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    • 2. 发明申请
    • METHOD FOR MANUFACTURING OPTICAL DEVICES
    • 制造光学器件的方法
    • WO2006012915A1
    • 2006-02-09
    • PCT/EP2004/008839
    • 2004-08-05
    • PIRELLI & C. S.p.A.COLOMBO, MarcoOSMOND, JohannZAOPO, Antonio
    • COLOMBO, MarcoOSMOND, JohannZAOPO, Antonio
    • B29D11/00
    • B29D11/00663
    • The present invention relates to a method for manufacturing an organic optical device (1) comprising at least one fluorinated polymer optical waveguide. The method of the invention comprises the steps of providing an elastomeric mold (2) with a patterned surface, oxidizing the patterned surface of the elastomeric mold (2), providing a core layer (7) of a fluorinated polymeric material, patterning the core layer (7) by means of the oxidized patterned surface of the elastomeric mold (2), and removing the elastomeric mold (2) from the patterned core layer (7). The above-mentioned oxidation step of the elastomeric mold (2) is preferably carried out by inductive coupled plasma. The mold (2) is advantageously both wettable with respect to the fluorinated polymeric material and releasable from the patterned core layer (7).
    • 本发明涉及一种制造包含至少一种氟化聚合物光波导的有机光学器件(1)的方法。 本发明的方法包括以下步骤:提供具有图案化表面的弹性体模具(2),氧化弹性体模具(2)的图案化表面,提供氟化聚合物材料的芯层(7),图案化芯层 (7)通过所述弹性体模具(2)的氧化图案化表面,以及从所述图案化芯层(7)移除所述弹性体模具(2)。 弹性体模具(2)的上述氧化步骤优选地通过电感耦合等离子体进行。 模具(2)有利地相对于氟化聚合物材料是可润湿的并且可从图案化的芯层(7)释放。
    • 3. 发明申请
    • OPTICAL DEVICE AND POLYMER MATERIAL WITH NONLINEAR OPTICAL PROPERTIES
    • 光学器件和具有非线性光学特性的聚合物材料
    • WO2008017318A1
    • 2008-02-14
    • PCT/EP2006/007857
    • 2006-08-08
    • PIRELLI & C. S.P.A.COLOMBO, MarcoZAOPO, AntonioGERBELLA, Giorgio
    • COLOMBO, MarcoZAOPO, AntonioGERBELLA, Giorgio
    • G02F1/361C08F2/50
    • C08F2/50G02F1/3617
    • Optical device comprising: (a) a substrate; (b) at least one core layer including a polymer material with nonlinear optical properties comprising at least one copolymer obtained by copolymerizing at least one monomer or oligomer having at least two polymerizable groups, said at least one monomer or oligomer being at least partially fluorinated, with at least one optically active cromophore having at least two polymerizable groups able to react with the polymerizable groups of said at least one monomer or oligomer. Said optical device may be an optical waveguide, an optical modulator, an electrooptical modulator, an optical switch, a frequency converter, an optical parametric oscillator, an optical parametric amplifier, or a data processor. Preferably, said optical device is an electrooptical modulator.
    • 光学装置,包括:(a)基板; (b)至少一个核心层,包括具有非线性光学性质的聚合物材料,该聚合物材料包含至少一种共聚物,所述共聚物通过共聚至少一种具有至少两个可聚合基团的单体或低聚物,所述至少一种单体或低聚物至少部分氟化, 其中至少一种具有至少两个能够与所述至少一种单体或低聚物的可聚合基团反应的可聚合基团的光学活性色素体。 所述光学器件可以是光波导,光调制器,电光调制器,光开关,变频器,光参量振荡器,光参量放大器或数据处理器。 优选地,所述光学装置是电光调制器。