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    • 7. 发明申请
    • PHOSPHAZENIUM SALT MIXTURES CONTAINING HEXAKIS(AMINO)DIPHOSPHAZENIUM, TETRAKIS(AMINO)-PHOSPHONIUM AND POLYAMINOPHOSPAZENIUM SALTS
    • 磷氮杂MIXES含六(氨基)Diphosphazenium,四(氨基)磷和POLYAMINOPHOSPAZENIUM盐类
    • WO2004074296A3
    • 2005-03-03
    • PCT/EP2004001253
    • 2004-02-11
    • CLARIANT GMBHWESSEL THOMASDECKER DANIELSOMMER THOMASHUENIG HAGENSCHWESINGER REINHARD
    • WESSEL THOMASDECKER DANIELSOMMER THOMASHUENIG HAGENSCHWESINGER REINHARD
    • B01J31/02C07B39/00C07C17/20C07C45/63C07F9/572C07F9/59C07F9/06
    • B01J31/0268B01J31/0239B01J31/0265B01J2231/40C07B39/00C07C17/208C07C45/63C07F9/5721C07F9/591C07C47/55
    • The invention relates to mixtures containing 5 99.5 wt. % of a compound of formula (I), 95 0.5 wt. % of a compound of formula (II) and a maximum of 10 wt. % of one of several compounds of general formula (III a), wherein A - A which are independent from each other are equal or different and represent a straight-chained or branched alkyl or alkenyl having 1 - 12 carbon atoms, cycloalkyl having 4 8 carbon atoms, an aryl having 6 -12 carbon atoms, an aralkyl having 7 - 12 carbon atoms, or A -A , A -A , A -A etc. - A -A which are independent from each other and are equal or different and are connected together directly or via O or N-A to a ring having 3 - 7 ring members, A represents an alkyl having 1 - 4 carbon atoms. X1 and/or X2 and/or X3 which are independent from each other represent a radical of formula (III b), or the radical X1 and/or X2 and/or X3 as well as a straight-chained or branched alkyl or alkenyl having 1 - 12 carbon atoms, cycloalkyl having 4 - 8 carbon atoms represent an aryl having 6 - 12 carbon atoms, an aralkyl having 7 - 12 carbon atoms, or respectively the radicals which are disposed on an identically bound nitrogen atom, e.g. A and A , A and A , A and A etc. - A and A which are independent from each other are equal or different and are connected together directly or via O or N-A to a ring having 3 - 7 ring members and A represents an alkyl having 1 - 4 carbon atoms and B represents a single-valent organic or inorganic acid radical or the equivalent of a multi-valent acid radical. The mixtures can be used as catalysts and co-catalysts for phase transfer reactions, nucleophilic substitution reactions or halogen-fluoro-exchange reactions.
    • 含有5混合物至99.5重量式(I)的化合物的%,95至0.5重量下式的化合物的%(II)和至多10重量通式的一种或多种化合物的%( III a),其中一个<1>到<32>独立地,相同或不同,表示直链或支链烷基或碳原子数1〜12的链烯基,具有环烷基为4〜8个碳原子,具有芳基为6〜12个碳原子 ,具有7至12个碳原子,或芳烷基一<1> -A <2>中,<3> -A <4>中,<5> -A <6>等,以一<31> -A < 32>独立地,相同或不同的,并直接或通过O或NA <33>连接在一起以形成具有3至7个环成员的环,<33>表示碳原子数1〜4的烷基,其中X 1和/或 X2和/或X3独立地是式的基团(III b)或基团X 1和/或X 2和/或X 3是也直链或支链烷基或具有1至烯12K个 ohlenstoffatomen,碳原子数为4〜8,具有6至12个碳原子,碳原子数7〜12的芳烷基,或在每种情况下其位于一个相同键合氮原子的基团,例如芳基环烷基 A <1>和A <2>,A <3>和A <4>中,A <5>和A <6>是,依此类推,以A <31>和A <32>彼此独立地相同或不同的直 或通过O或NA <33>被连接到彼此,以形成具有3至7个环成员和一个环的<33>表示具有1至4个碳原子和B的烷基< - >为一价的有机或无机酸基团或一价的等效 酸根看台。 的混合物用作催化剂和助催化剂为相转移反应,亲核取代反应或卤素 - 氟交换反应是有用的。