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    • 1. 发明申请
    • RUBBER MODIFIED STYRENIC COPOLYMERS AND THEIR USE IN DISPOSABLE CARD APPLICATIONS
    • 橡胶改性苯乙烯共聚物及其在不可用卡应用中的应用
    • WO2006076072A2
    • 2006-07-20
    • PCT/US2005/041289
    • 2005-11-15
    • NOVA CHEMICALS INC.
    • KWOK, John, Chi, HeeDELANEY, Richard, Jr.DESMARAIS, Michael, W.DESMARAIS, Richard, W.
    • C08L53/00
    • C08F287/00C08L33/06C08L35/06C08L51/006C08L53/02C08L53/025Y10T428/24479C08L2666/24C08L2666/02C08L2666/04
    • A thermoplastic sheet that includes a continuous phase and a dispersed phase, where A) the continuous phase contains a polymer composition resulting from the polymerization of a monomer mixture containing a styrenic monomer and an alkyl (meth) acrylate monomer in the presence of the dispersed phase; and B) the dispersed phase contains one or more block copolymer selected from diblock and triblock copolymers of styrene-butadiene, styrene­ butadiene-styrene, styrene-isoprene, styrene-isoprene-styrene, partially hydrogenated styrene-isoprene-styrene. The thermoplastic sheet is formed by extruding a thermoplastic composition that is cut to desired dimensions to form thermoplastic items, e.g. identification cards, credit cards, bank cards, key cards, gift cards, phone cards, playing cards, menus, and the like. Indicia and/or printing can be applied to the items to provide for commercial applications. The sheet may be opaque or may be relatively clear to transparent with a Haze value of 0.01 % up to 10%.
    • 一种包含连续相和分散相的热塑性片,其中A)连续相含有聚合物组合物,其由在分散相存在下的含有苯乙烯类单体和(甲基)丙烯酸烷基酯单体的单体混合物聚合而得到 ; 和B)分散相含有一种或多种选自苯乙烯 - 丁二烯,苯乙烯 - 丁二烯 - 苯乙烯,苯乙烯 - 异戊二烯,苯乙烯 - 异戊二烯 - 苯乙烯,部分氢化的苯乙烯 - 异戊二烯 - 苯乙烯的二嵌段和三嵌段共聚物的嵌段共聚物。 热塑性片材通过挤出被切割成所需尺寸的热塑性组合物形成热塑性物品,例如, 身份证,信用卡,银行卡,钥匙卡,礼品卡,电话卡,扑克牌,菜单等。 标记和/或打印可以应用于商业应用。 片材可以是不透明的或者可以相对清澈透明,雾度值为0.01%至10%。
    • 2. 发明申请
    • STYRENIC RESIN COMPOSITION AND ARTICLES PRODUCED THEREFROM
    • 苯乙烯树脂组合物及其生产的制品
    • WO2005016978A1
    • 2005-02-24
    • PCT/US2004/009010
    • 2004-03-24
    • NOVA CHEMICALS INC.
    • KWOK, John, Chi, HeeCOOPER, Richard, AlbertKRUPINSKI, Steven, Michael
    • C08F8/00
    • C08F279/02C08F255/10C08L23/20C08L51/06C08F222/08C08F212/08C08L2666/06C08F220/08
    • Styrenic resin composition comprising a rubber modified styrene maleic anhydride copolymer and polybutene. The resin is prepared by several methods including adding polybutene into the reactor, or adding polybutene to the syrup exiting the reactor and prior to entering the devolatilizer, or compounding polybutene into the polymer in an extruder after the polymer exits the devolatilizer. The polybutene ranges from 0.1 to 8% by weight and has a number average molecular weight from 900 to 2500. The rubber ranges from 4% to 20% by weight and has a particle size from 0.1 micron to 11 microns. The resin can be extruded into sheet and thermoformed into an article or can be coextruded to produce a laminated article, which may be a container for packaged foods that can be heated in microwave ovens and which container has improved toughness, elongation, and heat distortion resistance properties.
    • 包含橡胶改性苯乙烯马来酸酐共聚物和聚丁烯的苯乙烯树脂组合物。 该树脂通过几种方法制备,包括将聚丁烯加入到反应器中,或者将聚丁烯加入到离开反应器的浆料中,并且在进入脱挥发物之前,或者在聚合物离开脱挥发物之后,在挤出机中将聚丁烯混合到聚合物中。 聚丁烯的含量为0.1至8重量%,数均分子量为900至2500.橡胶的范围为4重量%至20重量%,其粒径为0.1微米至11微米。 该树脂可以挤出成片并热成型成制品,或者可以共挤出以制成层压制品,其可以是用于微波炉中加热的包装食品的容器,并且该容器具有改善的韧性,伸长率和耐热变形性 属性。