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1. 发明申请

WO1998028338A1 METHOD FOR THE EPOXIDATION OF UNSATURATED POLYMERS 审中-公开
标题翻译：环氧化不饱和聚合物的方法
公开(公告)号：WO1998028338A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007284
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , CESKA, Gary, W. , FAN, Mingxin , HORGAN, James
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C08C19/06
CPC分类号： C08C19/06
摘要： A process for epoxidizing unsaturated polymers comprising reacting an unsaturated polymer with hydrogen peroxide in the presence of (a) tungstic acid or a metal salt thereof or molybdic acid or a molybdenum oxide, (b) phosphoric acid or a metal salt, and (c) at least one phase transfer catalyst.
摘要翻译：一种使不饱和聚合物环氧化的方法，包括在（a）钨酸或其金属盐或钼酸或氧化钼存在下使不饱和聚合物与过氧化氢反应，（b）磷酸或金属盐，和（c）至少一种相转移催化剂。

2. 发明申请

WO1998028307A1 FREE RADICALLY POLYMERIZABLE SILANE MONOMERS AND OLIGOMERS AND THE METHOD FOR MAKING THEM 审中-公开
标题翻译：自由可聚合的硅烷单体和低聚物及其制备方法
公开(公告)号：WO1998028307A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007285
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , CESKA, Gary, W. , FAN, Mingxin , HORGAN, James
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07F07/18
CPC分类号： C07F7/1896 , C07F7/081 , C07F7/1804
摘要： Compounds of formula (I), wherein R is H or CH3; n is 1 to 6; A is a bivalent to heptavalent linking group; X is O, S, NH; R is H or a C1-C20 organic group; R is a divalent linking group; and each of Y Y Y , which may be the same or different, represents alkoxyl, carboxy, alkoxy ether, alkyl, aryl. A process of making compounds of formula (I) comprises reacting a multifunctional (meth)acrylate of formula (II), with a silane of formula (III). Compounds (I) are shown to be useful as coupling agents or adhesion promotors in free radically, radiation curable compositions where the odor of allyl methacrylate is undesirable. The associated methods, curable compositions, coatings, adhesives and coated articles are also disclosed.
摘要翻译：式（I）化合物，其中R 1是H或CH 3; n为1至6; A是二价至七价连接基团; X是O，S，NH; R 2是H或C 1 -C 20有机基团; R 3是二价连接基团; Y Y Y Y 3中的每一个可以相同或不同，表示烷氧基，羧基，烷氧基醚，烷基，芳基。制备式（I）化合物的方法包括使式（II）的多官能（甲基）丙烯酸酯与式（III）的硅烷反应。化合物（I）被证明可用作自由基可辐射固化组合物中的偶联剂或粘合促进剂，其中甲基丙烯酸烯丙酯的气味是不期望的。还公开了相关方法，可固化组合物，涂料，粘合剂和涂覆制品。

3. 发明申请

WO1998028308A1 SILICON-CONTAINING ALKOXYLATED (METH)ACRYLATE MONOMERS 审中-公开
标题翻译：含硅烷氧基（甲基）丙烯酸酯单体
公开(公告)号：WO1998028308A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007287
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , FAN, Mingxin , CESKA, Gary, W. , HORGAN, James , HAZELL, Thomas, W.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07F07/18
CPC分类号： C08F30/08 , C07F7/081 , C07F7/12 , C07F7/1804 , C09D4/00 , Y10T428/31663 , C08F230/08
摘要： Compounds of formula (I), wherein R = H, -CH3; each of the Y, which may be the same or different when n is higher than 1, represents an alkylene oxide unit of formula (Ia) or (Ib), wherein R is H, -CH3, -CH2CH3 or -CH2CH2CH3; n = 1-10; X = halogen, (C1-C6) alkyl, (C1-C6) alkoxy, or aromatic radical, wherein each of the three X substituents can be the same or different, are shown to be useful as coupling agents or adhesion promotors in free radically curable compositions such as radiation (UV or EB) curable and/or peroxide curable (meth)acrylate-based coating compositions. The associated methods, curable compositions, coatings, adhesives and coated articles are also disclosed.
摘要翻译：式（I）化合物，其中R 1 = H，-CH 3; 当n高于1时，每个Y可以相同或不同，表示式（Ia）或（Ib）的烯化氧单元，其中R 2是H，-CH 3，-CH 2 CH 3或-CH 2 CH 2 CH 3 ; n = 1-10; X =卤素，（C 1 -C 6）烷基，（C 1 -C 6）烷氧基或芳族基团，其中三个X取代基中的每一个可以相同或不同，被证明可用作自由基中的偶联剂或粘附促进剂可固化组合物如辐射（UV或EB）可固化和/或过氧化物可固化（甲基）丙烯酸酯基涂料组合物。还公开了相关方法，可固化组合物，涂料，粘合剂和涂覆制品。

4. 发明申请

WO1998028287A1 ALKOXYLATED GLYCIDYL (METH)ACRYLATES AND METHOD OF PREPARATION 审中-公开
标题翻译：烷基甘氨酸（甲基）丙烯酸酯及其制备方法
公开(公告)号：WO1998028287A1
公开(公告)日：1998-07-02
申请号：PCT/EP1997007283
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , FAN, Mingxin , CESKA, Gary, W. , HORGAN, James , HAZELL, Thomas, W.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07D303/16
CPC分类号： C08G65/14 , C07D303/16 , C08F20/32 , C08L71/02 , C08L2666/04
摘要： The present invention relates to compounds of formula (I) (R = H, CH3; each of the Y, which may be the same or different when x is higher than 1, represents an alkylene oxide unit of formula (a) or (b), wherein R is hydrogen or (C1-C6) alkyl; and x = 1-20, with the proviso that x is higher than 10 when all the alkylene oxide units Y are ethylene oxide units); and to a process for preparing compounds (I) which comprises reacting an alkoxylated allyl acrylate or methacrylate of formula (II) wherein R ans Y are as defined above and x = 1-20, with hydrogen peroxide in the presence of (a) tungstic acid or a metal salt thereof or molybdic acid or a molybdenum oxide; (b) phosphoric acid or a metal salt thereof; and (c) at least one phase transfer catalyst.
摘要翻译：本发明涉及式（I）化合物（R 1 = H，CH 3;当x高于1时Y可各自相同或不同，表示式（a）的烯化氧单元）或（b），其中R 2为氢或（C 1 -C 6）烷基; x = 1-20，条件是当所有环氧烷单元Y为环氧乙烷单元时x高于10）; 以及制备化合物（I）的方法，其包括使式（II）的烷氧基化烯丙基丙烯酸酯或甲基丙烯酸酯（其中R 1和Y如上定义）和x = 1-20与过氧化氢在（ a）钨酸或其金属盐或钼酸或氧化钼; （b）磷酸或其金属盐; 和（c）至少一种相转移催化剂。

5. 发明申请

WO1998028286A2 UNSATURATED (METH)ACRYLATE ESTERS CONTAINING EPOXIDIZED CYCLIC GROUPS AND PROCESS FOR PREPARING 审中-公开
标题翻译：含有环氧化环状团的不饱和（METH）丙烯酸酯和制备方法
公开(公告)号：WO1998028286A2
公开(公告)日：1998-07-02
申请号：PCT/EP1997007286
申请日：1997-12-22
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , CESKA, Gary, W. , FAN, Mingxin , HORGAN, James
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
IPC分类号： C07D303/00
CPC分类号： C07D303/40 , C07D301/12 , C07D303/16 , C07D303/24 , C08G59/24
摘要： A process of making compounds of formula (I), wherein Z is an unsubstituted or substituted n-valent cyclic moiety bearing at least one endocyclic oxirane group; Y is O, S, NH, (Ia) or (Ib); R is a divalent linking group; X is O, S or NH; R is H or (C1-C6) alkyl; and n is an integer from 1 to 6, Z being mono- to hexavalent respectively, it being possible for -Y-R to represent a single bond, comprises reacting a compound of formula (II), wherein Z is a cyclic moiety bearing at least one endocyclic C=C group; and Y, R , X, R and n are as defined above with hydrogen peroxide in the presence of (a) tungstic acid or tungsten oxide or molybdic acid or a molybdenum oxide; (b) phosphoric acid or a salt thereof; and (c) at least one phase transfer catalyst.
摘要翻译：制备式（I）化合物的方法，其中Z是具有至少一个环内环氧基团的未取代或取代的n价环状部分; Y是O，S，NH，（Ia）或（Ib）; R 2是二价连接基团; X是O，S或NH; R 1是H或（C 1 -C 6）烷基; n为1〜6的整数，Z分别为1〜6价，-YR 2可以表示单键，包括使式（II）化合物（其中Z 1为具有至少一个环内C = C基团的环状部分; 在（a）钨酸或钨氧化物或钼酸或氧化钼的存在下，Y，R 2，X，R 1和n如上定义，与过氧化氢反应; （b）磷酸或其盐; 和（c）至少一种相转移催化剂。

6. 发明申请

WO1996041827A1 AMINE CURABLE EPOXY COATING COMPOSITIONS HAVING AN IMPROVED ADHESION TO SUBSTRATES 审中-公开
标题翻译：具有改进粘合剂基质的可固化环氧涂料组合物
公开(公告)号：WO1996041827A1
公开(公告)日：1996-12-27
申请号：PCT/EP1996002502
申请日：1996-06-07
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , COSTIN, C., Richard , CESKA, Gary, W. , BAILEY, Michael, A.
IPC分类号： C08G59/68
CPC分类号： C08K5/098 , C08G59/50 , C08G59/685 , C09D4/06 , C08L63/00 , C08F283/00
摘要： A curable coating composition comprising: (a) the constituents of an amine cure epoxy coating composition, which comprise: (a1) at least one polyepoxide; (a2) possibly at least one polyacrylate or polymethacrylate ester of a polyol; and (a3) at least one curing agent of the amine type; (b) an adhesion improving effective amount of at least a metal salt of an alpha , beta -ethylenically unsaturated carboxylic acid.
摘要翻译：一种可固化涂料组合物，其包含：（a）胺固化环氧涂料组合物的组分，其包含：（a1）至少一种聚环氧化物; （a2）可能是多元醇的至少一种聚丙烯酸酯或聚甲基丙烯酸酯; 和（a3）至少一种胺型固化剂; （b）粘附改善有效量的至少一种α，β-烯属不饱和羧酸的金属盐。

7. 发明申请

WO1997007140A1 FUNCTIONALIZED POLYBUTADIENE RESINS, METHOD FOR MAKING SAME AND THEIR USES 审中-公开
标题翻译：功能性聚丁二烯树脂，其制备方法及其用途
公开(公告)号：WO1997007140A1
公开(公告)日：1997-02-27
申请号：PCT/EP1996003593
申请日：1996-08-14
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , BOECKELER, Rudolph, Henry
IPC分类号： C08C19/38
CPC分类号： C08F290/048 , C08C19/34 , C08C19/38 , C08F279/02
摘要： A polybutadiene resin functionalized by R-COO- type terminal functions which are derived from an alpha , beta unsaturated carboxylic acid, said resin consisting of the product of the reaction of a -COOH or anhydride-terminated polybutadiene derivative with at least one epoxide, said epoxide being a monoepoxide in such a case it bears a R-COO- type function as defined above, or a diepoxide in such a case the reaction has been conducted with a stoichiometric excess of diepoxide or of -COOH or anhydride-terminated polybutadiene, and as the case may be, the residual epoxide functions having partly or totally reacted with an alpha , beta unsaturated carboxylic acid or the residual -COOH or anhydride functions having partly or totally reacted with a monoepoxide having a R-COO- type function as defined above.
摘要翻译：由R-COO型末端官能化官能化的聚α丁二烯树脂，其衍生自α，β不饱和羧酸，所述树脂由-COOH或酸酐封端的聚丁二烯衍生物与至少一种环氧化物反应的产物组成，所述在这种情况下，环氧化物是单环氧化物，其具有如上定义的R-COO-型功能，或在这种情况下，化学计量过量的二环氧化物或-COOH或酸酐封端的聚丁二烯进行反应的二环氧化物，以及根据情况，残留的环氧化物功能部分或完全与α，β不饱和羧酸反应或残留的-COOH或酸酐官能部分或全部与具有上述R-COO-型功能的单环氧化物反应。

8. 发明申请

WO1997001597A1 IMPROVED PHENOLIC SCORCH RETARDERS 审中-公开
标题翻译：改进的PHENOLIC SCORCH延迟器
公开(公告)号：WO1997001597A1
公开(公告)日：1997-01-16
申请号：PCT/EP1996002800
申请日：1996-06-26
申请人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A.
发明人： SARTOMER COMPANY, INC. , CRAY VALLEY S.A. , BROOKS, Lester, A. , COSTIN, C., Richard , NAGEL, Walter, R.
IPC分类号： C08K05/17
CPC分类号： C08K5/17 , C08F291/02
摘要： A scorch retarding system suited for curing free radical curable elastomers, consisting of or comprising at least one aminoalkyl phenolic scorch retarder acid salt, and possibly at least one polyfunctional monomer coagent. A curable elastomer composition, characterized in that it comprises: (a) an elastomer; (b) a scorch retarding effective amount of at least one aminoalkyl phenolic scorch retarder acid salt; (c) possibly a cross-linking effective amount of at least one polyfunctional monomer coagent; and (d) a cure effective amount of at least one free radical generating compound, said acid salt(s) and said coagent(s) constituting the system as defined above.
摘要翻译：一种适用于固化可自由基固化的弹性体的焦烧缓和体系，由或由至少一种氨基烷基酚焦烧缓凝剂酸盐组成或包含至少一种多官能单体助剂。一种可固化弹性体组合物，其特征在于它包括：（a）弹性体; （b）减焦有效量的至少一种氨基烷基酚焦烧缓凝剂酸盐; （c）可能的交联有效量的至少一种多官能单体助剂; 和（d）固化有效量的至少一种产生自由基的化合物，所述酸性盐和所述助剂构成如上所定义的体系。

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