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1. 发明申请

WO2019089887A1 PHTHALIMIDINE COPOLYCARBONATE OPTICAL ARTICLES, ARTICLES FORMED THEREFROM, AND METHODS OF MANUFACTURE 审中-公开
公开(公告)号：WO2019089887A1
公开(公告)日：2019-05-09
申请号：PCT/US2018/058638
申请日：2018-11-01
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , ZHAO, Wei , VAN DER MEE, Mark Adrianus Johannes , SWAMINATHAN, Shubashree , PAL, Jaykisor , CALVERAS, Jordi
IPC分类号： C08G64/12 , C08G64/30 , G02C7/04 , G02B1/04
摘要： A copolycarbonate optical article comprises a polycarbonate composition including: a copolycarbonate having: 2 to 60 mol% of phthalimidine carbonate units, 2 to 90 mol% of high heat carbonate units, and optionally 2 to 60 mol% of bisphenol A carbonate units. The copolycarbonate has less than 100 ppm of each of phthalimidine, high heat bisphenol, and bisphenol A monomers, and less than 5 ppm of various ions, and is prepared from monomers each having a purity of at least 99.6%. The polycarbonate composition has a glass transition temperature of 200 ºC to and a yellowness index of less than 30.

2. 发明申请

WO2020112591A1 SULFUR-STABILIZED THERMOPLASTIC COMPOSITIONS, METHODS OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开
公开(公告)号：WO2020112591A1
公开(公告)日：2020-06-04
申请号：PCT/US2019/062920
申请日：2019-11-25
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SYBERT, Paul Dean
发明人： SYBERT, Paul Dean , MAHOOD, James Alan , HOOVER, James Franklin , CALVERAS, Jordi
IPC分类号： C08L69/00
摘要： A copolycarbonate included 2-95 mole percent of high heat carbonate units derived from a high heat aromatic dihydroxy monomer, wherein a polycarbonate homopolymer derived from the high heat aromatic dihydroxy monomer has a glass transition temperature of 175-330C determined by differential scanning calorimetry as per ASTM D3418 with a 20C/min heating rate, and 5-98 mole percent of a low heat carbonate units derived from a low heat aromatic monomer, wherein a polycarbonate homopolymer derived from the low heat aromatic monomer has a glass transition temperature of less than 170C determined by differential scanning calorimetry as per ASTM D3418 with a 20C/min heating rate, each based on the sum of the moles of the carbonate units; and a sulfur-containing stabilizer compound, wherein the sulfur-containing stabilizer compound is a thioether carboxy compound, a thioether dicarboxy compound, a thioether ester compound, or a combination thereof, wherein the sulfur-containing stabilizer compound is present in an amount effective to provide 5-50 parts per million by weight of added sulfur, based on the total parts by weight of the copolycarbonate, wherein a source of the added sulfur is the sulfur-containing stabilizer.

3. 发明申请

WO2018191612A1 SYNTHESIS OF A PHOSPHOROUS CONTAINING MONOMER AND THE INCORPORATION IN POLYCARBONATE BY INTERFACIAL POLYMERIZATION THEREOF 审中-公开
公开(公告)号：WO2018191612A1
公开(公告)日：2018-10-18
申请号：PCT/US2018/027479
申请日：2018-04-13
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , CALVERAS, Jordi
发明人： CALVERAS, Jordi
IPC分类号： C08G64/08
摘要： A phosphinate copolycarbonate having units of the formula (1) wherein each R a is independently a halogen atom, C 1-10 alkyl, C 1-10 haloalkyl, C 1-12 alkoxy, C 6-10 aryl, or C 6-12 haloaryl, each X a is as defined herein, R e and R f are independently a halogen atom, C 1-10 alkyl, C 1-10 haloalkyl, C 1-10 alkoxy, C 1-10 haloalkoxy, C 2-10 alkenyl, or C 3-10 cycloalkyl, each R g is a substituted or unsubstituted C 6-18 aryl, C 1-10 alkyl, C 1-10 haloalkyl, C 1-10 alkoxy, C 1-10 haloalkoxy, C 2-10 alkenyl, C 3-10 cycloalkyl, C 6-10 aryl, or C 6-12 haloaryl, Ar a and Ar b are each independently the same or different C 6-18 aryl, a, e, and f are each independently 0 to 4, or 0 to 2, or 0, c is 0 or 1, and x and y represent the molar ratio of each unit in the phosphinate copolycarbonate, and are 0.5:99.5 to 99.5:0.5, or 1:99 to 99:1, or 10:90 to 90:10, or 20:80 to 80:20.

4. 发明申请

WO2021170386A1 METHOD FOR THE MANUFACTURE OF POLYCARBONATE 审中-公开
公开(公告)号：WO2021170386A1
公开(公告)日：2021-09-02
申请号：PCT/EP2021/053015
申请日：2021-02-09
申请人： SABIC GLOBAL TECHNOLOGIES B.V.
发明人： KONDA, Shivakumar , SCHMIDT, Chelsea , POLASA, Indira, Jyothi , CALVERAS, Jordi , KANJIRATHADATHIL, Thomas, Paul
IPC分类号： C08G64/10 , C08G64/24 , C08L69/00
摘要： The present invention relates to a method for the manufacture of a (co)polycarbonate comprising reacting tetrabromo bisphenol A and optionally one or more bisphenol comonomer(s) with phosgene wherein the tetrabromo bisphenol A contains an amount of tetrabromo bisphenol A dimer of at most 3.0 wt.% based on the weight of the tetrabromo bisphenol A, determined after heat treating the tetrabromo bisphenol A at a temperature of 260 °C for a period of 15 minutes.

5. 发明申请

WO2015073847A1 METHODS OF IDENTIFYING CROSSLINKING MOLECULES FOR POLYMERS 审中-公开
标题翻译：识别聚合物交联分子的方法
公开(公告)号：WO2015073847A1
公开(公告)日：2015-05-21
申请号：PCT/US2014/065736
申请日：2014-11-14
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , CALVERAS, Jordi
发明人： CALVERAS, Jordi
IPC分类号： A61K49/00 , A61L27/16 , A61K9/00 , A61L15/28
CPC分类号： G01N33/442 , C08G64/14
摘要： Methods for screening molecules or moieties for their ability to crosslink are disclosed. An aromatic carbonate, aromatic ester, or aliphatic ester group is attached to the molecule to mimic the presence of a polymer. A solution of the modified molecule is irradiated, and the first-order kinetic rate constant is measured. If the rate constant is high enough or a threshold amount of the molecule is consumed, a polymer is synthesized using the molecule/moiety as an endcap or co-monomer. The polymer is irradiated, and the increase in crosslink density and the gel formation percentage are determined. These parameters, if high enough, indicate the suitability of the molecule/moiety to act as a crosslinking agent, particularly for polycarbonates. Alternatively, the molecule/moiety may be identified as suitable solely by its first-order kinetic rate constant.
摘要翻译：公开了用于筛选分子或部分交联能力的方法。将芳族碳酸酯，芳族酯或脂族酯基团连接到分子上以模拟聚合物的存在。照射改性分子的溶液，测定一级动力学速率常数。如果速率常数足够高或分子的阈值被消耗，则使用分子/部分作为端基或共聚单体来合成聚合物。照射聚合物，确定交联密度和凝胶形成百分比的增加。这些参数，如果足够高，表明分子/部分适合作为交联剂，特别是聚碳酸酯。或者，分子/部分可以仅通过其一级动力学速率常数来确定为合适的。

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