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1. 发明申请

WO0144376B1 PIGMENT DISPERSIONS CONTAINING DISPERSANTS PREPARED BY CONTROLLED RADICAL POLYMERIZATION AND HAVING PENDANT HYDROPHILIC POLYMERIC SEGMENTS 审中-公开
标题翻译：含有分散剂的颜料分散体由控制的自由基聚合制备并具有悬浮聚合物聚合物部分
公开(公告)号：WO0144376B1
公开(公告)日：2001-11-22
申请号：PCT/US0034319
申请日：2000-12-13
申请人： PPG IND OHIO INC
发明人： WOODWORTH BRIAN E , COCA SIMION , O'DWYER JAMES B
IPC分类号： C09B67/20 , C09B67/46 , C09B67/00
CPC分类号： C09B67/0085 , C09B67/0066
摘要： A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of a radically polymerizable monomer in the presence of a polymeric initiator having at least one radically transferable group. The polymeric initiator forms the polymeric backbone segment of the pigment dispersant, and the monomer forms polymeric segments that are pendent to the polymeric backbone segment. The pigment dispersant has comb-like architecture in which the polymeric backbone segment is hydrophobic, and at least a portion of each pendent polymeric segment is hydrophilic.
摘要翻译：描述了包含颜料的颜料分散体，选自水和水和至少一种有机溶剂的混合物的水性载体和颜料分散剂。在具有至少一个可自由基转移基团的聚合物引发剂的存在下，通过可自由基聚合的单体的可控自由基聚合，例如原子转移自由基聚合制备颜料分散剂。聚合物引发剂形成颜料分散剂的聚合物主链段，并且单体形成与聚合物骨架链段相反的聚合链段。颜料分散剂具有梳状结构，其中聚合物骨架链段是疏水性的，并且每个侧链聚合链段的至少一部分是亲水的。

2. 发明申请

WO02070575A2 ACRYLIC-HALOGENATED POLYOLEFIN COPOLYMER ADHESION PROMOTERS 审中-公开
标题翻译：丙烯酸聚合物共聚物粘合促进剂
公开(公告)号：WO02070575A2
公开(公告)日：2002-09-12
申请号：PCT/US0148305
申请日：2001-12-11
申请人： PPG IND OHIO INC
发明人： COCA SIMION , REARICK BRIAN K , O'DWYER JAMES B
IPC分类号： C08F4/00 , C08F293/00 , C08J7/04
CPC分类号： C08F4/00 , C08F293/005 , C08F2438/01
摘要： The present invention is directed to a method for producing a copolymer and a copolymer product of the method. The copolymer is prepared by a controlled radical polymerization process, typically an atom transfer radical polymerization process, in which polymerizable alkene monomers are polymerized in the presence of a halogenated polyolefin macroinitiator. The copolymer product of this process is useful in a film-forming composition that adheres strongly to polyolefinic substrates and to which non-polyolefinic film-forming compositions strongly adhere. The copolymer can be applied to a substrate in an adhesion-promoting layer or can be incorporated into a film-forming composition, such as a primer, that contains additional resinous compounds.
摘要翻译：本发明涉及一种制备该方法的共聚物和共聚物的方法。共聚物通过受控自由基聚合方法制备，通常是原子转移自由基聚合方法，其中可聚合烯烃单体在卤代聚烯烃大分子引发剂存在下聚合。该方法的共聚物产物可用于强烈粘附到聚烯烃基材上并且非聚烯烃成膜组合物强烈粘附的成膜组合物。共聚物可以施加到粘合促进层中的基材上，或者可以加入到含有另外的树脂化合物的成膜组合物如引物中。

3. 发明申请

WO0230996A3 MULTI-FUNCTIONAL INITIATORS FOR ATOM TRANSFER RADICAL POLYMERIZATION 审中-公开
标题翻译：原子转移自由基聚合的多功能引发剂
公开(公告)号：WO0230996A3
公开(公告)日：2002-07-11
申请号：PCT/US0132141
申请日：2001-10-12
申请人： PPG IND OHIO INC
发明人： OLSON KEVIN C , O'DWYER JAMES B , COCA SIMION
IPC分类号： C08F4/00 , C08F4/40
CPC分类号： C08F4/00
摘要： The present invention is directed to a controlled radical polymerization process in which novel (co)polymers are prepared using alkylene bis-(dialkyl 2-halomalonate) initiators, such as a methylene bis-(diethyl 2-bromomalonate). The present invention is also directed to novel (co)polymer products of the process.
摘要翻译：本发明涉及一种受控自由基聚合方法，其中使用亚烷基双 - （二烷基2-卤代丙二酸酯）引发剂如亚甲基双 - （2-溴丙二酸二乙酯）制备新型（共）聚合物。本发明还涉及该方法的新型（共）聚合物产物。

4. 发明申请

WO03070795B1 COPOLYMERS COMPRISING ISOBUTYLENE TYPE AND ACRYLATE TYPE MONOMERS 审中-公开
标题翻译：包含异丁烯类型和丙烯酸酯类单体的共聚物
公开(公告)号：WO03070795B1
公开(公告)日：2003-12-18
申请号：PCT/US0303983
申请日：2003-02-10
申请人： PPG IND OHIO INC
发明人： COCA SIMION , MCCOLLUM GREGORY J , O'DWYER JAMES B , COLERIDGE EDWARD R , BARANCYK STEVEN V
IPC分类号： B05D1/00 , B05D3/02 , B05D3/06 , B05D7/00 , C08F8/00 , C08F210/10 , C08F220/10 , C09D123/22 , C08F220/12
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C09D123/22 , C08F220/12 , C08L2666/28
摘要： A composition that includes a non-gelled copolymer that contains residues having structural units (Formula I) where n is an integer from 1 to 10,000; R is linear or branched C1 to C4 alkyl; R is selected from the group consisting of methyl, linear, cyclic or branched C2 to C20 alkyl, alkenyl, aryl, alkaryl and aralkyl, and R is a group resulting from a post polymerization reaction selected from transesterification, transamidification and hydrolysis with a compound selected from hydroxy functional compounds and amine functional compounds. The compositionmay contain co-reactive functional groups and may be a thermosetting composition. A substrate may be coated with the thermosetting composition singly or as part of a multi-layer composite coating that includes a base coat layer and a substantially pigment free top coat layer.
摘要翻译：一种包含非凝胶共聚物的组合物，其含有具有结构单元（式I）的残基，其中n为1至10,000的整数; R 1是直链或支链C 1至C 4烷基; R 2选自甲基，直链，环状或支链C 2至C 20烷基，烯基，芳基，烷芳基和芳烷基，R 3是由后聚合反应产生的基团，其选自酯交换反应，并用选自羟基官能化合物和胺官能化合物的化合物水解。该组合物可以含有共反应性官能团并且可以是热固性组合物。基材可以单独地涂覆有热固性组合物，或者作为多层复合涂层的一部分，其包括底涂层和基本上不含颜料的顶涂层。

5. 发明申请

WO0075791A3 BLOCK COPOLYMERS PREPARED BY CONTROLLED RADICAL POLYMERIZATION AND THEIR USE AS FLOW MODIFIERS 审中-公开
标题翻译：通过控制的自由基聚合制备的嵌段共聚物及其作为流动改性剂的使用
公开(公告)号：WO0075791A3
公开(公告)日：2001-02-01
申请号：PCT/US0015202
申请日：2000-06-02
申请人： PPG IND OHIO INC
发明人： SCHIMMEL KARL F , BARKAC KAREN A , HUMBERT KURT A , GOETZ JONATHAN D , O'DWYER JAMES B
IPC分类号： C08F287/00 , C08F293/00 , C08F297/00 , C08L53/00 , C09D5/03 , C09D153/00 , C09D163/00 , C09D201/00 , C09D201/02 , C09D201/06
CPC分类号： C08L53/00 , C08F293/005 , C09D153/00
摘要： Provided are block copolymers containing at least two blocks are provided and comprise: (a) a first block containing residues of at least one first ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., 2-ethylhexyl methacrylate, and, optionally, a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer, e.g., hydroxypropyl methacrylate; and (b) a second block containing residues of at least one second ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., iso-butyl methacrylate, and, optionally, a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer. The calculated Tg of the second monomer of the block copolymer is at least 20 DEG C greater than the calculated Tg of the first monomer. Also provided are thermosetting coating compositions that contain the block copolymers as flow additives.
摘要翻译：提供含有至少两个嵌段的嵌段共聚物，其包含：（a）含有至少一种不含羟基官能团的至少一种第一烯属不饱和自由基聚合性单体残基的第一嵌段，例如甲基丙烯酸2-乙基己酯，少量的至少一种羟基官能烯属不饱和自由基聚合单体，例如甲基丙烯酸羟丙酯; 和（b）含有至少一种不含羟基官能团的第二烯属不饱和自由基可聚合单体的残基的第二嵌段，例如甲基丙烯酸异丁酯，以及任选地少量的至少一种羟基官能烯属不饱和可自由基聚合的单体。嵌段共聚物的第二单体的计算Tg比第一单体的计算Tg高至少20℃。还提供含有作为流动添加剂的嵌段共聚物的热固性涂料组合物。

6. 发明申请

WO2006039658A2 THERMOSETTING COATING COMPOSITIONS COMPRISING A COPOLYMER FORMED FROM CHLOROTRIFLUOROETHYLENE AND METHODS OF MAKING COPOLYMERS FORMED FROM CHLOROTRIFLUOROETHYLENE 审中-公开
标题翻译：包含由氯离子乙烯形成的共聚物的热固化涂料组合物和由氯化三氟乙烯形成的共聚物的方法
公开(公告)号：WO2006039658A2
公开(公告)日：2006-04-13
申请号：PCT/US2005035501
申请日：2005-09-30
申请人： PPG IND OHIO INC
发明人： COCA SIMION , COLERIDGE EDWARD R , O'DWYER JAMES B , WOODWORTH BRIAN E
IPC分类号： C08K5/00 , C08F8/00 , C08F214/24 , C08L27/02 , C08L27/22
CPC分类号： C08F8/00 , C08F214/18 , C08F214/24 , C08K5/0025 , C09D127/12 , D06M15/277 , C08L27/12
摘要： Fluoropolymers are disclosed. The fluoropolymers include (i) units derived from a fluoromonomer composition comprising chlorotrifluoroethylene, and (ii) units derived from at least one donor monomer composition. In the disclosed fluoropolymers, units (i) and (ii) are distributed along the fluoropolymer chain in a substantially alternating fashion. Also disclosed are thermosetting compositions containing such fluoropolymers, substrates coated with such compositions, methods for making such compositions, and methods for coating substrates with such compositions.
摘要翻译：公开了含氟聚合物。含氟聚合物包括（i）衍生自包含氯三氟乙烯的含氟单体组合物的单元，和（ii）衍生自至少一种供体单体组合物的单元。在所公开的含氟聚合物中，单元（i）和（ii）以基本交替的方式沿着含氟聚合物链分布。还公开了含有这样的含氟聚合物的热固性组合物，用这种组合物涂覆的基材，制备这种组合物的方法，以及用这种组合物涂覆基材的方法。

7. 发明申请

WO03070826A2 POWDER COATING COMPOSITIONS HAVING IMPROVED MAR AND ACID RESISTANCE 审中-公开
标题翻译：粉末涂料组合物具有改善的抗酸性和耐酸性
公开(公告)号：WO03070826A2
公开(公告)日：2003-08-28
申请号：PCT/US0304193
申请日：2003-02-12
申请人： PPG IND OHIO INC
发明人： RECHENBERG KAREN S , COCA SIMION , BARKAC KAREN A , O'DWYER JAMES B , BOWSER LINDA J
IPC分类号： B05D7/24 , B05D1/00 , B05D3/02 , B05D3/06 , B05D7/00 , B32B27/30 , C08F8/00 , C08F210/00 , C08F210/10 , C08F210/14 , C08F220/10 , C08F290/04 , C08G18/62 , C08G18/79 , C08G18/80 , C08K5/092 , C08L23/20 , C08L23/22 , C08L33/06 , C08L33/14 , C08L63/00 , C08L101/00 , C09D7/12 , C09D109/00 , C09D109/02 , C09D123/22 , C09D133/00 , C09D133/02 , C09D133/06 , C09D133/08 , C09D133/14 , C09D133/24 , C09D157/04 , C09D163/00 , C09D167/00 , C09D175/04 , C09D201/00 , B05D7/26 , C09D5/03
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes a co-reactable solid, particulate mixture of a film forming material having functional groups and a crosslinking agent having at least two functional groups that are reactive with the functional groups in the film forming material. The crosslinking agent includes a copolymer having at least 30 mol % of alternating structural units of a residue from a donor monomer and a residue from one or more acrylic acceptor monomers. The thermosetting composition may coat a substrate by coalescing the composition to form a continuous film and curing the composition. The thermosetting composition may be included as part of a multi-component composite coating composition that includes an optional primer coat, a base coat deposited from a pigmented film-forming composition, and a transparent top coat applied over the base coat, where either the base coat, the transparent top coat, or both, are deposited from the thermosetting composition.
摘要翻译：一种热固性组合物，其包含具有官能团的成膜材料和具有至少两个可与成膜材料中的官能团反应的官能团的交联剂的可共反应固体颗粒混合物。交联剂包括具有至少30摩尔％的来自供体单体的残基和来自一种或多种丙烯酸受体单体的残基的交替结构单元的共聚物。该热固性组合物可以通过聚结该组合物以形成连续膜并固化该组合物来涂覆基底。所述热固性组合物可作为多组分复合涂料组合物的一部分被包括，所述组合物包含任选的底漆涂层，从着色成膜组合物沉积的底漆和施涂在底漆上的透明顶涂层，其中底漆涂层，透明面涂层或两者由热固性组合物沉积。

8. 发明申请

WO0230992A3 MULTI-FUNCTIONAL INITIATORS FOR ATOM TRANSFER RADICAL (CO)POLYMERIZATION 审中-公开
标题翻译：原子转移自由基（CO）聚合的多功能引发剂
公开(公告)号：WO0230992A3
公开(公告)日：2002-08-22
申请号：PCT/US0142705
申请日：2001-10-12
申请人： PPG IND OHIO INC
发明人： O'DWYER JAMES B , OLSON KEVIN C , COCA SIMION , WOODWORTH BRIAN E
IPC分类号： C08F2/00 , C08F4/00 , C08F4/40 , C09B67/46 , C09D17/00
CPC分类号： C09D17/001 , C08F4/00 , C09B67/009
摘要： The present invention is directed to novel compounds that can serve as highly efficient initiators for controlled radical (co)polymerization processes including atom transfer radical (co)polymerization processes. These compounds include di-(trimethylolpropane)-tetra-(2-haloisobutyrate) compounds. The present invention also is directed to controlled radical (co)polymerization processes in which novel (co)polymers are prepared using the novel compounds, as well as to the novel (co)polymer products of the process.
摘要翻译：本发明涉及可用作用于受控自由基（共）聚合过程（包括原子转移自由基（共）聚合过程）的高效引发剂的新型化合物。这些化合物包括二（三羟甲基丙烷） - 四（2-卤代异丁酸酯）化合物。本发明还涉及受控的自由基（共）聚合方法，其中使用该新型化合物制备新型（共）聚合物，以及该方法的新型（共）聚合物产物。

9. 发明申请

WO0144388A3 PIGMENT DISPERSIONS CONTAINING DISPERSANTS HAVING PENDENT HYDROPHILIC POLYMERIC SEGMENTS PREPARED BY CONTROLLED RADICAL POLYMERIZATION 审中-公开
标题翻译：含有分散剂的颜料分散体，具有由控制的自由基聚合制备的先进的水解聚合物部分
公开(公告)号：WO0144388A3
公开(公告)日：2002-08-08
申请号：PCT/US0034322
申请日：2000-12-13
申请人： PPG IND OHIO INC
发明人： COCA SIMION , MCCOLLUM GREGORY J , O'DWYER JAMES B , WOODWORTH BRIAN E
IPC分类号： C09B67/20 , C09B67/46 , C09D17/00 , C09B67/00
CPC分类号： C09D17/001 , C09B67/0066 , C09B67/009
摘要： A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by polymerizing (i) at least one prepolymer having a radically polymerizable group, and (ii) at least one second monomer. The prepolymer is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of at least one radically polymerizable first monomer. The second monomer forms a polymeric backbone segment of the pigment dispersant, and the prepolymer forms polymeric segments that are pendent to the backbone. The backbone segment of the pigment dispersant in hydrophobic, while at least a portion of each pendent polymeric segment is hydrophilic.
摘要翻译：描述了包含颜料，选自水和水与至少一种有机溶剂的混合物的水性载体和颜料分散剂的颜料分散体。通过聚合（i）至少一种具有自由基聚合性基团的预聚物和（ii）至少一种第二单体来制备颜料分散剂。预聚物通过至少一种可自由基聚合的第一单体的受控自由基聚合，例如原子转移自由基聚合制备。第二单体形成颜料分散剂的聚合物主链段，并且预聚物形成与主链相关的聚合物链段。疏水性的颜料分散剂的骨架部分，而每个侧链聚合物链段的至少一部分是亲水的。

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