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    • 1. 发明申请
    • AQUEOUS COMPOSITIONS THICKENED WITH ACRYLATE-BASED POLYMERIC RHEOLOGY MODIFIERS
    • 基于丙烯酸酯的聚合物流变学改性剂的水性组合物
    • WO1998006757A1
    • 1998-02-19
    • PCT/US1997014317
    • 1997-08-14
    • NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATION
    • NATIONAL STARCH AND CHEMICAL INVESTMENT HOLDING CORPORATIONVERSTRAT, Daniel, W.BARRON, Milagros, C.WILKERSON, John, M., III
    • C08F02/24
    • C08F220/12A61K8/23A61K8/36A61K8/365A61K8/463A61K8/8152A61K8/86A61Q5/02A61Q19/10
    • The present invention relates to aqueous compositions having pH of less than or equal to about 11 and which contain a thickening amount of an acrylate-based rheology modifier, which modifier contains an emulsion which is prepared by single-stage emulsion polymerization of a C2-C6alkyl ester of acrylic acid and/or C1-C6alkyl ester of methacrylic acid, a monomer chosen from a vinyl-substituted heterocyclic compound containing at least one of a nitrogen or sulfur atom, (meth)acrylamide, a mono- or di-(C1-C4)alkylamino (C1-C4)alkyl (meth)acrylate, a mono or di-(C1-C4)alkylamino (C1-C4)alkyl (meth)acrylamide, and optionally cross-linking monomers and/or associative monomers, in the presence of water, a first surfactant, a free-radical initiator and an alcohol selected from C2-C12 linear or branched alcohols, ethylene glycol, propylene glycol and glycerol, or mixtures thereof, and essentially in the absence of a polymeric colloidal stabilizer such as polyvinyl alcohol, and which compositions further contain an active ingredient selected from the group consisting of an acid and a second surfactant which may be the same as or different than the first surfactant.
    • 本发明涉及pH小于或等于约11的含水组合物,其含有增稠量的基于丙烯酸酯的流变改性剂,该改性剂含有通过C2-C6烷基的单阶段乳液聚合制备的乳液 丙烯酸和/或甲基丙烯酸的C 1 -C 6烷基酯的酯,选自含有氮或硫原子中的至少一个的乙烯基取代的杂环化合物的单体,(甲基)丙烯酰胺,单 - 或二 - (C1- C4)烷基(C1-C4)烷基(甲基)丙烯酸酯,单或二(C1-C4)烷基氨基(C1-C4)烷基(甲基)丙烯酰胺,以及任选的交联单体和/或缔合单体 存在水,第一表面活性剂,自由基引发剂和选自C 2 -C 12直链或支链醇,乙二醇,丙二醇和甘油或其混合物的醇,并且基本上不存在聚合物胶体稳定剂如 聚乙烯醇,哪些组合物 还含有选自与第一表面活性剂相同或不同的酸和第二表面活性剂的活性成分。