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    • 2. 发明申请
    • PROCESS FOR PRODUCTION OF COPOLYCARBONATES WITH REDUCED COLOR
    • 生产具有降低颜色的共聚碳酸酯的方法
    • WO2005073274A8
    • 2006-08-24
    • PCT/US2005002186
    • 2005-01-20
    • GEN ELECTRICKAMPS JAN HENKLENS JAN PLEUN
    • KAMPS JAN HENKLENS JAN PLEUN
    • C08G64/30
    • C08G64/307
    • A method is provided for reducing the color generated during production of copolycarbonate that includes quinone-type residues. The method includes the steps preparing a reaction mixture containing precursors of monomer residues, selecting a catalyst, introduction strategy and adding catalysts according to the strategy. The strategy is sufficient to result in a product copolycarbonate with improved color. The method further includes the steps of introducing the reaction mixture to a series of process units and allowing the reaction mixture to polymerize thereby forming a copolycarbonate. The resulting copolycarbonate has improved color as compared to a copolycarbonate formed in a process without the steps of selecting a catalyst introduction strategy and introducing catalysts according to the selected strategy.
    • 提供了一种减少在生产包括醌型残留物的共聚碳酸酯期间产生的颜色的方法。 该方法包括制备含有单体残基前体的反应混合物,选择催化剂,引入策略和根据该策略加入催化剂的步骤。 该策略足以产生具有改进颜色的产品共聚碳酸酯。 该方法还包括将反应混合物引入一系列处理单元并使反应混合物聚合从而形成共聚碳酸酯的步骤。 所得共聚碳酸酯与在不进行选择催化剂引入策略和引入催化剂的步骤的步骤中形成的方法相比,具有改进的颜色。
    • 3. 发明申请
    • FLAME RETARDANT AND SCRATCH RESISTANT THERMOPLASTIC POLYCARBONATE COMPOSITIONS
    • 阻燃和耐刮擦热塑性聚碳酸酯组合物
    • WO2008054884A3
    • 2008-07-03
    • PCT/US2007070674
    • 2007-06-08
    • GEN ELECTRICSIRIPURAPU SRINIVASAGARWAL NAVEENLENS JAN PLEUN
    • SIRIPURAPU SRINIVASAGARWAL NAVEENLENS JAN PLEUN
    • C08L69/00
    • C08L69/00C08K5/005C08K5/523C08L51/04C08L53/00C08L55/02C08L83/10C08L2666/02
    • A thermoplastic composition comprising in combination a polycarbonate homopolymer or copolymer comprising repeat carbonate units having the following structure: (I) wherein Ri and R2 are independently at each occurrence a Ci -C4 alkyl, n and p are each an integer having a value of 1 to 4, and T is selected from the group consisting of C5-Ci0 cycloalkanes attached to the aryl groups at one or two carbons, Ci-C5 alkyl groups, C6-C13 aryl groups, and C7-C12 aryl alkyl groups; an impact modifier, wherein the impact modifier comprises a first impact modifier comprising a polycarbonate - polysiloxane copolymer and a second impact modifier different from the first impact modifier; and a flame retardant is disclosed. The compositions have excellent scratch resistance as well as an improved balance of physical properties such as impact strength and spiral flow, while at the same time maintaining their good flame performance.
    • 一种包含聚碳酸酯均聚物或共聚物的热塑性组合物,其包含具有以下结构的重复碳酸酯单元:(I)其中R 1和R 2在每次出现时独立地为C 1 -C 4烷基,n和p各自为值为1的整数 至4,并且T选自与一个或两个碳上的芳基相连的C 5 -C 10环烷烃,C 1 -C 5烷基,C 6 -C 13芳基和C 7 -C 12芳基烷基; 抗冲改性剂,其中所述抗冲改性剂包含第一抗冲改性剂,其包含聚碳酸酯 - 聚硅氧烷共聚物和不同于所述第一抗冲改性剂的第二抗冲改性剂; 并且公开了阻燃剂。 组合物具有优异的耐刮擦性以及改善的物理性能的平衡,例如冲击强度和螺旋流,同时保持其良好的火焰性能。
    • 5. 发明申请
    • FLAME RETARDANT AND SCRATCH RESISTANT THERMOPLASTIC POLYCARBONATE COMPOSITIONS
    • 阻燃和耐刮擦热塑性聚碳酸酯组合物
    • WO2008048718A2
    • 2008-04-24
    • PCT/US2007070673
    • 2007-06-08
    • GEN ELECTRICSIRIPURAPU SRINIVASAGARWAL NAVEENLENS JAN PLEUN
    • SIRIPURAPU SRINIVASAGARWAL NAVEENLENS JAN PLEUN
    • C08L69/00C08L51/00
    • C08L69/00C08F265/04C08K5/0066C08K5/523C08L51/04C08L55/02C08L83/10C08F212/10C08L2666/24C08L2666/84C08L2666/02
    • A flame retardant thermoplastic composition comprising in combination a polycarbonate homopolymer or copolymer comprising repeat carbonate units having the following structure: (I) wherein R 1 and R 2 are independently at each occurrence a C 1 -C 4 alkyl, n and p are each an integer having a value of 1 to 4, and T is selected from the group consisting of C 5 -C 10 cycloalkanes attached to the aryl groups at one or two carbons, C 1 -C 5 alkyl groups, C 6 -C 13 aryl groups, and C 7 -C 12 aryl alkyl groups; an impact modifier, wherein the impact modifier comprises wherein the impact modifier comprises a rubber modified thermoplastic resin comprising a discontinuous elastomeric phase dispersed in a rigid thermoplastic phase, and wherein the impact modifier has a specific mean particle size and Q value; and a flame retardant. The compositions have excellent scratch resistance as well as an improved balance of physical properties such as impact strength and spiral flow, while at the same time maintaining their good flame performance.
    • 一种阻燃热塑性组合物,其组合包含聚碳酸酯均聚物或共聚物,其包含具有以下结构的重复碳酸酯单元:(I)其中R 1和R 2在每次出现时独立地为 C 1 -C 4烷基,n和p各自为1至4的整数,T选自C 1 -C 4烷基, 在一个或两个碳上连接到芳基上的C 1 -C 10 - 环烷烃,C 1 -C 5烷基,C C 6 -C 13芳基和C 7 -C 12芳基烷基; 抗冲改性剂,其中所述抗冲改性剂包括其中所述抗冲改性剂包含橡胶改性的热塑性树脂,其包含分散在刚性热塑性相中的不连续弹性体相,并且其中所述抗冲改性剂具有特定的平均粒度和Q值; 和阻燃剂。 组合物具有优异的耐刮擦性以及改善的物理性能的平衡,例如冲击强度和螺旋流,同时保持其良好的火焰性能。