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1. 发明申请

WO2012031274A1 REGENERABLE IONIC LIQUID SOLVENTS FOR ACID -GAS SEPARATION 审中-公开
标题翻译：可再生的离子液体溶剂用于酸分离
公开(公告)号：WO2012031274A1
公开(公告)日：2012-03-08
申请号：PCT/US2011/050442
申请日：2011-09-02
申请人： RESEARCH TRIANGLE INSTITUTE , LAIL, Marty , COLEMAN, Luke
发明人： LAIL, Marty , COLEMAN, Luke
IPC分类号： B01D53/14
CPC分类号： B01D53/40 , B01D53/1425 , B01D53/1456 , B01D53/1475 , B01D53/1493 , B01D2252/202 , B01D2252/20405 , B01D2252/20421 , B01D2252/20426 , B01D2252/504 , B01D2257/30 , B01D2257/302 , B01D2257/308 , B01D2257/404 , B01D2257/504 , B01D2258/0283 , Y02A50/2342 , Y02C10/06
摘要： A solvent system comprising an ionic Liquid formed from a relatively acidic component and a nitrogenous base for the removal of acid gases from mixed gas streams is provided. Also provided is a process for removing acid gases from mixed gas streams using the disclosed solvent system. The solvent system may be utilized within a gas processing system.
摘要翻译：提供了一种溶剂系统，其包括由相对酸性组分形成的离子液体和用于从混合气流中除去酸性气体的含氮碱。还提供了使用公开的溶剂系统从混合气流中除去酸性气体的方法。溶剂系统可以在气体处理系统内使用。

2. 发明申请

WO2012031281A2 REGENERABLE SOLVENT MIXTURES FOR ACID-GAS SEPARATION 审中-公开
标题翻译：用于酸气分离的可再生溶剂混合物
公开(公告)号：WO2012031281A2
公开(公告)日：2012-03-08
申请号：PCT/US2011/050452
申请日：2011-09-03
申请人： RESEARCH TRIANGLE INSTITUTE , LAIL, Marty , COLEMAN, Luke
发明人： LAIL, Marty , COLEMAN, Luke
IPC分类号： B01D53/14
CPC分类号： B01D53/40 , B01D53/1425 , B01D53/1456 , B01D53/1475 , B01D53/1493 , B01D2252/202 , B01D2252/20405 , B01D2252/20421 , B01D2252/20426 , B01D2252/504 , B01D2257/30 , B01D2257/302 , B01D2257/308 , B01D2257/404 , B01D2257/504 , B01D2258/0283 , Y02A50/2342 , Y02C10/06
摘要： A solvent system comprising a diluent and a nitrogenous base for the removal of CO 2 from mixed gas streams is provided. Also provided is a process for removing CO 2 from mixed gas streams using the disclosed solvent system. The solvent system may be utilized within a gas processing system.
摘要翻译：提供了一种包含用于从混合气流中除去CO 2的稀释剂和含氮碱的溶剂体系。还提供了使用公开的溶剂系统从混合气流中除去CO 2的方法。溶剂系统可以在气体处理系统内使用。

3. 发明申请

WO2015020862A3 MIXED METAL IRON OXIDES AND USES THEREOF 审中-公开
公开(公告)号：WO2015020862A3
公开(公告)日：2015-02-12
申请号：PCT/US2014/049007
申请日：2014-07-31
申请人： RESEARCH TRIANGLE INSTITUTE , SHEN, Jian-ping , LAIL, Marty , TURK, Brian , MOBLEY, Paul, D. , NORMAN, Jason, S. , DOUGLAS, Laura , PETERS, Jonathan
发明人： SHEN, Jian-ping , LAIL, Marty , TURK, Brian , MOBLEY, Paul, D. , NORMAN, Jason, S. , DOUGLAS, Laura , PETERS, Jonathan
IPC分类号： B01J23/74 , B01J23/76
摘要： This invention is directed to novel mixed transition metal iron (II/III) catalysts for the extraction of oxygen from CO 2 and the selective reaction with organic compounds.

4. 发明申请

WO2022269546A1 MBZA/PEG ETHYL ETHER BASED LIQUID SOLVENT CO2 CAPTURE IN ROTATING PACKED BED 审中-公开
公开(公告)号：WO2022269546A1
公开(公告)日：2022-12-29
申请号：PCT/IB2022/055855
申请日：2022-06-23
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： MOBLEY, Paul David , LAIL, Marty
IPC分类号： B01D53/14 , B01D53/06 , B01D53/62 , B01D2252/2026 , B01D2252/20405 , B01D2252/20421 , B01D2252/20426 , B01D2252/504 , B01D2258/0283 , B01D53/1425 , B01D53/1475 , B01D53/1493 , B01D53/18
摘要： The disclosure provides an apparatus, as well as associated systems and methods for removing acid gas components from gas streams. The disclosure provides a rotating packed bed (RPB)-based absorber with a non-aqueous liquid solvent contained therein for treatment of the gas streams, wherein the non-aqueous liquid solvent captures acid components from the gas stream. Various advantages, e.g., with respect to spatial considerations and associated expenses can be realized using the apparatus, systems, and methods described herein.

5. 发明申请

WO2019222566A1 METHOD OF MAKING COLLOIDAL SUSPENSIONS OF METAL ORGANIC FRAMEWORKS IN POLYMERIC SOLUTIONS AND USES THEREOF 审中-公开
公开(公告)号：WO2019222566A1
公开(公告)日：2019-11-21
申请号：PCT/US2019/032766
申请日：2019-05-17
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： LUZ MINGUEZ, Ignacio , SOUKRI, Mustapha , LAIL, Marty , TOY, Lora, Goon
IPC分类号： B01J20/22 , B01J20/28 , B01J31/22
摘要： A method for making a metal organic framework suspension is described herein. The method includes providing a hybrid material comprising a nano-crystalline metal organic framework comprising micropores and a mesoporous polymeric material comprising mesopores, wherein the nano-crystalline metal organic framework is homogeneously dispersed and substantially present only within the mesopores or void spaces of the mesoporous polymeric material; and wherein the hybrid material has a weight percentage of the metal organic framework in the range of 5-50% relative to the total weight of the hybrid material. The method includes contacting the hybrid material with a solvent in which the mesoporous polymeric material is soluble, thereby forming a polymeric solution in which the nano-crystalline metal organic framework is substantially homogeneously dispersed and suspended.

6. 发明申请

WO2018031733A1 SOLID-STATE CRYSTALLIZATION OF METAL ORGANIC FRAMEWORKS WITHIN MESOPOROUS METERIALS METHODS AND HYBRID MATERIALS THEREOF 审中-公开
标题翻译：中孔材料中金属有机骨架的固态结晶及其混杂材料
公开(公告)号：WO2018031733A1
公开(公告)日：2018-02-15
申请号：PCT/US2017/046231
申请日：2017-08-10
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： LUZ MINGUEZ, Ignacio , SOUKRI, Mustapha , LAIL, Marty
IPC分类号： C01B39/00 , C01B39/02
摘要： A method, comprising i) contacting an aqueous solution of an organic ligand salt of the formula A X (L -X ) with a mesoporous material (MPM) to form an impregnated mesoporous salt material of the formula A X (L -X )/MPM, ii) treating the impregnated mesoporous salt material with an aqueous acidic solution to form an impregnated mesoporous acid material of the formula H X (L -X )/MPM, iii) contacting an aqueous solution of a metal precursor of the formula M +y (B)y with the impregnated mesoporous acid material to form an impregnated mesoporous metal organic framework precursor of the formula [M +y (B) y ][H x (L -x )]/MPM, and iv) at least one of 1) heating the impregnated mesoporous metal organic framework precursor in the absence of a solvent or 2) exposing the impregnated mesoporous metal organic framework precursor to a volatile vapor in the absence of a solvent such that the heating or the exposing forms a hybrid material of the formula (M +y L -x )/MPM, wherein the hybrid material comprises a nano-crystalline metal organic framework (MOF) embedded within the mesoporous material.
摘要翻译：一种方法，其包括：i）将式A的有机配体盐的水溶液（L 1 -X 2）与介孔材料（MPM）反应以形成式A（X）（L-X-X）/ MPM的浸渍介孔盐材料，ii）用含水酸性物质处理浸渍的中孔盐材料形成式HN（L 1 -X）/ MPM的浸渍中孔酸材料，iii）使式M的金属前体的水溶液与式III的金属前体的水溶液接触，（B）y与浸渍的介孔酸材料反应，形成式[M + Y（B）y]的浸渍介孔金属有机骨架前体，并且iv）至少以下之一：1）在不存在以下情况下加热浸渍的中孔金属有机骨架前体：或2）在不存在溶剂的情况下将浸渍的中孔金属有机骨架前体暴露于挥发性蒸气，加热或暴露形成式（M + Y→X-X）/ MPM的混合材料，其中混合材料包含纳米晶体金属有机骨架（ MOF）嵌入介孔材料中。

7. 发明申请

WO2018022740A9 CATALYSTS UTILIZING CARBON DIOXIDE FOR THE EPOXIDATION OF OLEFINS 审中-公开
公开(公告)号：WO2018022740A9
公开(公告)日：2018-02-01
申请号：PCT/US2017/043921
申请日：2017-07-26
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： LAIL, Marty , MOBLEY, Paul , PETERS, Jonathan , AKUNURI, Sree, Nandita , HLEBAK, Joshua, J.
IPC分类号： B01J23/68 , B01J23/652 , B01J29/03 , B01J37/03 , C07D301/03
摘要： The present disclosure provides mixed molybdenum oxide catalysts, methods for preparing epoxides from olefins and CO 2 using them, and methods of making the mixed molybdenum oxide catalysts by impregnation or co-precipitation. In a preferred embodiment, the mixed molybdenum oxide catalysts are silver/molybdenum oxide catalysts, ruthenium/molybdenum oxide catalysts, or a combination thereof.

8. 发明申请

WO2021154704A2 METHODS AND SYSTEMS FOR REDUCING THE CONCENTRATION OF AMINE IN WASH LIQUID USED IN INDUSTRIAL PROCESSING 审中-公开
公开(公告)号：WO2021154704A2
公开(公告)日：2021-08-05
申请号：PCT/US2021/015050
申请日：2021-01-26
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： MOBLEY, Paul , ZHOU, Shaojun James , THOMPSON, Samuel John , TANTHANA, Jak , RABINDRAN, Aravind Villava Rayer , LAIL, Marty
IPC分类号： C02F1/28 , C02F1/58 , B01D53/14 , B01J20/00 , C02F1/283 , C02F2101/38 , C02F2103/18
摘要： A method for reducing the concentration of amines in a wash liquid stream exiting a wash section in an acid gas scmbbing process includes introducing the wash liquid stream exiting the wash section of the acid gas scrubbing process to an adsorbent material, wherein the wash liquid stream has a first concentration of amines. The wash liquid stream having the first concentration of amines is flowed through the adsorbent material, and the adsorbent material retains at least a portion of the amines thereby providing a wash liquid stream having a second, reduced concentration of amines. The wash stream with reduced concentration of amines is recycled back to the wash section to remove amines more effectively from the acid gas being scrubbed. The adsorbent material can be regenerated for reuse. Amine recovered from the regenerated adsorbent material can be recycled to the process for reuse.

9. 发明申请

WO2019191034A1 METHOD OF MAKING CONFINED NANOCATALYSTS WITHIN MESOPOROUS MATERIALS AND USES THEREOF 审中-公开
公开(公告)号：WO2019191034A1
公开(公告)日：2019-10-03
申请号：PCT/US2019/023989
申请日：2019-03-26
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： LUZ MINGUEZ, Ignacio , SOUKRI, Mustapha , LAIL, Marty , CARPENTER, John R. , PARVATHIKAR, Sameer , CARPENTER, Michael
IPC分类号： B01J35/00 , B01J31/16 , B01J29/70 , B01J35/10 , B01J35/02 , B01J37/08
摘要： The present disclosure provides methods of making confined nanocatalysts within mesoporous materials (MPMs). The methods utilize solid state growth of nanocrystalline metal organic frameworks (MOFs) followed by controlled transformation to generate nanocatalysts in situ within the mesoporous material. The disclosure also provides applications of the nanocatalysts to a wide variety of fields including, but not limited to, liquid organic hydrogen carriers, synthetic liquid fuel preparation, and nitrogen fixation.

10. 发明申请

WO2018022740A2 CATALYSTS UTILIZING CARBON DIOXIDE FOR THE EPOXIDATION OF OLEFINS 审中-公开
标题翻译：利用二氧化碳催化烯烃环氧化的催化剂
公开(公告)号：WO2018022740A2
公开(公告)日：2018-02-01
申请号：PCT/US2017/043921
申请日：2017-07-26
申请人： RESEARCH TRIANGLE INSTITUTE
发明人： LAIL, Marty , MOBLEY, Paul , PETERS, Jonathan , AKUNURI, Sree, Nandita , HLEBAK, Joshua, J.
IPC分类号： B01J23/68
摘要： The present disclosure provides novel mixed molybdenum catalysts, methods for preparing epoxides from olefins, and methods of making the mixed molybdenum catalysts. In one embodiment, the mixed molybdenum catalysts may be silver/molybdenum catalysts, ruthenium/molybdenum catalysts, or a combination thereof.
摘要翻译：本公开提供了新型混合钼催化剂，由烯烃制备环氧化物的方法以及制备混合钼催化剂的方法。在一个实施方案中，混合钼催化剂可以是银/钼催化剂，钌/钼催化剂或其组合。

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