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    • 1. 发明申请
    • HIGH-STRENGTH BLACK POLYURETHANE FOAMS
    • 高强度黑色POLYURETHANE FOAMS
    • WO2004094496A3
    • 2004-12-16
    • PCT/US2004005476
    • 2004-02-25
    • MILLIKEN & COXIA JUSONGBATLAW RAJNISH
    • XIA JUSONGBATLAW RAJNISH
    • C08G20060101C08G18/00C08G18/48C08J9/00C08K5/00
    • C08J9/00C08G18/48C08G2101/0008C08J2375/04C08K5/0041C08L75/04
    • Black polyurethane foams that exhibit higher strength black colorations without the need for concomitant increases in black colorants therein are provided. Such a resultant jetter black foam article is possible through the unexpectedly effective introduction of small amounts of certain toner compounds or combinations that exhibit specific measurable appearance characteristics. Such toners exhibit at least one absorption peak within a specific range of wavelengths (e.g., from about 560 to 610 nm) and specific ranges of half-height bandwidths (from 40 to 130 nm). Furthermore, such a compound or combination of compounds, is preferably liquid in nature (at room temperature) or in dispersion form and may thus be easily incorporated within target polyurethane precursor compositions for admixture with either black pigments (or dispersions thereof), black polymeric (liquid) colorants, or both. Methods of high strength black polyurethane foam production as well as separate pigmented and liquid polymeric colored foams of such type including the necessary toner compounds and/or combinations, as noted above, are also encompassed within this invention.
    • 提供了表现出较高强度黑色着色而不需要伴随着黑色着色剂增加的黑色聚氨酯泡沫。 通过意想不到地有效地引入少量的具有特定的可测量的外观特征的某些调色剂化合物或组合,可以获得这样一种合成的喷射黑色泡沫制品。 这种调色剂在特定波长范围(例如,约560至610nm)和半高带宽(40至130nm)的特定范围内表现出至少一个吸收峰。 此外,这种化合物或化合物的组合在本质上(在室温下)或分散体形式优选是液体,因此可以容易地掺入目标聚氨酯前体组合物中,用于与黑色颜料(或其分散体),黑色聚合物 液体)着色剂或两者。 高强度黑色聚氨酯泡沫体生产方法以及如上所述的包括所需调色剂化合物和/或组合的分开的这类颜料和液体聚合物着色泡沫体的方法也包括在本发明内。
    • 2. 发明申请
    • ULTRAVIOLET LIGHT (UV) ABSORBING COMPOUNDS AND COMPOSITIONS CONTAINING UV ABSORBING COMPOUNDS
    • 紫外线(UV)吸收化合物和含有紫外线吸收化合物的组合物
    • WO2006023687A3
    • 2006-12-21
    • PCT/US2005029482
    • 2005-08-18
    • MILLIKEN & COXIA JUSONG
    • XIA JUSONG
    • C08K5/34
    • C08K5/3475C07D249/20
    • Hydroxybenzotriazole-based compounds are useful for ultraviolet light absorbing additives for a variety of applications. Such compounds have particular usefulness in various applications, including plastics, automotive, coatings, and food packaging applications. Such inventive compound exhibit excellent UV radiation absorbing activity, high thermal stability, excellent low fogging, low extraction/low migration rates, and high lightfastness levels, particularly when incorporated within certain media and/or on the surface of certain substrates, particularly polyesters, polyolefins, and polyurethanes. Block copolymer chain or chains consisting of poly(oxyalkylene) and/or aliphatic polyester segments can be conveniently tailored to increase the solubility or compatibility in different solvents or resins thereby permitting the introduction of such excellent UV absorbing chromophores within diverse media and/or or diverse substrates. Compositions and articles comprising such compounds are provided as well as methods for producing such inventive compounds.
    • 基于羟基苯并三唑的化合物可用于各种应用的紫外光吸收添加剂。 这些化合物在各种应用中特别有用,包​​括塑料,汽车,涂料和食品包装。 特别是在特定的介质和/或某些基材,特别是聚酯,聚烯烃的表面上时,这种本发明的化合物表现出优异的UV辐射吸收活性,高热稳定性,优异的低雾度,低萃取/低迁移速率和高耐光性水平 ,和聚氨酯。 可以方便地调整由聚(氧化烯)和/或脂族聚酯链段组成的嵌段共聚物链或链,以增加在不同溶剂或树脂中的溶解度或相容性,从而允许在不同的介质和/或多样性中引入这些优异的UV吸收发色团 基板。 提供了包含这些化合物的组合物和制品以及制备这种本发明化合物的方法。
    • 4. 发明申请
    • NOVEL METHOD OF PRODUCING POLYESTERIFIED LIQUID ANTHRAQUINONE-BASED COLORANTS
    • 一种生产基于聚氨酯的基于颜料的新方法
    • WO2005000913A2
    • 2005-01-06
    • PCT/US2004017648
    • 2004-06-04
    • MILLIKEN & COXIA JUSONGXIE CHUNPINGCREEL VANESSA
    • XIA JUSONGXIE CHUNPINGCREEL VANESSA
    • C09B69/10C08F
    • C09B69/101
    • An inventive blue colorant comprising a chromophore having at least one hydroxy group-terminated polyester chain attached, through a suitable alkylamino linking group (or groups), to the 1- position, the 4- position, or both, of an anthraquinone backbone is provided. Such colorants exhibit excellent amine/base stability and thermal stability, effective colorations, excellent low extraction rates, and high lightfastness levels, particularly when incorporated within certain media and/or on the surface of certain polyurethane substrates. The polyester chain or chains can be conveniently tailored to increase the solubility or compatibility in different types of polyurethane resin precursors thereby permitting the introduction of such excellent coloring chromophores within diverse polyurethane media and/or or diverse polyurethane substrates as well as provides a liquid colorant which facilitates handling. Compositions and articles comprising such inventive colorants are provided as well as methods for producing such inventive colorants.
    • 提供了一种本发明的蓝色着色剂,其包含具有至少一个羟基封端的聚酯链的发色团,通过合适的烷基氨基连接基团(或基团)连接到蒽醌骨架的1-位,4-位或二者上 。 这种着色剂表现出优异的胺/碱稳定性和热稳定性,有效着色,优异的低萃取速率和高耐光性水平,特别是当结合到某些介质和/或某些聚氨酯基材的表面上时。 可以方便地调整聚酯链或链,以增加不同类型的聚氨酯树脂前体的溶解度或相容性,从而允许在多种聚氨酯介质和/或多种聚氨酯底物内引入这些优异的着色发色团,并提供液体着色剂 方便处理。 提供了包含这种本发明着色剂的组合物和制品以及制备这种本发明着色剂的方法。
    • 5. 发明申请
    • POLYURETHANE ARTICLES, COLORANTS, AND SUCH ARTICLES COMPRISING NOVEL HIGH TOLUENE DIISOCYANATE-STABLE BLUE COLORANTS
    • 包含新型高钛白云母稳定蓝色颜料的聚氨酯文章,颜料和这些文章
    • WO2005000910A3
    • 2005-02-03
    • PCT/US2004016971
    • 2004-06-01
    • MILLIKEN & COXIA JUSONG
    • XIA JUSONG
    • C08F20060101C08G18/00C08G18/28C08G18/70C08G63/02C08G63/18C08G63/44C08G69/00C08G69/44
    • C08G18/4615C08G18/7664C08G63/6852C08K5/0041C08L75/04C09B1/201C09B69/00C09B69/101
    • An inventive blue colorant comprising a chromophore having at least one hydroxy group-terminated polyester chain attached, through a suitable alkylamino linking group (or groups), to the 1- position, the 4- position, or both, of an anthraquinone backbone and having at least one hindering group in a secondary position in relation to said amino linking group is provided. Such colorants exhibit excellent amine/base stability and thermal stability, effective colorations, excellent low extraction rates, high lightfastness levels, particularly when incorporated within certain media and/or on the surface of certain polyurethane substrates, and, most importantly excellent stability in the presence of excess of diisocyanates. The polyester chain or chains can be conveniently tailored to increase the solubility or compatibility in different types of polyurethane resin precursors thereby permitting the introduction of such excellent coloring chromophores within diverse polyurethane media and/or or diverse polyurethane substrates as well as provides a liquid colorant which facilitates handling. Compositions and articles comprising such inventive colorants are provided as well as methods for producing such inventive colorants.
    • 本发明的蓝色着色剂包括具有至少一个羟基封端的聚酯链的发色团,其通过合适的烷基氨基连接基团(或基团)连接到蒽醌骨架的1-位置,4-位或二者,并具有 提供了相对于所述氨基连接基团处于二级位置的至少一个受阻基团。 这些着色剂表现出优异的胺/碱稳定性和热稳定性,有效着色,优异的低萃取速率,高耐光性水平,特别是当结合到某些介质中和/或在某些聚氨酯基材的表面上时,最重要的是在存在下优异的稳定性 的过量二异氰酸酯。 可以方便地调整聚酯链或链,以增加不同类型的聚氨酯树脂前体的溶解度或相容性,从而允许在多种聚氨酯介质和/或多种聚氨酯底物内引入这些优异的着色发色团,并提供液体着色剂 方便处理。 提供了包含这种本发明着色剂的组合物和制品以及制备这种本发明着色剂的方法。
    • 7. 发明申请
    • AROMATIC BIS-ACETOACETAMIDE INTERMEDIATES
    • 芳香双酚A酰胺中间体
    • WO0244282A2
    • 2002-06-06
    • PCT/US0144402
    • 2001-11-26
    • MILLIKEN & CO
    • XIA JUSONGMILEY JOHN W
    • C09B33/153C09B
    • C09B33/153
    • Specific novel compounds of aromatic bis-acetoamide structures are provided as intermediate compounds to forming different types of coloring agents, at least. Such compounds are useful as intermediates in the production of certain bis-acetoanilide azo dyes, pigments, and polymeric colorants. Such compounds facilitate production of such coloring agents that exhibit favorable tinctorial strength and intense color from orange to greenish yellow within and on different substrates and media. Coloring agents and methods of making such agents are encompassed within this invention as well.
    • 作为中间体化合物,至少提供了形成不同类型的着色剂的具体的芳香族双乙酰胺结构化合物。 这些化合物可用作生产某些双苯乙酰苯胺偶氮染料,颜料和聚合物着色剂的中间体。 这样的化合物有助于生产这样的着色剂,其在不同的底物和介质内和在不同的底物和介质上表现出良好的着色强度和强烈的颜色从橙色到黄绿色。 着色剂及其制备方法也包括在本发明内。
    • 8. 发明申请
    • POLYMERIC BIS-ACETOACETANILIDE AZO COLORANTS
    • 聚合双乙酰丙酮腈偶氮染料
    • WO0244283A2
    • 2002-06-06
    • PCT/US0144406
    • 2001-11-26
    • MILLIKEN & CO
    • XIA JUSONGSTEPHENS ERIC BMASON MARY GMILEY JOHN WSTARKS LEONARD J
    • C09B33/153C09B43/32C09B69/00C09B69/10C09B
    • C09B69/00C09B69/106
    • This invention relates to colorants comprising a chromophore having two azo acetoacetanilide moieties, wherein said moieties each have at least one poly(oxyalkylene) chain, preferably at least two such chains, Such colorants exhibit extremely good base stability and lightfastness, particularly when incorporated within certain media and/or on the surface of certain substrates. These poly(oxyalkylene) chains provide solubility in different solvents or resins thereby permitting the introduction of such excellent coloring chromophores within diverse media and/or diverse substrates. Compositions and articles comprising such colorants are provided as are methods for producing such inventive colorants.
    • 本发明涉及包含具有两个偶氮乙酰乙酰替苯胺部分的发色团的着色剂,其中所述部分各自具有至少一个聚(氧化烯)链,优选至少两个这样的链。这种着色剂表现出非常好的碱稳定性和耐光性,特别是当掺入某些 介质和/或某些基底的表面上。 这些聚(氧化烯)链提供在不同溶剂或树脂中的溶解度,从而允许在不同的介质和/或不同的底物内引入这些优异的着色发色团。 作为制造这种着色剂的方法,提供了包含这种着色剂的组合物和制品。
    • 9. 发明申请
    • IMPROVED LOW-COLOR ULTRAVIOLET ABSORBERS FOR THERMOPLASTIC AND THERMOSET HIGH UV WAVELENGTH PROTECTION APPLICATIONS
    • 改进的低色度紫外线吸收剂,用于热塑性和热固性高紫外波长保护应用
    • WO2005062733A3
    • 2005-08-18
    • PCT/US0338044
    • 2003-12-02
    • MILLIKEN & CO
    • XIA JUSONGMASON MARY ESTEPHENS ERIC B
    • A61K8/39A61Q17/04C08K5/315C07C69/74C03C17/00C08K5/10C08L1/00C09K3/00
    • A61K8/39A61Q17/04C08K5/315
    • Novel ultraviolet absorbing compounds that are liquid in nature, are low in color (and thus permit use without the concomitant necessity of adding large amounts of other coloring agents to combat such discoloring), and are highly effective in providing protection in wavelength ranges for which previous attempts at low-color ultraviolet absorbers have failed are provided herein. Such compounds provide such excellent, inexpensive, and beneficial protection from ultraviolet exposure within various media, including, but not limited to, clear thermoplastics. The particular compounds are generally polymeric in nature including various chain lengths of polyoxyalkylenes thereon and are liquid in nature to facilitate handling and introduction within the target media. In addition, such ultraviolet absorbers also exhibit extremely low migratory properties thereby providing long-term protective benefits to the target media as well. This invention also concerns the end products, specific broadly defined types of compounds providing such beneficial characteristics, methods of making such low-color compounds, and methods of producing such clear, UV protected end products.
    • 具有液态性质的新型紫外线吸收化合物颜色较低(并且因此允许使用而不伴随必须添加大量其他着色剂来防止这种变色),并且在以前的波长范围内提供保护是非常有效的 本文提供了低色紫外线吸收剂失败的尝试。 此类化合物在各种介质(包括但不限于透明热塑性塑料)中提供了这种优异的,便宜的和有益的免受紫外线照射的保护。 特定化合物通常为聚合物,包括其上的各种链长的聚氧化烯,并且本质上为液体以便于在目标介质内处理和引入。 另外,这种紫外线吸收剂还表现出极低的迁移性质,从而为目标介质提供长期的保护益处。 本发明还涉及最终产品,提供这种有益特征的具体广义定义类型的化合物,制备这种低色化合物的方法以及生产这种透明的UV防护最终产品的方法。