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1. 发明申请

WO1993000368A1 SUPPORTED HIGH ACTIVITY POLYOLEFIN CATALYST COMPONENT WITH REGULAR DISTRIBUTION OF MAGNESIUM VALUES PROVIDED UTILIZING A CONTROLLED DRYING PROTOCOL 审中-公开
标题翻译：支持的高活性聚烯烃催化剂组分，通过使用控制干燥协议提供的镁值的定期分布
公开(公告)号：WO1993000368A1
公开(公告)日：1993-01-07
申请号：PCT/US1992005069
申请日：1992-06-19
申请人： QUANTUM CHEMICAL CORPORATION
发明人： QUANTUM CHEMICAL CORPORATION , BUEHLER, Charles, K. , MASINO, Albert, P. , MENON, Raghu
IPC分类号： C08F04/654
CPC分类号： C08F10/00 , C08F4/6565 , C08F4/6567 , C08F4/6578
摘要： A novel catalyst support and a method for preparation thereof, characterized by the presence of selected amounts of a hydrocarbon soluble magnesium-containing compound applied to the support relative to solvent, wherein a surface uniformly and essentially continuously moistened with the solvated magnesium compound is achieved in a condition of incipient precipitation to permit the formation of a regular essentially continuous distribution of the magnesium compound onto and conforming to the support material. The drying process under these conditions is effective in maintaining to a high degree the effective surface area and pore volume of the material. The support containing the adsorbed magnesium in then dried in a controlled manner to essential incipient wetness conditions providing a regular spatial distribution of stacked reticular magnesium values at a level of one to five molecular monolayers on the support. A representative process for polymerizing or copolymerizing olefins providing stereospecific polymers such as propylene is disclosed.
摘要翻译：一种新颖的催化剂载体及其制备方法，其特征在于相对于溶剂存在选择量的可溶于烃的可溶性镁化合物，其中用溶剂化镁化合物均匀且基本上连续润湿的表面在初始沉淀的条件允许形成规则的基本上连续的镁化合物分布到载体材料上并与之相符合。在这些条件下的干燥过程有效地保持材料的有效表面积和孔体积的高度。含有吸附的镁的载体以受控的方式干燥以达到必需的初始湿度条件，从而提供在载体上1-5个分子单层水平的堆叠网状镁值的规则空间分布。公开了提供立体特异性聚合物如丙烯的烯烃聚合或共聚的代表性方法。

2. 发明申请

WO1994016816A1 FOUR COMPONENT POLYMERIZATION CATALYST 审中-公开
标题翻译：四组分聚合催化剂
公开(公告)号：WO1994016816A1
公开(公告)日：1994-08-04
申请号：PCT/US1994000667
申请日：1994-01-26
申请人： QUANTUM CHEMICAL CORPORATION
发明人： QUANTUM CHEMICAL CORPORATION , MENON, Raghu , MASINO, Albert, P. , REINKING, Mark, K.
IPC分类号： B01J31/00
CPC分类号： C08F10/00 , B01J21/08 , B01J31/0254 , B01J31/0274 , B01J31/128 , B01J31/143 , B01J35/023 , B01J35/1019 , B01J35/1047 , C08F4/6265 , C08F4/685
摘要： A catalyst which comprises (a) a solid catalyst component which includes a magnesium-containing agent and at least one transition metal-containing agent; (b) an organometallic compound where the metal is a metal of Group II or Group III of the Periodic Table of the Elements; (c) a hydrocarbylhydrocarbyloxysilane compound; and (d) a halosilane compound is disclosed. This catalyst is useful in the polymerization of olefins.
摘要翻译：一种催化剂，其包含（a）包含含镁试剂和至少一种含过渡金属的试剂的固体催化剂组分; （b）有机金属化合物，其中金属是元素周期表第II族或第III族的金属; （c）烃基氢氧化硅烷化合物; 和（d）卤代硅烷化合物。该催化剂可用于烯烃的聚合。

3. 发明申请

WO1991017190A1 OLEFIN POLYMERIZATION CATALYST AND METHODS 审中-公开
标题翻译：烯烃聚合催化剂和方法
公开(公告)号：WO1991017190A1
公开(公告)日：1991-11-14
申请号：PCT/US1991002900
申请日：1991-04-26
申请人： QUANTUM CHEMICAL CORPORATION
发明人： QUANTUM CHEMICAL CORPORATION , MASINO, Albert, P.
IPC分类号： C08F04/64
CPC分类号： C08F10/00 , C08F4/6565
摘要： A solid catalyst component, a method of making the same, a catalyst system incorporating the solid catalyst component, and a method of polymerizing one or more 1-olefins using the catalyst system are disclosed wherein the catalyst component is prepared by contacting, in the presence of an inert liquid hydrocarbon, silica, a soluble organomagnesium compound, an SiCl4 magnesium fixing agent, an alcohol, TiCl4, and a diester compound, followed by extraction with a TiCl4-containing extraction liquid. The inventive catalyst system allows ready control of product molecular weight by control of hydrogen concentration in the reactor, and allows the production of high MI or MF polymers at high productivities.

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