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    • 5. 发明申请
    • THERMOPLASTIC COMPOSITIONS BASED ON SATURATED POLYESTER AND MOULDED ARTICLES CONTAINING THEM
    • 基于饱和聚酯和含有它们的成型制品的热塑性组合物
    • WO1989005838A1
    • 1989-06-29
    • PCT/FR1988000641
    • 1988-12-23
    • NORSOLORHERT, MariusBERTIN, Germain
    • NORSOLOR
    • C08L67/02
    • C08L67/02F16F13/00F16F15/067C08L23/08C08L2666/12C08L63/00C08L23/00
    • Thermoplastic composition comprising not less than 60 % by weight of a saturated polyester and not more than 40 % by weight of at least one polymer reinforcing agent. Said polymer reinforcing agent is an at least partially cross-linked composition obtained by mixing: (a) at least copolymer comprising 94 to 60 % by weight of ethylene, 5 to 25 % by weight of at least one alkyl or cycloalkyl acrylate or methacrylate, the alkyl or cycloalkyl group of which has 2 to 10 carbon atoms, and 1 to 15 % by weight of at least one unsaturated epoxyde, (b) at least one copolymer comprising 84 to 60 % by weight for ethylene, 15 to 34 % by weight of at least one alkyl or cycloalkyl acrylate or methacrylate, the akyl or cycloalkyl group of which has 2 to 10 carbon atoms, and 1 to 6 % by weight of at least one unsaturated dicarboxylic acid anhydride, and (c) at least one compound capable of accelerating reaction between the epoxy function present in the copolymer (a) and the anhydride function present in copolymer (b). Application to the production of moulded articles.
    • 包含不小于60重量%的饱和聚酯和不超过40重量%的至少一种聚合物增强剂的热塑性组合物。 所述聚合物增强剂是至少部分交联的组合物,其通过以下方法获得:(a)至少包含94-60重量%的乙烯,5至25重量%的至少一种烷基或环烷基丙烯酸酯或甲基丙烯酸酯的共聚物, 其烷基或环烷基具有2至10个碳原子和1至15重量%的至少一种不饱和环氧化物,(b)至少一种共聚物,其包含84至60重量%的乙烯,15至34重量% 至少一个烷基或环烷基丙烯酸酯或甲基丙烯酸酯的重量,其烷基或环烷基具有2至10个碳原子,和1至6重量%的至少一种不饱和二羧酸酐,和(c)至少一种化合物 能够促进共聚物(a)中存在的环氧官能团与共聚物(b)中存在的酸酐官能团的反应。 适用于模制品的生产。
    • 6. 发明申请
    • METHOD FOR OBTAINING CARBOXYLIC ACIDS BY REACTION OF ALKANES AND FORMIATES
    • 通过反应碱和羧酸获得羧酸的方法
    • WO1990012779A1
    • 1990-11-01
    • PCT/FR1990000243
    • 1990-04-05
    • NORSOLORLAZZERI, VéroniqueJALAL, RachidGALLO, Roger
    • NORSOLOR
    • C07C51/353
    • C07C51/353
    • To produce a carboxylic acid R -COOH, in which R is a tertiary branched alkyl residue or a cylcoalkyl residue with one or more rings, which may be attached, and possibly substituted by at least one alkyl residue, the alpha carbon atom of the carbonyl group being a tertiary carbon atom, a branched or cyclic alkane R H, in which R is a branched alkyl residue or a cycloalkyl residue with one or more rings, which may be attached, and possibly substituted by at least one alkyl residue, the alpha carbon atom of the hydrogen atom being a tertiary carbon atom or a secondary carbon atom capable of being rearranged during reaction to a tertiary atom, is reacted in the presence of an acid catalyst with a formiate H(CO)O(CR R R ), in which R , R and R denote hydrogen or alkyl, under the three following conditions: that R , R and R are not simultaneously hydrogen; that the formiate yields, in the reaction medium, directly or following a rearrangement, a stable R R R C cation; and that the alkane R R R CH formed can be easily eliminated from the reaction medium.
    • 为了制备羧酸R 1 -COOH,其中R 1是叔支链烷基残基或具有一个或多个环的环烷基残基,其可以连接并且可能被至少一个烷基残基取代, 羰基的碳原子是叔碳原子,支链或环状烷烃R 1 H,其中R 1是支链烷基残基或具有一个或多个环的环烷基残基,可以连接, 并且可能被至少一个烷基残基取代,氢原子的α碳原子是叔碳原子或能够在与叔原子反应期间重新排列的仲碳原子,在酸催化剂存在下与 在三个以下条件下,形成H(CO)O(CR 2 R 3 R 4),其中R 2,R 3和R 4表示氢或烷基,其中R R 3和R 4不同时为氢; 反应介质中的甲酸酯产率直接或重排后,稳定的R 2 R 3 R 4 C +阳离子; 并且可以容易地从反应介质中除去形成的烷烃R 2 R 3 R 4 CH。
    • 10. 发明申请
    • QUATERNIZATION PROCESS
    • 四化过程
    • WO1989007589A1
    • 1989-08-24
    • PCT/FR1989000037
    • 1989-02-02
    • NORSOLOR
    • NORSOLORLACROIX, ChristianHESS, Raymond
    • C07C93/193
    • C07C233/38C07C219/08
    • Process for preparing aqueous solutions of unsaturated quaternary ammonium salts according to the formula H2C=CH-C(O)-A-R3-N+(R1)(R2)(R), X-, in which A is an oxygen atom or an NH group, R3 is a linear or branched alkyl radical, with 1 to 6 carbon atoms, R1, R2 and R, which are different or identical, are each an alkyl radical or aryl radical, X is selected from Cl, Br, I, CH3-CO3 and CH3-SO4 from at least one acrylic monomer (II) of formula H2C=CH-C(O)-A-R3-N(R1)(R2) and of at least one quaternizing agent (III) of formula RX. The reaction is performed at an absolute pressure of between 3 and 10 bars. Application: preparation in a shorter time of low-impurity solutions.
    • 制备相应于下式的不饱和季铵盐(I)的水溶液的方法:H 2 C = CH-C(O)-A-R 3 -N +(R 1)(R 2)(R) 其中A是氧原子或NH基团,R3是1-6个碳原子的直链或支链烷基,R1,R2和R不同或相同,各自是烷基或芳基; X选自来自至少一种式H 2 C = CH-C(O)-A-R 3 -N(R 1)((II))的丙烯酸单体(II)的Cl,Br,I,CH 3 -CO 3和CH 3 -SO 4 R2)和至少一种式RX的季铵化剂(III)。 该反应在3至10巴的绝对压力下进行。 应用于含有少量杂质的溶液,并缩短其持续时间。