This invention relates generally to olefin metathesis, and more particularly relates to the synthesis of terminal alkenes from internal alkenes using a cross-metathesis reaction catalyzed by a selected olefin metathesis catalyst. In one embodiment of the invention, for example, a method is provided for synthesizing a terminal olefin, the method comprising contacting an olefinic substrate comprised of at least one internal olefin with ethylene, in the presence of a metathesis catalyst, wherein the catalyst is present in an amount that is less than about 1000 ppm relative to the olefinic substrate, and wherein the metathesis catalyst has the structure of formula (II), wherein the various substituents are as defined herein. The invention has utility, for example, in the fields of catalysis, organic synthesis, and industrial chemistry.
摘要翻译：本发明一般涉及烯烃复分解，更具体地涉及使用由选定的烯烃复分解催化剂催化的交叉复分解反应从内部烯烃合成末端烯烃。在本发明的一个实施方案中，例如，提供了一种用于合成末端烯烃的方法，该方法包括在复分解催化剂存在下将由至少一种内烯烃组成的烯属基材与乙烯接触，其中存在催化剂其量相对于烯属底物小于约1000ppm，并且其中复分解催化剂具有式（II）的结构，其中各种取代基如本文所定义。本发明可用于例如催化，有机合成和工业化学领域。

6. 发明申请

WO2008140469A3 ANTIMICROBIAL COMPOSITIONS, METHODS AND SYSTEMS 审中-公开
公开(公告)号：WO2008140469A3
公开(公告)日：2008-11-20
申请号：PCT/US2007/021941
申请日：2007-10-15
申请人： ELEVANCE RENEWABLE SCIENCES, INC. , DE SOUZA, Mervyn, L. , ZULLO, Jill,, Louise , ANDERSON, James, C. , PEDERSON, Richard,, L. , SCHRODI, Yann
发明人： DE SOUZA, Mervyn, L. , ZULLO, Jill,, Louise , ANDERSON, James, C. , PEDERSON, Richard,, L. , SCHRODI, Yann
IPC分类号： A01N37/00 , A01N43/16
摘要： Antimicrobial compositions comprising a combination of a first antimicrobial agent of Formula I and a second antimicrobial agent of Formula IV are reported. The antimicrobial compositions including a combination of antimicrobial agents of Formula (I) and Formula (IV) are effective as an antimicrobial agent with MIC levels of about 0.1% or less against certain fungi. Also reported are antimicrobial products such as consumer products, industrial preparations, and food and feed formulations.

7. 发明申请

WO2008060383A2 METHODS OF MAKING ORGANIC ACID AND ORGANIC ALDEHYDE COMPOUNDS BY METATHESIS 审中-公开
标题翻译：通过METATHESIS制备有机酸和有机醛类化合物的方法
公开(公告)号：WO2008060383A2
公开(公告)日：2008-05-22
申请号：PCT/US2007/021935
申请日：2007-10-15
申请人： CARGILL, INCORPORATED , MATERIA, INCORPORATED , ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard, L. , SCHRODI, Yann , TUPY, Michael, John , UPTAIN, Kevin, D.
发明人： ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard, L. , SCHRODI, Yann , TUPY, Michael, John , UPTAIN, Kevin, D.
CPC分类号： C07C51/34 , C07C51/353 , C07C55/14 , C07C55/18 , C07C55/12 , C07C55/02 , C07C57/03
摘要： The invention is directed to methods of making organic compounds (e.g., organic acid or aldehyde compounds) by metathesis followed by oxidation and either oxidative or reductive cleavage. The methods may be used to make certain industrially important organic acid compounds, for example, azelaic acid. The methods of the invention make use of a cross-metathesis step with a short-chain olefin to chemically modify the starting composition in order to produce a functionalized alkene intermediate that has a pre-determined carbon-carbon double bond position. Upon separation of the functionalized alkene intermediate from the other cross-metathesis products, it is oxidized and then may be oxidatively cleaved to form an organic acid or reductively cleaved to form an aldehyde.
摘要翻译：本发明涉及通过复分解，然后氧化和氧化还原性裂解制备有机化合物（例如有机酸或醛化合物）的方法。该方法可用于制备某些工业上重要的有机酸化合物，例如壬二酸。本发明的方法利用具有短链烯烃的交叉复分解步骤来化学改性起始组合物，以便制备具有预定碳 - 碳双键位置的官能化烯烃中间体。在将官能化烯烃中间体与其它交叉复分解产物分离后，将其氧化，然后氧化裂解形成有机酸或还原性裂解形成醛。

8. 发明申请

WO2007075427A1 ORGANOMETALLIC RUTHENIUM COMPLEXES AND RELATED METHODS FOR THE PREPARATION OF TETRA-SUBSTITUTED AND OTHER HINDERED OLEFINS 审中-公开
标题翻译：有机金属配合物及相关方法制备四氯化钛和其他有关的烯烃
公开(公告)号：WO2007075427A1
公开(公告)日：2007-07-05
申请号：PCT/US2006/047934
申请日：2006-12-18
申请人： MATERIA, INC. , CALIFORNIA INSTITUTE OF TECHNOLOGY , BERLIN, Jacob , GRUBBS, Robert, H. , SCHRODI, Yann , STEWARD, Ian, C.
发明人： BERLIN, Jacob , GRUBBS, Robert, H. , SCHRODI, Yann , STEWARD, Ian, C.
IPC分类号： C07F15/00 , B01J31/22 , C08G61/08
CPC分类号： C07F15/0046 , B01J31/2265 , B01J31/2404 , B01J2231/543 , B01J2531/821 , C08G61/08
摘要： The invention relates to ruthenium alkylidene complexes having an N-heterocyclic carbene ligand comprising a 5-membered heterocyclic ring having a carbenic carbon atom and at least one nitrogen atom contained within the 5-membered heterocyclic ring, wherein the nitrogen atom is directly attached to the carbenic carbon atom and is substituted by a phenyl ring, and wherein the phenyl ring has a hydrogen at either or both ortho positions and is substituted and at least one orthq or meta position. The invention also relates to an olefin metathesis reactions and particularly to the preparation of tetra-substituted cyclic olefins via a ring-closing metathesis.
摘要翻译：本发明涉及具有N-杂环卡宾配体的钌亚烷基配合物，其包括具有碳原子数为5元的五元杂环和至少一个含有5元杂环的氮原子，其中氮原子直接连接到碳原子并被苯环取代，并且其中所述苯环在一个或两个邻位具有氢，并且被取代和至少一个直链或间位。本发明还涉及烯烃复分解反应，特别涉及通过闭环复分解制备四取代环烯烃。

9. 发明申请

WO2008140468A2 METHODS OF MAKING ORGANIC COMPOUNDS BY METATHESIS 审中-公开
标题翻译：通过METATHESIS制备有机化合物的方法
公开(公告)号：WO2008140468A2
公开(公告)日：2008-11-20
申请号：PCT/US2007/021933
申请日：2007-10-15
申请人： ELEVANCE RENEWABLE SCIENCES, INC. , ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard,, L. , SCHRODI, Yann , TUPY, Michael, John
发明人： ABRAHAM, Timothy, W. , KAIDO, Hiroki , LEE, Choon, Woo , PEDERSON, Richard,, L. , SCHRODI, Yann , TUPY, Michael, John
IPC分类号： C07C6/02 , C07C67/38 , C07C69/34 , B01J19/00
CPC分类号： C07C67/475 , B01J31/2265 , B01J31/2278 , B01J2231/543 , B01J2531/821 , C07C6/04 , C07C67/02 , C07C67/303 , C07C67/307 , C07C67/31 , C07C67/333 , C07C2531/22 , C07C2531/24 , C07F7/1884 , C07C11/02 , C07C69/65 , C07C69/734 , C07C69/533 , C07C69/593 , C07C69/73
摘要： Described are methods of making organic compounds by metathesis chemistry. The methods of the invention are particularly useful for making industrially-important organic compounds beginning with starting compositions derived from renewable feedstocks, such as natural oils. The methods make use of a cross-metathesis step with an olefin compound to produce functionalized alkene intermediates having a pre-determined double bond position. Once isolated, the functionalized alkene intermediate can be self-metathesized or cross-metathesized (e.g., with a second functionalized alkene) to produce the desired organic compound or a precursor thereto. The method may be used to make bifunctional organic compounds, such as diacids, diesters, dicarboxylate salts, acid/esters, acid/amines, acid/alcohols, acid/aldehydes, acid/ketones, acid/halides, acid/nitriles, ester/amines, ester/alcohols, ester/aldehydes, ester/ketones, ester/halides, ester/nitriles, and the like.
摘要翻译：描述的是通过复分解化学制备有机化合物的方法。本发明的方法特别可用于制备工业上重要的有机化合物，起始于可再生原料如天然油的组合物。该方法利用与烯烃化合物的交叉复分解步骤来制备具有预定双键位置的官能化烯烃中间体。一旦分离，官能化的烯烃中间体可以是自我化的或交叉的（例如用第二官能化的烯烃）产生所需的有机化合物或其前体。该方法可用于制备双官能有机化合物，例如二酸，二酯，二羧酸盐，酸/酯，酸/胺，酸/醇，酸/醛，酸/酮，酸/卤化物，酸/腈，酯/ 胺，酯/醇，酯/醛，酯/酮，酯/卤化物，酯/腈等。

10. 发明申请

WO2008063322A2 METATHESIS METHODS INVOLVING HYDROGENATION AND COMPOSITIONS RELATING TO SAME 审中-公开
标题翻译：涉及相同的氢化和组成的多元方法
公开(公告)号：WO2008063322A2
公开(公告)日：2008-05-29
申请号：PCT/US2007/021934
申请日：2007-10-15
申请人： CARGILL, INCORPORATED , MATERIA, INCORPORATED , KAIDO, Hiroki , TUPY, Michael, John , PEDERSON, Richard, L. , SCHRODI, Yann
发明人： KAIDO, Hiroki , TUPY, Michael, John , PEDERSON, Richard, L. , SCHRODI, Yann
IPC分类号： C07C31/125 , C07C69/533
CPC分类号： C11C3/00
摘要： Disclosed are improved methods for conducting metathesis utilizing polyunsaturated fatty acid compositions (e.g., polyunsaturated fatty acid polyol esters, polyunsaturated fatty acids, polyunsaturated fatty esters, and mixtures), such as those found in naturally occurring oils and fats, as the starting material. The inventive methods involve hydrogenation of polyunsaturated fatty acid compositions prior to metathesis, thereby providing partially-hydrogenation compositions having a relatively higher amount of monounsaturated fatty acid species. The partially hydrogenated composition can then be subjected to metathesis to provide a metathesis product composition containing industrially useful compounds.
摘要翻译：公开了利用多不饱和脂肪酸组合物（例如，多不饱和脂肪酸多元醇酯，多不饱和脂肪酸，多不饱和脂肪酸酯和混合物）进行复分解的改进方法，例如在天然存在的油中发现的那些和脂肪作为起始材料。本发明方法涉及在复分解之前氢化多不饱和脂肪酸组合物，由此提供具有相对较高量的单不饱和脂肪酸物种的部分氢化组合物。然后可以使部分氢化的组合物经复分解以提供含有工业上有用的化合物的复分解产物组合物。

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