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1. 发明申请

WO2004019681B1 PESTICIDE COMPOSITIONS CONTAINING DICARBOXYLIC ACIDS 审中-公开
公开(公告)号：WO2004019681B1
公开(公告)日：2004-08-26
申请号：PCT/US0327195
申请日：2003-08-29
申请人： MONSANTO TECHNOLOGY LLC , ABRAHAM WILLIAM , STERN MICHAEL K , GRAHAM JEFFREY ALAN , XU XIAODONG CHRIS , BRINKER RONALD J , TRAVERS JEFFREY N , REYNOLDS TRACEY L
发明人： ABRAHAM WILLIAM , STERN MICHAEL K , GRAHAM JEFFREY ALAN , XU XIAODONG CHRIS , BRINKER RONALD J , TRAVERS JEFFREY N , REYNOLDS TRACEY L
IPC分类号： A01N25/00 , A01N25/30 , A01N37/04 , A01N57/00 , A01N57/20
CPC分类号： A01N57/20 , A01N61/00 , A01N37/04 , A01N25/30 , A01N2300/00
摘要： Solid and liquid pesticidal concentrate and spray compositions are described which exhibit enhanced efficacy due to the addition thereto of a compound which increases EPSPS enzyme inhibition by the pesticide, cell membrane permeability, or expression of hydroxyproline-rich glycoproteins.

2. 发明申请

WO2004019681A3 PESTICIDE COMPOSITIONS CONTAINING DICARBOXYLIC ACIDS 审中-公开
标题翻译：含有二羧酸的农药组合物
公开(公告)号：WO2004019681A3
公开(公告)日：2004-06-17
申请号：PCT/US0327195
申请日：2003-08-29
申请人： MONSANTO TECHNOLOGY LLC , ABRAHAM WILLIAM , STERN MICHAEL K , GRAHAM JEFFREY ALAN , XU XIAODONG CHRIS , BRINKER RONALD J , TRAVERS JEFFREY N , REYNOLDS TRACEY L
发明人： ABRAHAM WILLIAM , STERN MICHAEL K , GRAHAM JEFFREY ALAN , XU XIAODONG CHRIS , BRINKER RONALD J , TRAVERS JEFFREY N , REYNOLDS TRACEY L
IPC分类号： A01N25/00 , A01N25/30 , A01N37/04 , A01N57/00 , A01N57/20
CPC分类号： A01N57/20 , A01N61/00 , A01N37/04 , A01N25/30 , A01N2300/00
摘要： Solid and liquid pesticidal concentrate and spray compositions are described which exhibit enhanced efficacy due to the addition thereto of a compound which increases EPSPS enzyme inhibition by the pesticide, cell membrane permeability, or expression of hydroxyproline-rich glycoproteins.
摘要翻译：描述了固体和液体农药浓缩物和喷雾组合物，由于其中添加了增加杀虫剂对EPSPS酶的抑制，细胞膜渗透性或富含羟脯氨酸的糖蛋白的表达的化合物，因此表现出增强的功效。

3. 发明申请

WO02051246A9 METHOD OF IMPROVING YIELD AND VIGOR OF PLANTS 审中-公开
标题翻译：改善植物的叶片和植物的方法
公开(公告)号：WO02051246A9
公开(公告)日：2003-07-31
申请号：PCT/US0150484
申请日：2001-12-20
申请人： MONSANTO TECHNOLOGY LLC , DE BILLOT MAURICE R , VAN WYK SCHALK , ODENDAAL T E M , PHILLION DENNIS PAUL , COULTAS JEFFREY S , SANDERS ERNEST F , PENNER GREG A , ASRAR JAWED , STERN MICHAEL K
发明人： DE BILLOT MAURICE R , VAN WYK SCHALK , ODENDAAL T E M , PHILLION DENNIS PAUL , COULTAS JEFFREY S , SANDERS ERNEST F , PENNER GREG A , ASRAR JAWED , STERN MICHAEL K
IPC分类号： A01N55/00 , A01N55/10
CPC分类号： A01N55/00
摘要： A method of improving the yield and vigor of agronomic plants, in particular leguminous plants such as soybeans, involves treating such plants and/or the propagation material of plants with a composition that includes an active agent, such as a fungicide, that has no significant activity against fungal plant pathogens of the treated plant. When the plant is not wheat, a preferred agent of this type is 4,5-dimethyl-N-(2-propenyl)-2-(trimethylsilyl)-3-thiophenecarboxamide (silthiofam). Plants and plant propagation material, such as seeds, that have been treated by the novel method are also described.
摘要翻译：改善农艺植物，特别是豆科植物如大豆的产量和活力的方法涉及用包含不具有显着性的活性剂（例如杀真菌剂）的组合物来处理这些植物和/或植物繁殖材料对被处理植物的真菌植物病原体的活性。当植物不是小麦时，优选的这种类型的试剂是4,5-二甲基-N-（2-丙烯基）-2-（三甲基甲硅烷基）-3-噻吩甲酰胺（硅硫酰）。还描述了已经通过新方法处理的植物和植物繁殖材料，例如种子。

4. 发明申请

WO0009520A9 CONTINUOUS PROCESS FOR THE PREPARATION OF N-(PHOSPHONOMETHYL) IMINODIACETIC ACID 审中-公开
标题翻译： N-（磷酸基乙基）亚氨基二乙酸的连续制备方法
公开(公告)号：WO0009520A9
公开(公告)日：2000-09-28
申请号：PCT/US9918501
申请日：1999-08-12
申请人： MONSANTO CO , STERN MICHAEL K , JOHNSON TODD J , JORGENSON AMY L , ROGERS MICHAEL D , FRANCZYK THADDEUS S III
发明人： STERN MICHAEL K , JOHNSON TODD J , JORGENSON AMY L , ROGERS MICHAEL D , FRANCZYK THADDEUS S III
IPC分类号： B01J20/26 , B01J20/34 , B01J31/20 , B01J31/40 , B01J38/00 , C07B61/00 , C07C233/47 , C07D241/08 , C07F9/38
CPC分类号： C07D241/08 , C07C233/47 , C07F9/3808
摘要： In the process of the present invention, N-acetyliminodiacetic acid is formed via a continuous amidocarboxymethylation reaction. In this reaction, N-(acetyl)iminodiacetic acid is formed in an amidocarboxymethylation reactor system, into which a source of each of the following is continuously fed: (1) acetamide or an acetamide derivative (2) formaldehyde or a formaldehyde generator or derivative (3) a carbonylation catalyst (4) carbon monoxide and optionally (5) hydrogen. In turn, an amidocarboxymethylation reaction product stream, which contains N-(acetyl)iminodiacetic acid and the carbonylation catalyst, is withdrawn from the amidocarboxymethylation reactor system. The carbonylation catalyst is separated from the amidocarboxymethylation reaction product stream to recover the carbonylation catalyst and form a catalyst depleted product stream which contains N-(acetyl)iminodiacetic acid. The separated carbonylation catalyst is returned to the amidocarboxymethylation reactor system, and the N-(acetyl)iminodiacetic acid in the catalyst depleted product stream is either: (1) reacted with a source of phosphorous and a source of formaldehyde in the presence of an acid to form a phosphonomethylation reaction product stream containing N-(phosphonomethyl)iminodiacetic acid and acetic acid; or (2) deacylated and cyclized to form a 2,5-diketopiperazine, and then reacted with a source of phosphorous and a source of formaldehyde in the presence of an acid to form a phosphonomethylation reaction product stream containing N-(phosphonomethyl)iminodiacetic acid and acetic acid. Either way, the N-(phosphonomethyl)iminodiacetic acid is precipitated from the phosphonomethylation reaction product stream in the presence of acetic acid, and the precipitate is recovered to form a filtrate stream. The filtrate stream is separated into an acetic acid enriched stream and an acetic acid depleted stream. At least a portion of the acetic acid enriched stream is fed to an acetamide synthesis reactor into which ammonia is simultaneously fed to form an acetamide product stream, which is fed (directly or indirectly) back to the amidocarboxymethylation reactor system.
摘要翻译：在本发明的方法中，N-乙酰基二乙酸通过连续的酰胺基羧甲基化反应形成。在该反应中，在酰氨基羧甲基化反应器系统中形成N-（乙酰基）亚氨基二乙酸，连续进料以下每一种来源：（1）乙酰胺或乙酰胺衍生物（2）甲醛或甲醛产生剂或衍生物（3）羰基化催化剂（4）一氧化碳和任选（5）氢。接着，将含有N-（乙酰基）亚氨基二乙酸和羰基化催化剂的酰胺基羧甲基化反应产物流从酰胺基羧甲基化反应器系统中排出。羰基化催化剂与酰氨基羧甲基化反应产物流分离以回收羰基化催化剂并形成含有N-（乙酰基）亚氨基二乙酸的催化剂耗尽产物流。将分离出的羰基化催化剂返回到酰氨基羧甲基化反应器体系中，并且催化剂去除产物流中的N-（乙酰基）亚氨基二乙酸或者：（1）在酸存在下与磷来源和甲醛来源反应以形成含有N-（膦酰基甲基）亚氨基二乙酸和乙酸的膦酰甲基化反应产物流; 或（2）脱酰并环化形成2,5-二酮哌嗪，然后在酸存在下与磷源和甲醛源反应，形成含N-（膦酰基甲基）亚氨基二乙酸的膦酰甲基化反应产物流和乙酸。不管怎样，在乙酸存在下N-膦酰基甲基化亚氨基二乙酸从膦酰基甲基化反应产物流中沉淀出来，沉淀物被回收形成滤液流。将滤液流分离成富含乙酸的物流和贫含乙酸的物流。将至少一部分富含乙酸的物流进料到乙酰胺合成反应器中，其中氨同时进料到乙酰胺合成反应器中以形成乙酰胺产物物流，将其（直接或间接）进料到酰胺基羧甲基化反应器体系中。

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