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    • 1. 发明申请
    • AN ALUMINOSILICATE GLASS CONTAINING Li2O AND P2O5 USED FOR CHEMICAL TOUGHENING
    • 包含用于化学增韧的Li2O和P2O5的铝酸钠玻璃
    • WO2012126394A1
    • 2012-09-27
    • PCT/CN2012/072941
    • 2012-03-23
    • SCHOTT GLASS TECHNOLOGIES (SUZHOU) CO. LTD.ZHANG, GuangjunLAUTENSCHLAEGER, GerhardZIMMER, JoseBAESEL, Matthias
    • ZHANG, GuangjunLAUTENSCHLAEGER, GerhardZIMMER, JoseBAESEL, Matthias
    • C03C3/093C03C10/12C03B27/03
    • C03C3/118C03C3/097C03C10/0036C03C10/0054C03C21/002
    • The present invention discloses an aluminosilicate glass and a glass ceramics for chemical tempering, specifically a novel aluminosilicate glass comprising Li 2 O and P 2 O 5 for chemical tempering. The glass of the present invention can have a high ion exchange rate by adding 0.01-8 wt% of P 2 O 5 . The glass of the present invention comprises 2-6 wt% of Li 2 O, which can reduce the glass molten temperature and glass transition temperature. The glass of the present invention has a low glass transition temperature (Tg) of 480-590°C, and a glass hardness of at least 600 Kg/mm. The glass of the present invention has a large depth of the surface compressive layer (DoL) and a high surface compressive stress (CS) after being chemical tempered. After tempering in pure KNO 3 , a surface compressive layer of potassium ion can be formed with a DoL of at least 20 μm and a CS of at least 600 MPa. And tempering in mixed salts of KNO 3 and NaNO 3 or a two-step tempering by using KNO 3 and NaNO 3 can form potassium and sodium ion compressive layers at the same time with a DoL of at least 50 μm and a CS of at least 600 MPa. In addition, the aluminosilicate glass of the present invention can be further subjected to thermal treatment to convert to glass ceramics.
    • 本发明公开了一种铝硅酸盐玻璃和用于化学回火的玻璃陶瓷,特别是包括用于化学回火的Li 2 O和P 2 O 5的新型铝硅酸盐玻璃。 本发明的玻璃可以通过加入0.01-8重量%的P 2 O 5而具有高的离子交换速率。 本发明的玻璃包含2-6重量%的Li 2 O,这可以降低玻璃熔融温度和玻璃化转变温度。 本发明的玻璃的玻璃化转变温度(Tg)为480-590℃,玻璃硬度至少为600Kg / mm 2。 本发明的玻璃在化学回火后具有较大的表面压缩层深度(DoL)和高表面压缩应力(CS)。 在纯KNO3回火后,可以以至少20μm的DoL和至少600MPa的CS形成钾离子的表面压缩层。 并且通过使用KNO 3和NaNO 3的混合盐回火,或者通过使用KNO 3和NaNO 3进行两步回火,可以同时形成钾和钠离子压缩层,DoL为至少50μm,CS为至少600MPa。 此外,本发明的铝硅酸盐玻璃可以进一步进行热处理以转化成玻璃陶瓷。
    • 2. 发明申请
    • ALKALI ALUMINOSILICATE GLASS FOR 3D PRECISION MOLDING AND THERMAL BENDING
    • 用于3D精密成型和热弯曲的ALKALI铝硅酸盐玻璃
    • WO2011144024A1
    • 2011-11-24
    • PCT/CN2011/074226
    • 2011-05-18
    • SCHOTT GLASS TECHNOLOGIES (SUZHOU) CO. LTD.ZHANG, GuangjunZIMMER, JoséHE, FengLAUTENSCHLAEGER, GerhardVOGL, Armin
    • ZHANG, GuangjunZIMMER, JoséHE, FengLAUTENSCHLAEGER, GerhardVOGL, Armin
    • C03C3/118C03C3/112C03C3/095C03B23/02G02B1/00
    • C03C3/112C03C3/095Y10T428/24628Y10T428/315
    • The present invention provides an alkali aluminosilicate glass having an working point lower than 1200°C (10 4 dPas), and a transition temperature T g lower than 610°C, comprising: based on the percentage by weight, 51 -63% of Si0 2 ; 5-18% of Al 2 0 3 ; 8-16% of Na 2 0; 0-6%of K 2 0; 3.5-10% of MgO; 0-5% of B 2 0 3 ; 0-4.5% of Li 2 0; 0-5% of ZnO; 0-8% of CaO; 0.1 -2.5% of Zr0 2 ; 0.01 - 2 ; 0-0.5% of F 2 ; 0.01 -0.5% of Sn0 2 ; 0-3% of BaO; 0-3% of SrO; 0-0.5% of Yb 2 0 3 ; wherein the sum of Si0 2 +Al 2 0 3 is 63-81 %, and the sum of CaO+MgO is 3.5-18%, and the ratio of Na20/(l_i20+Na20+K20) is 0.4-1.5. The glass is environmentally friendly and free of As203 and Sb203. The glass can be readily manufactured at a lower cost and is suitable to be chemically toughened through ion exchange. The glass has high chemical stability, high impact strength and high hardness, and is suitable for 3D precision molding and thermal bending. The glass can be used as a cover plate or a substrate glass of a touch panel. The glass is also suitable to be used as an electronic substrate.
    • 本发明提供了一种工作点低于1200℃(104dPas),转变温度Tg低于610℃的碱金属铝硅酸盐玻璃,其包含:基于重量百分比为51-63%的SiO 2; 5-18%Al2O3; 8-16%的Na2O; 0〜6%K20; 3.5-10%的MgO; 0〜5%的B203; 0-4.5%的Li20; 0-5%的ZnO; 0-8%的CaO; 0.1〜2.5%的ZrO2; 0.01 -2; 0-0.5%的F2; 0.01〜0.5%的SnO 2; 0-3%的BaO; 0-3%的SrO; 0〜0.5%的Yb203; 其中SiO 2 + Al 2 O 3的总和为63〜81%,CaO + MgO的总和为3.5〜18%,Na 2 O /(1i 20 + Na 2 O + K 2 O)的比例为0.4〜1.5。 玻璃是环保的,不含As203和Sb203。 玻璃可以容易地以更低的成本制造,并且适合于通过离子交换进行化学增韧。 该玻璃具有化学稳定性高,冲击强度高,硬度高,适用于3D精密成型和热弯曲。 玻璃可以用作触摸面板的盖板或基板玻璃。 玻璃也适合用作电子基板。