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1. 发明申请

WO2008047101A2 MASS SPECTROMETER 审中-公开
标题翻译：质谱仪
公开(公告)号：WO2008047101A2
公开(公告)日：2008-04-24
申请号：PCT/GB2007003937
申请日：2007-10-16
申请人： MICROMASS LTD , KENNY DANIEL JAMES , BATEMAN ROBERT HAROLD , GREEN MARTIN , WILDGOOSE JASON LEE , PRINGLE STEVEN DEREK
发明人： KENNY DANIEL JAMES , BATEMAN ROBERT HAROLD , GREEN MARTIN , WILDGOOSE JASON LEE , PRINGLE STEVEN DEREK
CPC分类号： H01J49/005 , H01J49/0031 , H01J49/004 , H01J49/0045 , H01J49/065 , H01J49/34 , H01J49/4235
摘要： A collision or fragmentation cell (4) is disclosed comprising a plurality of electrodes wherein a first RF voltage (7a) is applied to an upstream group of electrodes and a second different RF voltage (7b) is applied to a downstream group of electrodes. The radial confinement of parent ions entering the collision or fragmentation cell (4) is optimised by the first RF voltage applied to the upstream group of electrodes and the radial confinement of daughter or fragment ions produced within the collision or fragmentation cell (4) is optimised by the second different RF voltage applied to the downstream group of electrodes.
摘要翻译：公开了一种碰撞或分裂单元（4），其包括多个电极，其中将第一RF电压（7a）施加到上游电极组，并且将第二不同RF电压（7b）施加到下游组电极。通过施加到上游电极组的第一RF电压来优化进入碰撞或破碎电池（4）的母体离子的径向约束，并且优化在碰撞或断裂电池（4）内产生的子或碎片离子的径向约束通过施加到下游组电极的第二不同RF电压。

2. 发明申请

WO2007125354A2 MASS SPECTROMETER 审中-公开
标题翻译：质谱仪
公开(公告)号：WO2007125354A2
公开(公告)日：2007-11-08
申请号：PCT/GB2007001589
申请日：2007-04-30
申请人： MICROMASS LTD , GREEN MARTIN , WILDGOOSE JASON LEE , PRINGLE STEVEN DEREK , KENNY DANIEL JAMES
发明人： GREEN MARTIN , WILDGOOSE JASON LEE , PRINGLE STEVEN DEREK , KENNY DANIEL JAMES
CPC分类号： H01J49/4235 , H01J49/065
摘要： An ion guide or mass analyser (2) is disclosed comprising a plurality of electrodes (2a) having apertures through which ions are transmitted in use. A pseudo-potential barrier is created at the exit of the ion guide or mass analyser (2). The amplitude or depth of the pseudo-potential barrier is inversely proportional to the mass to charge ratio of an ion. One or more transient DC voltages (4) are applied to the electrodes (2a) of the ion guide or mass analyser (2) in order to urge ions along the length of the ion guides or mass analyser (2). The amplitude of the transient DC voltage (4) applied to the electrode (2a) may be increased with time so that ions are caused to be emitted from the ion guide or mass analyser (2) in reverse order of their mass to charge ratio.
摘要翻译：公开了一种离子导向器或质量分析器（2），其包括具有孔的多个电极（2a），在使用中通过该孔具有离子。在离子导向器或质量分析器（2）的出口处产生伪势垒。伪势垒的幅度或深度与离子的质荷比成反比。一个或多个瞬态DC电压（4）被施加到离子导向器或质量分析器（2）的电极（2a），以促使沿着离子导向器或质量分析器（2）的长度的离子。施加到电极（2a）的瞬态直流电压（4）的振幅可以随时间增加，使得离子以其质荷比相反的顺序从离子导向器或质量分析器（2）发射。

3. 发明申请

WO2012085595A2 FAST PUSHING TIME OF FLIGHT MASS SPECTROMETER COMBINED WITH RESTRICTED MASS TO CHARGE RATIO RANGE DELIVERY 审中-公开
标题翻译：与限制质量组合的飞行质谱仪的快速推送时间以充电比例范围传送
公开(公告)号：WO2012085595A2
公开(公告)日：2012-06-28
申请号：PCT/GB2011052577
申请日：2011-12-22
申请人： MICROMASS LTD , GREEN MARTIN RAYMOND , KENNY DANIEL JAMES , WILDGOOSE JASON LEE
发明人： GREEN MARTIN RAYMOND , KENNY DANIEL JAMES , WILDGOOSE JASON LEE
IPC分类号： H01J49/40
CPC分类号： H01J49/401 , H01J49/0031 , H01J49/0086
摘要： Ions having a restricted range of mass to charge ratios are transmitted to the acceleration region of a Time of Flight mass analyser. A control system applies a first extraction pulse to an acceleration electrode in order to accelerate a first group of ions into the time of flight region at a first time T1, wherein tons having the lowest mass to charge ratio in the first group of ions have a time of flight ?T1min through the time of flight region and ions having the highest mass to charge ratio in the first group of ions have a time of flight ?T1max through the time of flight region. The control system applies a second extraction pulse to the acceleration electrode at a subsequent second time T2, wherein ?T1max- ?T1min = T2-T1 max.
摘要翻译：具有有限范围的质荷比的离子被传送到飞行时间质量分析器的加速区域。控制系统将第一提取脉冲施加到加速电极，以便在第一时间T1将第一组离子加速到飞行时间区域，其中在第一组离子中具有最低质荷比的吨具有飞行时间T1min通过飞行时间段，第一组离子中质荷比最高的离子在飞行时间段内具有飞行时间T1max。控制系统在随后的第二时间T2向加速电极施加第二提取脉冲，其中ΔT1max-ΔT1min= T2-T1max。

4. 发明申请

WO2008071993A3 MASS SPECTROMETER 审中-公开
标题翻译：质谱仪
公开(公告)号：WO2008071993A3
公开(公告)日：2009-04-02
申请号：PCT/GB2007004820
申请日：2007-12-14
申请人： MICROMASS LTD , KENNY DANIEL JAMES , WILDGOOSE JASON LEE , GREEN MARTIN
发明人： KENNY DANIEL JAMES , WILDGOOSE JASON LEE , GREEN MARTIN
IPC分类号： H01J49/40
CPC分类号： H01J49/401
摘要： A mass spectrometer is disclosed comprising an orthogonal acceleration Time of Flight mass analyser. A pulse or packet of ions is released either from an ion trap (7) or alternatively from a travelling wave ion guide arranged upstream of an orthogonal acceleration electrode (2) which forms part of the Time of Flight mass analyser. Ions in the pulse or packet of ions which is released become temporally dispersed and the orthogonal acceleration electrode (2) is energised multiple times prior the release of a subsequent pulse or packet of ions.
摘要翻译：公开了一种质谱仪，其包括正交加速时间飞行质量分析器。从离子阱（7）或替代地从布置在作为飞行时间质量分析器的一部分的正交加速电极（2）的上游的行波离子导向器释放脉冲或包离子。释放的脉冲或离子束中的离子变得暂时分散，并且在随后的脉冲或包离子的释放之前，正交加速电极（2）被多次通电。

5. 发明申请

WO2013027054A2 ION TRAP WITH SPATIALLY EXTENDED ION TRAPPING REGION 审中-公开
标题翻译：离子阱与空间扩展的离子俘获区域
公开(公告)号：WO2013027054A2
公开(公告)日：2013-02-28
申请号：PCT/GB2012052053
申请日：2012-08-22
申请人： MICROMASS LTD , GILES KEVIN , GREEN MARTIN RAYMOND , KENNY DANIEL JAMES , LANGRIDGE DAVID J , WILDGOOSE JASON LEE
发明人： GILES KEVIN , GREEN MARTIN RAYMOND , KENNY DANIEL JAMES , LANGRIDGE DAVID J , WILDGOOSE JASON LEE
IPC分类号： H01J49/42
CPC分类号： H01J49/424 , H01J49/421 , H01J49/422 , H01J49/4285
摘要： A mass or mass to charge ratio selective ion trap is disclosed having an increased charge storage capacity. A RF voltage acts to confine ions in a first (y) direction within the ion trap. A DC voltage and/or an RF voltage acts to confine ions in a second (x) direction within the ion trap. A quadratic DC potential well acts to confine ions in a third (z) direction within the ion trap. Ions are excited in the third (z) direction and are caused to be mass or mass to charge ratio selectively ejected in the third (z) direction.
摘要翻译：公开的具有增加的电荷存储容量的质量或质荷比选择离子阱。 RF电压用于在离子阱内的第一（y）方向上限制离子。直流电压和/或RF电压用于在离子阱内的第二（x）方向上限制离子。二次直流势阱用于在离子阱内的第三（z）方向上限制离子。离子在第三（z）方向上被激发，并且导致质量或质荷比选择性地在第三（z）方向上喷射。

6. 发明申请

WO2009007739A2 MASS SPECTROMETER 审中-公开
标题翻译：质谱分析仪
公开(公告)号：WO2009007739A2
公开(公告)日：2009-01-15
申请号：PCT/GB2008002402
申请日：2008-07-14
申请人： MICROMASS LTD , GREEN MARTIN , KENNY DANIEL JAMES , LANGRIDGE DAVID , WILDGOOSE JASON LEE
发明人： GREEN MARTIN , KENNY DANIEL JAMES , LANGRIDGE DAVID , WILDGOOSE JASON LEE
IPC分类号： H01J49/42
CPC分类号： H01J49/4205 , H01J49/02 , H01J49/4225
摘要： A mass spectrometer is disclosed comprising a quadrupole rod set ion trap (2, 3) wherein a potential field is created at the exit of the ion trap (4, 5) which decreases with increasing radius in one radial direction. Ions within the ion trap (2, 3) are mass selectively excited in a radial direction. Ions which have been excited in the radial direction experience a potential field which no longer confines the ions axially within the ion trap but which instead acts to extract the ions and hence causes the ions to be ejected axially from the ion trap (2, 3).
摘要翻译：公开了一种包括四极杆组离子阱（2,3）的质谱仪，其中在离子阱（4,5）的出口处产生势能场，其在一个径向方向上随半径增加而减小。离子阱（2,3）内的离子在径向方向上被质量选择性地激发。已经在径向激发的离子经历势场，该势场不再将离子轴向限制在离子阱内，而是用于提取离子并因此导致离子从离子阱（2,3）轴向射出，。

7. 发明申请

WO2009087402A3 LINEAR ION TRAP 审中-公开
标题翻译：线性离子阱
公开(公告)号：WO2009087402A3
公开(公告)日：2010-02-18
申请号：PCT/GB2009000071
申请日：2009-01-12
申请人： MICROMASS LTD , GREEN MARTIN RAYMOND , KENNY DANIEL JAMES , LANGRIDGE DAVID , WILDGOOSE JASON LEE
发明人： GREEN MARTIN RAYMOND , KENNY DANIEL JAMES , LANGRIDGE DAVID , WILDGOOSE JASON LEE
IPC分类号： H01J49/42
CPC分类号： H01J49/4225 , H01J49/4285
摘要： A linear ion trap (6,7,8) is disclosed comprising a central quadrupole rod set (6) and a post-filter quadrupole rod set (8). A 180° phase difference is maintained between axially adjacent rod electrodes of the central quadrupole rod set (6) and the post-filter quadrupole (8) so that an axial pseudo-potential barrier is created between the central quadrupole rod set (6) and the post-filter quadrupole (8). A supplementary AC voltage is applied to the rods of the central quadrupole (6) in order to radially excite ions which are desired to be ejected from the ion trap. The ions are ejected from the ion trap (6,7,8) non-adiabatically in an axial direction.
摘要翻译：公开了一种线性离子阱（6,7,8），其包括中心四极杆组（6）和后过滤四极杆组（8）。在中心四极杆组（6）和后过滤器四极（8）的轴向相邻杆电极之间保持180°相位差，使得在中心四极杆组（6）和后滤器四极杆（8）。补充的交流电压施加到中心四极杆（6）的杆上，以便径向地激发希望从离子阱排出的离子。离子从离子阱（6,7,8）沿轴向非绝热地排出。

8. 发明申请

WO2012164314A2 ION INLET FOR A MASS SPECTROMETER 审中-公开
标题翻译：离子入口用于质谱仪
公开(公告)号：WO2012164314A2
公开(公告)日：2012-12-06
申请号：PCT/GB2012051261
申请日：2012-06-01
申请人： MICROMASS LTD , GORDON DAVID , KENNY DANIEL JAMES , PRINGLE STEVEN DEREK
发明人： GORDON DAVID , KENNY DANIEL JAMES , PRINGLE STEVEN DEREK
IPC分类号： H01J49/24
CPC分类号： H01J49/04 , H01J49/067 , H01J49/24
摘要： An ion inlet for a mass spectrometer is disclosed comprising a housing having a sampling orifice (12) and an atmospheric pressure orifice (13). One or more gas outlets are provided in the housing. Gas is drawn through the sampling orifice (12) by a pump (14) so that the gas exits via the one or more gas outlets.
摘要翻译：公开了一种用于质谱仪的离子入口，其包括具有采样孔（12）和大气压力孔（13）的壳体。一个或多个气体出口设置在壳体中。通过泵（14）将气体抽吸通过采样孔（12），使得气体经由一个或多个气体出口排出。

9. 发明申请

WO2008087389A2 MASS SPECTROMETER 审中-公开
标题翻译：质谱仪
公开(公告)号：WO2008087389A2
公开(公告)日：2008-07-24
申请号：PCT/GB2008000121
申请日：2008-01-15
申请人： MICROMASS LTD , KENNY DANIEL JAMES , WILDGOOSE JASON LEE
发明人： KENNY DANIEL JAMES , WILDGOOSE JASON LEE
CPC分类号： H01J49/401
摘要： A Time of Flight mass analyser is disclosed wherein the time period between successive orthogonal acceleration pulses is less than the time of flight of ions having the maximum mass to charge ratio of interest. As a result, some ions are subject to wrap-around and will appear in a subsequent mass spectrum. Mass spectra obtained at two different sampling rates may be compared and mass peaks relating to ions which have and have not been subject to wrap-around may be identified.
摘要翻译：公开了一种飞行时间质量分析器，其中连续正交加速脉冲之间的时间段小于具有最大质荷比的离子的飞行时间。结果，一些离子被卷绕并将出现在随后的质谱中。可以比较以两种不同采样速率获得的质谱，并且可以鉴定与已经和未被卷绕的离子有关的质谱峰。

10. 发明申请

WO2011089419A3 MASS TO CHARGE RATIO SELECTIVE EJECTION FROM ION GUIDE HAVING SUPPLEMENTAL RF VOLTAGE APPLIED THERETO 审中-公开
标题翻译：从适用于补充RF电压的离子导轨充电选择性引出的质量
公开(公告)号：WO2011089419A3
公开(公告)日：2011-09-15
申请号：PCT/GB2011050073
申请日：2011-01-18
申请人： MICROMASS LTD , HOYES JOHN BRIAN , KENNY DANIEL JAMES , LANGRIDGE DAVID
发明人： HOYES JOHN BRIAN , KENNY DANIEL JAMES , LANGRIDGE DAVID
IPC分类号： H01J49/06 , H01J49/42
CPC分类号： H01J49/34 , H01J49/065 , H01J49/4235 , H01J49/4275 , H01J49/429
摘要： An ion guide is disclosed wherein an axial DC voltage barrier 103 is created at the exit of the ion guide. A primary RF voltage is applied to the electrodes in order to confine ions radially within the ion guide. A supplemental RF voltage is also applied to the electrodes. The supplemental RF voltage has a greater axial repeat length than that of the primary RF voltage. The amplitude of the supplemental RF voltage is increased with time causing ions to become unstable and gain sufficient axial kinetic energy such that the ions overcome the axial DC voltage barrier. Ions emerge axially from the ion guide in mass to charge ratio order.
摘要翻译：公开了一种离子导向器，其中在离子导向器的出口处产生轴向DC电压屏障103。将初级RF电压施加到电极，以便将离子径向限制在离子导向器内。补充的RF电压也被施加到电极。补充RF电压具有比初级RF电压更大的轴向重复长度。补充RF电压的幅度随时间增加，导致离子变得不稳定并获得足够的轴向动能，使得离子克服轴向DC电压屏障。离子以质量与电荷的比例顺序从离子导向器轴向出现。

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