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    • 1. 发明申请
    • LITHIUM ION BATTERY ANODE CONTAINING SILICON NANOWIRES GROWN IN SITU IN PORES OF GRAPHENE FOAM AND PRODUCTION PROCESS
    • 石墨泡沫孔内原位生长的含有纳米硅的锂离子电池阳极及生产工艺
    • WO2018067391A1
    • 2018-04-12
    • PCT/US2017/054234
    • 2017-09-29
    • NANOTEK INSTRUMENTS, INC.
    • SU, Yu-ShengYIN, JunFANG, QingZHAMU, ArunaJANG, Bor Z.
    • H01M4/02H01M4/04H01M4/133H01M4/134H01M4/1395H01M4/36
    • A process for producing an anode layer, comprising: (a) dispersing catalyst metal-coated Si particles, graphene sheets, and an optional blowing agent in a liquid medium to form a graphene/Si dispersion; (b) dispensing and depositing the dispersion onto a supporting substrate to form a wet layer and removing the liquid medium from the wet layer to form a dried layer of graphene/Si mixture material; and (c) exposing the dried layer to a high temperature environment, from 300°C to 2,000°C, to induce volatile gas molecules from graphene sheets or to activate the blowing agent for producing the graphene foam and, concurrently, to enable a catalyst metal-catalyzed growth of multiple Si nanowires emanated from Si particles as a feed material in pores of the foam to form the anode layer; wherein the Si nanowires have a diameter of 5-100 nm and a length-to-diameter aspect ratio of at least 5.
    • 一种制备阳极层的方法,包括:(a)将催化剂金属涂覆的Si颗粒,石墨烯片和任选的发泡剂分散在液体介质中以形成石墨烯/ Si分散体; (b)将分散体分散并沉积到支撑基底上以形成湿层,并从湿层去除液体介质以形成石墨烯/ Si混合物材料的干燥层; 和(c)将干燥层暴露于300℃-2000℃的高温环境中以从石墨烯片上诱导挥发性气体分子或活化用于生产石墨烯泡沫的发泡剂,并且同时使得 催化剂金属催化生长多个Si纳米线,所述多个Si纳米线由作为泡沫孔隙中的进料材料的Si颗粒散发以形成阳极层; 其中Si纳米线具有5-100nm的直径和至少5的长径比直径比。