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    • 4. 发明申请
    • AQUEOUS FLUOROPOLYMER DISPERSIONS
    • 水性氟聚合物分散体
    • WO1996003447A1
    • 1996-02-08
    • PCT/US1995008649
    • 1995-07-11
    • PPG INDUSTRIES, INC.
    • PPG INDUSTRIES, INC.DAS, Suryya, K.KILIC, Soner
    • C08F214/18
    • C08F216/14C08F214/24C09D127/12C08L2666/02
    • A stable, aqueous fluorocopolymer dispersion prepared by aqueous dispersion polymerization of: a) a dispersed phase containing a fluoroolefin monomer component and a vinyl ether monomer component in the presence of b) a base neutralized, stable aqueous dispersion of a polymeric dispersant having an acid value of at least 1.5 mg KOH/gram not exceeding about 35 mg KOH/gram and the amount of neutralizing base does not exceed about 10 % based on resin solids of the dispersant. The acid value is adapted to provide a stable dispersion of the fluorocopolymer in water without externally added surfactant. Thermoplastic and thermosetting coating compositions can be prepared from these aqueous fluorocopolymer dispersions.
    • 一种通过水分散聚合制备的稳定的含氟含氟共聚物分散体,其分散体为:a)在含有酸值的聚合物分散剂的碱中和稳定的水分散体的存在下,含有氟烯烃单体组分和乙烯基醚单体组分的分散相 至少1.5mg KOH / g不超过约35mg KOH / g,并且基于分散剂的树脂固体,中和碱的量不超过约10%。 酸值适于提供含氟共聚物在水中的稳定分散体,而不需要外部添加的表面活性剂。 热塑性和热固性涂料组合物可由这些含氟共聚物含水分散体制备。
    • 6. 发明申请
    • STABLE AQUENOUS DISPERTIONS OF CELLULOSE ESTERS, METHOD OF MAKING AND THEIR USE IN COATINGS
    • 纤维素酯的稳定分布,制备方法及其在涂料中的用途
    • WO1997049739A1
    • 1997-12-31
    • PCT/US1997010020
    • 1997-06-11
    • PPG INDUSTRIES, INC.
    • PPG INDUSTRIES, INC.DAS, Suryya, K.KILIC, SonerMCMILLAN, Robyn, E.
    • C08F251/02
    • C08F251/02
    • A stable aqueous dispersion containing cellulose ester, the dispersion being polymeric microparticles comprised of cellulose ester and a polymer formed from at least two different vinyl monomers of which at least one vinyl monomer is polyethylenically unsaturated. The dispersion of microparticles is formed by a high stress technique prior to polymerization of the vinyl monomers in the presence of the cellulose ester. Typically, the dispersion also contains surfactant. A method of making the stable, cellulose ester-containing aqueous dispersion by: (a) mixing together a cellulose ester, at least two vinyl monomers of which at least one vinyl monomer is polyethylenically unsaturated, surfactant, and water to form an emulsion; (b) particulating the emulsified mixture of (a) into microparticles by a high stress technique; and (c) copolymerizing the vinyl monomers in the cellulose ester-containing particulated emulsion of (b) to form a cross-linked polymer within the microparticles of the dispersion. Also, aqueous coating compositions formed from the stable cellulose ester-containing aqueous dispersion; cross-linking material; and, optionally, additional film forming resins. The aqueous coating compositions can also contain pigments. The coating compositions are very advantageous, particularly in automotive base coats containing metallic pigments and exhibit good humidity resistance, appearance, adhesion and chip resistance when used in an automotive "low bake repair" process.
    • 一种含有纤维素酯的稳定的含水分散体,该分散体是由纤维素酯组成的聚合物微粒和由至少两种乙烯基单体形成的聚合物,其中至少一种乙烯基单体是多烯属不饱和的。 在纤维素酯存在下,在乙烯基单体聚合之前,通过高应力技术形成微粒的分散体。 通常,分散体还含有表面活性剂。 通过以下方法制备含纤维素酯的水分散体的方法:(a)将纤维素酯,至少两种乙烯基单体混合在一起,所述乙烯基单体至少一种乙烯基单体是多烯属不饱和的,表面活性剂和水以形成乳液; (b)通过高应力技术使(a)的乳化混合物微粒化; 和(c)使(B)的含纤维素酯的微粒乳液中的乙烯基单体共聚以在分散体的微粒内形成交联聚合物。 此外,由含稳定的含纤维素酯的水分散体形成的水性涂料组合物; 交联材料; 和任选的另外的成膜树脂。 水性涂​​料组合物还可以含有颜料。 涂料组合物非常有利,特别是在用于汽车“低温烘烤修复”方法中的含有金属颜料的汽车底涂层中并且表现出良好的耐湿性,外观,粘附性和抗碎屑性。
    • 7. 发明申请
    • POLYISOCYANATE CURED ULTRADURABLE GLOSSY COATING COMPOSITIONS
    • POLYISOCYANATE固化超可塑性涂料组合物
    • WO1997022646A1
    • 1997-06-26
    • PCT/US1996017724
    • 1996-11-05
    • PPG INDUSTRIES, INC.
    • PPG INDUSTRIES, INC.DAS, Suryya, K.KILIC, SonerLAUER, Andrew, J.
    • C08G18/62
    • C08G18/6229
    • A curable, film-forming composition is provided which includes: (a) a hydroxyl-containing acrylic solution polymer, and (b) a polyisocyanate cross-linking agent. The hydroxyl-containing acrylic solution polymer is present in an amount ranging from between about 60 to about 90 weight percent; and, the polyisocyanate cross-linking agent is present in an amount ranging from between about 10 to about 40 weight percent. The acrylic solution polymer is the reaction product of: (a) a cycloaliphatic and/or aromatic ester of (meth)acrylic acid having at least 6 carbon atoms in the cycloaliphatic and/or aromatic group, and (b) a hydroxyl functional acrylic monomer component. The hydroxy functional acrylic monomer component does not contain a significant concentration of 4-hydroxy-n-butylacrylate or 4-hydroxy-n-butylmethacrylate or a mixture thereof. Moreover, the hydroxyl functional acrylic monomer component is present in an amount such that the hydroxyl number of the resulting acrylic solution polymer is less than about 200. This invention also provides a color-plus-clear coating system. This system includes: (a) applying a film-forming base coat onto a substrate, and (b) applying a clear, film-forming topcoat over the base coat. The clear topcoat includes the curable, film-forming composition described above.
    • 提供一种可固化的成膜组合物,其包括:(a)含羟基的丙烯酸溶液聚合物,和(b)多异氰酸酯交联剂。 含羟基的丙烯酸溶液聚合物的存在量为约60至约90重量%; 多异氰酸酯交联剂的存在量为约10至约40重量%。 丙烯酸溶液聚合物是:(a)在脂环族和/或芳族基团中具有至少6个碳原子的(甲基)丙烯酸的脂环族和/或芳族酯的反应产物,和(b)羟基官能的丙烯酸单体 零件。 羟基官能丙烯酸单体组分不含有显着浓度的丙烯酸4-羟基 - 正丁酯或甲基丙烯酸4-羟基 - 正丁酯或其混合物。 此外,羟基官能的丙烯酸单体组分的存在量使得所得丙烯酸溶液聚合物的羟值低于约200.本发明还提供了一种颜色加透明的涂料体系。 该系统包括:(a)将成膜基底涂层施加到基底上,和(b)在底涂层上涂布透明的成膜面漆。 透明面漆包括上述可固化的成膜组合物。
    • 8. 发明申请
    • POLYISOCYANATE CURED ULTRADURABLE GLOSSY COATING COMPOSITIONS
    • POLYISOCYANATE固化超可塑性涂料组合物
    • WO1997022645A1
    • 1997-06-26
    • PCT/US1996017595
    • 1996-11-04
    • PPG INDUSTRIES, INC.
    • PPG INDUSTRIES, INC.DAS, Suryya, K.KILIC, SonerLAUER, Andrew, J.
    • C08G18/62
    • C08G18/6229
    • A curable, film-forming composition is provided which includes: (a) a hydroxyl-containing acrylic solution polymer, and (b) a polyisocyanate cross-linking agent. The hydroxyl-containing acrylic solution polymer is present in an amount ranging from between about 60 to about 90 weight percent; and, the polyisocyanate cross-linking agent is present in an amount ranging from between about 10 to about 40 weight percent. The acrylic solution polymer is the reaction product of: (a) a cycloaliphatic and/or aromatic ester of (meth)acrylic acid having at least 6 carbon atoms in the cycloaliphatic and/or aromatic group, and (b) a hydroxyl functional acrylic monomer component. The hydroxyl functional acrylic monomer component is present in an amount such that the hydroxyl number of the resulting acrylic solution polymer is less than 60. This invention also provides a color-plus-clear coating system. This system includes: (a) applying a film-forming base coat onto a substrate, and (b) applying a clear, film-forming topcoat over the base coat. The clear topcoat includes the curable, film-forming composition described above.
    • 提供一种可固化的成膜组合物,其包括:(a)含羟基的丙烯酸溶液聚合物,和(b)多异氰酸酯交联剂。 含羟基的丙烯酸溶液聚合物的存在量为约60至约90重量%; 多异氰酸酯交联剂的存在量为约10至约40重量%。 丙烯酸溶液聚合物是:(a)在脂环族和/或芳族基团中具有至少6个碳原子的(甲基)丙烯酸的脂环族和/或芳族酯的反应产物,和(b)羟基官能的丙烯酸单体 零件。 羟基官能丙烯酸单体组分的存在量使得所得丙烯酸溶液聚合物的羟值小于60.本发明还提供了一种颜色加透明的涂料体系。 该系统包括:(a)将成膜基底涂层施加到基底上,和(b)在底涂层上涂布透明的成膜面漆。 透明面漆包括上述可固化的成膜组合物。