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1. 发明申请

WO2010021545A1 PROCESS FOR SEPARATING LIQUID MIXTURES 审中-公开
标题翻译：分离液体混合物的方法
公开(公告)号：WO2010021545A1
公开(公告)日：2010-02-25
申请号：PCT/NL2009/050501
申请日：2009-08-19
申请人： NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO , MEULEMAN, Erik Everhardus Bernardus , GEERDINK, Peter , GOETHEER, Earl Lawrence Vincent , SANCHEZ FERNANDEZ, Eva
发明人： MEULEMAN, Erik Everhardus Bernardus , GEERDINK, Peter , GOETHEER, Earl Lawrence Vincent , SANCHEZ FERNANDEZ, Eva
IPC分类号： B01D61/36 , B01D63/08 , B01D63/02
CPC分类号： B01D61/362 , B01D61/364 , B01D63/02 , B01D63/082 , B01D2313/146 , B01D2313/22 , C02F1/447 , C02F1/448
摘要： The invention is directed to a process for separating liquid mixtures and an apparatus for separating liquid mixtures. The process of the invention comprises: - passing a liquid stream of the liquid mixture over a permeable non-porous selective membrane, said membrane being selective for at least one of said first and second compounds, whereby at least part of the liquid stream passes through said membrane leaving the other side of said membrane as a vapor, with the remainder of the liquid stream forming a retentate stream, and - condensing said vapor on a condenser surface having a lower temperature than the liquid stream to give a distillate stream, said condenser surface forming a non-permeable heat conducting separation wall between said distillate stream and a cooling stream which cooling stream is a) said feed stream, in case the feed stream has a sufficiently low temperature to serve as a suitable cooling medium for the condensation of the permeate vapor, or b) said retentate stream, in case the feed stream has such a high temperature that would make it unsuitable as a cooling medium for the condensation of the permeate vapor, so that heat can be transferred between the vapor and the cooling stream, wherein the distance between said membrane and said condenser surface is smaller than 10 mm, and wherein the vapor pressure of said distillate stream is lower than the vapor pressure of the compounds in the liquid stream for which the permeable non- porous selective membrane is selective, resulting in sufficient driving force for the separation to occur.
摘要翻译：本发明涉及一种用于分离液体混合物的方法和用于分离液体混合物的装置。本发明的方法包括：将液体混合物的液体流通过可渗透的无孔选择性膜，所述膜对于所述第一和第二化合物中的至少一种是选择性的，由此至少部分液体流通过所述膜离开所述膜的另一侧为蒸气，其余液体流形成滞留物流，并且将所述蒸气冷凝在具有比液体流低的温度的冷凝器表面上以产生馏出物流，所述冷凝器表面在所述馏出物流和冷却流之间形成不可渗透的导热分隔壁，所述冷却流是冷却流，a）所述进料流，在进料流具有足够低的温度以用作合适的冷却介质以冷凝渗透气体，或b）所述滞留物流，在进料流具有如此高的温度使其不适合作为冷却介质渗透蒸汽的致密化，使得热量可以在蒸气和冷却流之间传递，其中所述膜和所述冷凝器表面之间的距离小于10mm，并且其中所述馏出物流的蒸气压低于蒸气在可渗透的非多孔选择性膜是选择性的液体流中的化合物的压力，导致足够的驱动力进行分离。

2. 发明申请

WO2011046441A1 METHOD FOR ABSORPTION OF ACID GASES USING AMINO ACIDS 审中-公开
标题翻译：使用氨基酸吸收酸性气体的方法
公开(公告)号：WO2011046441A1
公开(公告)日：2011-04-21
申请号：PCT/NL2010/050684
申请日：2010-10-15
申请人： NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO , GOETHEER, Earl Lawrence Vincent , SANCHEZ FERNANDEZ, Eva , ROELANDS, Cornelis Petrus Marcus
发明人： GOETHEER, Earl Lawrence Vincent , SANCHEZ FERNANDEZ, Eva , ROELANDS, Cornelis Petrus Marcus
IPC分类号： B01D53/14
CPC分类号： B01D53/1406 , B01D53/1462 , B01D53/1493 , B01D2251/80 , B01D2252/20494
摘要： The invention is directed to a method for preparing a gas mixture depleted in gaseous acid compounds, comprising the steps of: a) contacting in a first container a gas mixture comprising gaseous acid compounds with a slurry comprising a first solution of an amino acid and a solid salt of said amino acid, thereby obtaining a slurry loaded with at least part of said acid compounds and a semi-lean gas mixture; and b) contacting in a second container said semi-lean gas mixture with a second solution of an amino acid, thereby obtaining a second solution loaded with at least part of the acid compounds from the semi-lean gas mixture and a lean gas mixture depleted in said gaseous acid compounds.
摘要翻译：本发明涉及一种制备贫气态化合物的气体混合物的方法，包括以下步骤：a）在第一容器中使包含气态酸化合物的气体混合物与包含氨基酸和所述氨基酸的固体盐，从而获得装有至少部分所述酸化合物和半贫气体混合物的浆料; 和b）在第二容器中使所述半贫气体混合物与氨基酸的第二溶液接触，从而获得装载有来自所述半贫气混合物的至少部分酸化合物的第二溶液和贫/ 在所述气态酸化合物中。

3. 发明申请

WO2012144898A1 METHOD FOR DEPLETING A FLUE GAS OF A GASEOUS ACID COMPOUND 审中-公开
标题翻译：用于去除气态酸化合物的燃气的方法
公开(公告)号：WO2012144898A1
公开(公告)日：2012-10-26
申请号：PCT/NL2012/050261
申请日：2012-04-19
申请人： NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO , GOETHEER, Earl, Lawrence, Vincent , SANCHEZ FERNANDEZ, Eva
发明人： GOETHEER, Earl, Lawrence, Vincent , SANCHEZ FERNANDEZ, Eva
IPC分类号： B01D53/14
CPC分类号： B01D53/1456 , B01D53/1425 , B01D53/1493 , B01D2252/20494 , B01D2257/2045 , B01D2257/2047 , B01D2257/302 , B01D2257/304 , B01D2257/504
摘要： The invention is directed to a method for depleting a flue gas of a gaseous acid compound. The method of the invention comprises the steps of: i) contacting the gas stream with an amino acid solution lean in said one or more gaseous acid compounds, thereby obtaining a solid phase comprising precipitated amino acid salt and a liquid phase comprising solution loaded with acid compound to be removed; ii) removing part of the liquid phase; and iii) heating the remaining mixture so as to obtain a solution semi-lean in said one or more acid compounds and a first gas comprising at least part of said gaseous acid compound.
摘要翻译：本发明涉及一种耗尽气态酸化合物烟道气的方法。本发明的方法包括以下步骤：i）使气流与贫的所述一种或多种气态酸化合物中的氨基酸溶液接触，从而获得包含沉淀的氨基酸盐的固相和含有酸的溶液的液相要除去的化合物 ii）除去部分液相; 和iii）加热剩余的混合物以获得在所述一种或多种酸性化合物中半稀的溶液和包含至少部分所述气态酸化合物的第一气体。

4. 发明申请

WO2012096576A1 METHOD AND APPARATUS FOR SEPARATING MIXED GAS FEED 审中-公开
标题翻译：用于分离混合气体进料的方法和装置
公开(公告)号：WO2012096576A1
公开(公告)日：2012-07-19
申请号：PCT/NL2012/050015
申请日：2012-01-12
申请人： NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO , A.V. TOPCHIEV INSTITUTE OF PETROCHEMICAL SYNTHESIS RUSSIAN ACADEMY OF SCIENCES , VAN DEN BROEKE, Leo Jacques Pierre , VAN DE RUNSTRAAT, Annemieke , SANCHEZ FERNANDEZ, Eva , VOLKOV, Alexey , VOLKOV, Vladimir , KHOTIMSKY, Valery
发明人： VAN DEN BROEKE, Leo Jacques Pierre , VAN DE RUNSTRAAT, Annemieke , SANCHEZ FERNANDEZ, Eva , VOLKOV, Alexey , VOLKOV, Vladimir , KHOTIMSKY, Valery
IPC分类号： B01D53/14 , B01D61/00
CPC分类号： B01D53/1425 , B01D19/0031 , B01D53/1462 , B01D53/229 , B01D61/36 , B01D2252/30 , B01D2256/16 , B01D2256/245 , B01D2257/304 , B01D2257/504 , B01D2311/2626
摘要： The invention is directed to a method for separating gases in a mixed gas feed stream, and to an apparatus for carrying out said method. The method of the invention comprises: i) contacting the mixed gas feed stream with an absorption liquid in an absorption column at a pressure of 1 bar or more, said absorption liquid being selective for absorption of one or more gases in the mixed gas feed stream so that part of the gas in the mixed gas feed stream is absorbed by the absorption liquid resulting in a rich absorption liquid; ii) regenerating at least part of the absorption liquid by contacting the rich absorption liquid with a desorption membrane, wherein the pressure at the retentate side of the desorption membrane is at least 1 bar higher than the pressure at the permeate side of the desorption membrane so that at least part of the absorbed gas desorbs from the rich absorption liquid and permeates through the desorption membrane thereby forming a lean absorption liquid; and iii) recycling at least part of the lean absorption liquid to step i) for contacting with the mixed gas feed stream.
摘要翻译：本发明涉及一种用于分离混合气体进料流中的气体的方法，以及用于实施所述方法的装置。本发明的方法包括：i）在1巴或更高的压力下将混合气体进料流与吸收塔中的吸收液体接触，所述吸收液体可选择性地吸收混合气体进料流中的一种或多种气体使得混合气体进料流中的气体的一部分被吸收液体吸收，产生丰富的吸收液体; ii）通过使富吸收液体与解吸膜接触来再生至少部分吸收液体，其中解吸膜的滞留侧的压力比解吸膜的渗透侧的压力高至少1巴，因此吸收的气体的至少一部分从富吸收液体中解吸并渗透通过解吸膜，从而形成贫吸收液体; 以及iii）将至少部分贫吸收液体再循环到步骤i）以与混合气体进料流接触。

5. 发明申请

WO2013023919A1 VERFAHREN UND VORRICHTUNG ZUM AUFREINIGEN EINES MIT NITROSAMIN VERUNREINIGTEN PRODUKTES EINER PROZESSANLAGE 审中-公开
标题翻译：方法和设备净化过程工厂的硝基SAMIN污染的产品
公开(公告)号：WO2013023919A1
公开(公告)日：2013-02-21
申请号：PCT/EP2012/065033
申请日：2012-08-01
申请人： SIEMENS AKTIENGESELLSCHAFT , FISCHER, Björn , GOETHEER, Earl Lawrence Vincent , JOH, Ralph , KUETTEL, Diego Andres , SCHNEIDER, Rüdiger , KIMBALL, Erin , KINZL, Markus , SANCHEZ FERNANDEZ, Eva , VAN DER STEL, Rob
发明人： FISCHER, Björn , GOETHEER, Earl Lawrence Vincent , JOH, Ralph , KUETTEL, Diego Andres , SCHNEIDER, Rüdiger , KIMBALL, Erin , KINZL, Markus , SANCHEZ FERNANDEZ, Eva , VAN DER STEL, Rob
IPC分类号： B01D53/14
CPC分类号： B01D53/1425 , B01D53/1475 , B01D53/62 , B01D2252/204 , B01D2257/504 , B01D2259/804 , Y02A50/2342 , Y02C10/06
摘要： Die Erfindung betrifft ein Verfahren zum Aufreinigen eines mit Nitrosaminen verunreinigten Produktes (12, 13) einer Prozessanlage. Das verunreinigte Produkt wird mit UV-Strahlung (50) aus einer UV-Lichtquelle (58) behandelt, wobei die Nitrosamine zerstört werden. Die Wellenlänge λ der UV-Strahlung (50) wird dabei so eingestellt, dass in dem Produkt enthaltene aktive Waschsubstanzen wie Aminosäuresalze weitgehend erhalten bleiben. Die Erfindung betrifft außerdem eine Vorrichtung (8) zum Regenieren eines mit Nitrosamin verunreinigten Produktes aus einer CO 2 Capture-Anlage, sowie eine Vorrichtung zum Aufreinigen eines mit Nitrosamin verunreinigten Abfallproduktes aus einer CO 2 Capture-Anlage.
摘要翻译：本发明涉及一种方法，用于纯化过程工厂的污染的产物的亚硝胺（12，13）。被污染的产物与从UV光源（58）的UV辐射（50）处理中，亚硝胺被破坏。波长？ UV辐射（50）被调整，以使得存在于产物活性洗涤物质如氨基酸盐在很大程度上保留。本发明还涉及一种装置（8），用于从CO2捕获系统，以及用于从CO 2捕集植物纯化污染亚硝胺废物产品的装置再生污染亚硝胺产物。

6. 发明申请

WO2013081460A1 METHOD FOR DEPLETING AN EXHAUST GAS STREAM IN GASEOUS ACID 审中-公开
标题翻译：在气体酸中排除排气的方法
公开(公告)号：WO2013081460A1
公开(公告)日：2013-06-06
申请号：PCT/NL2012/050848
申请日：2012-11-29
申请人： NEDERLANDSE ORGANISATIE VOOR TOEGEPAST-NATUURWETENSCHAPPELIJK ONDERZOEK TNO
发明人： GOETHEER, Earl Lawrence Vincent , SANCHEZ FERNANDEZ, Eva , DE MIGUEL MERCADER, Ferran , NIENOORD, Michiel , BERGSMA, Egbertus Jan , DE KLER, Robert Christiaan Franciscus
IPC分类号： B01D53/14 , B01D19/00 , F23J15/00
CPC分类号： B01D53/1456 , B01D19/0005 , B01D53/1425 , B01D53/1475 , B01D2251/304 , B01D2251/306 , B01D2251/606 , B01D2251/61 , B01D2252/10 , B01D2252/20415 , B01D2252/20447 , B01D2252/20489 , B01D2252/20494 , B01D2257/2045 , B01D2257/2047 , B01D2257/302 , B01D2257/304 , B01D2257/404 , B01D2257/504 , B01D2258/0283 , F23B30/00 , F23J1/06 , F23J15/006 , F23J2215/20 , F23J2215/50 , F23J2219/40 , F23J2900/15081 , F23K3/02 , Y02C10/06 , Y02E20/326 , Y02E20/344
摘要： A method for depleting an exhaust gas stream in one or more gaseous acid compounds is described. The method comprises the steps of: • i) combusting fuel (10), thereby obtaining a stream of exhaust gas (8) comprising one or more gaseous acid compounds; • ii) contacting said stream of exhaust gas comprising one or more gaseous acid compounds with an absorbent solution (4) lean in said one or more gaseous acid compounds, thereby obtaining an absorbent solution (11) rich in said one or more gaseous acid com pounds and a gas stream depleted in said one or more gaseous acid compounds; • iii) subjecting at least part of the absorbent solution rich in said one or more gaseous acid compounds to a thermal stripping step at a temperature of 90 °C or less, thereby obtaining an absorbent solution (1) semi-lean in said one or more gaseous acid compounds; • iv) subjecting at least part of the absorbent solution semi-lean in said one or more gaseous acid compounds to an air stripping step, thereby obtaining an absorbent solution lean in said one or more gaseous acid compounds and a stream of air (5) rich in said one or more gaseous acid compounds; • v) recycling at least part of the stream of air rich in said one or more gaseous acid compounds to combustion step i); and • vi) recycling at least part of the absorbent solution lean in said one or more gaseous acid compounds to the contacting step ii), • wherein the solvent in said absorbent solution is non-volatile.
摘要翻译：描述了在一种或多种气态酸化合物中排出废气流的方法。该方法包括以下步骤： i）燃烧燃料（10），从而获得包含一种或多种气态酸化合物的废气流（8）; 。 ii）将包含一种或多种气态酸化合物的废气流与所述一种或多种气态酸化合物中的贫的吸收剂溶液（4）接触，从而获得富含所述一种或多种气态酸的化合物的吸收剂溶液（11）以及在所述一种或多种气态酸化合物中贫化的气流; 。 iii）使所述一种或多种气态酸化合物中富含的吸收剂溶液的至少一部分在90℃或更低的温度下进行热汽提步骤，从而获得在所述一种或多种气态酸化合物中半稀的吸收剂溶液（1）气态酸化合物; 。 iv）使所述一种或多种气态酸化合物中的半贫的吸收剂溶液的至少一部分进行空气汽提步骤，从而获得在所述一种或多种气态酸化合物中稀薄的吸收剂溶液和富含（5）在所述一种或多种气态酸化合物中; 。 v）将富含所述一种或多种气态酸化合物的空气流的至少一部分再循环到燃烧步骤i）; 和。 vi）将所述一种或多种气态酸化合物中的稀薄的吸收剂溶液的至少一部分再循环至接触步骤ii）。其中所述吸收剂溶液中的溶剂是非挥发性的。

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