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1. 发明申请

WO2013040519A2 IMPROVED ELECTROLYTIC CELL COVERS COMPRISING A RESIN COMPOSITION POLYMERIZED WITH A GROUP 8 OLEFIN METATHESIS CATALYST 审中-公开
标题翻译：改进的电解槽包含与8族烯烃METATHESIS催化剂聚合的树脂组合物
公开(公告)号：WO2013040519A2
公开(公告)日：2013-03-21
申请号：PCT/US2012/055663
申请日：2012-09-14
申请人： MATERIA, INC. , GIARDELLO, Michael, A. , TRIMMER, Mark, S. , CRUCE, Christopher, J. , STEPHEN, Anthony, R. , TONER, Stuart, A. M. , PAPPANO, Albert, E.
发明人： GIARDELLO, Michael, A. , TRIMMER, Mark, S. , CRUCE, Christopher, J. , STEPHEN, Anthony, R. , TONER, Stuart, A. M. , PAPPANO, Albert, E.
IPC分类号： C25B9/00 , G12B9/04 , C08J5/00
CPC分类号： C25B9/00 , B29C39/003 , B29C67/246 , B29K2023/00 , B29K2023/38 , B29K2105/0014 , B29K2995/0029 , B29L2031/7146 , C08G61/02 , C08G2120/00 , C08G2261/3325 , C08G2261/418 , C08G2261/58 , C25B1/34
摘要： Articles of manufacture possessing corrosion resistance characteristics are described, in particular for use in the chlor-alkali and other industries. The articles are formed from a resin composition, e.g., a cyclic olefin composition, polymerized with a Group 8 olefin metathesis catalyst. In particular aspects, an electrolytic cell component, such as a cell cover for use in the electrolysis of brine, may be formed from the resin composition. Among other benefits, such articles provide improved corrosion resistance compared to articles molded from other resin compositions, such as Fiberglass reinforced polyesters and vinyl esters, and two-component dicyclopentadiene (DCPD) resins comprising molybdenum or tungsten pre-catalysts.
摘要翻译：描述了具有耐腐蚀特性的制品，特别是用于氯碱等行业。制品由用第8族烯烃复分解催化剂聚合的树脂组合物形成，例如环烯烃组合物。在特定方面，可以由树脂组合物形成用于电解盐水的电解池组件，例如电池盖。除了其它益处之外，与由其它树脂组合物（例如玻璃纤维增强聚酯和乙烯基酯）和包含钼或钨预催化剂的双组分二环戊二烯（DCPD）树脂模制的制品相比，这些制品提供了改进的耐腐蚀性。

2. 发明申请

WO2012174502A2 ADHESION PROMOTERS AND GEL-MODIFIERS FOR OLEFIN METATHESIS COMPOSITIONS 审中-公开
标题翻译：粘合剂组合物的粘合促进剂和凝胶改性剂
公开(公告)号：WO2012174502A2
公开(公告)日：2012-12-20
申请号：PCT/US2012/042850
申请日：2012-06-17
申请人： MATERIA, INC. , WANG, Li-sheng , STEPHEN, Anthony, R. , BOOTHE, Paul, W. , SCHULZE, Tessa , GIARDELLO, Michael, A. , TRIMMER, Mark, S. , CRUCE, Christopher, J. , MOTAMEDI, Farshad, J. , EDGECOMBE, Brian
发明人： WANG, Li-sheng , STEPHEN, Anthony, R. , BOOTHE, Paul, W. , SCHULZE, Tessa , GIARDELLO, Michael, A. , TRIMMER, Mark, S. , CRUCE, Christopher, J. , MOTAMEDI, Farshad, J. , EDGECOMBE, Brian
IPC分类号： C08L45/00 , C08L65/00 , C08K5/16 , C08K5/14 , C08F32/02
CPC分类号： C03C25/30 , C08F32/02 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C08K5/0025 , C08K5/14 , C08K5/29 , C08K2201/014 , C08L65/00
摘要： This invention relates to compositions and methods for improving the adhesion of resin compositions to substrate materials, pre-treating substrate materials to improve the adhesion of resin compositions to the substrate materials, and/or controlling gel formation of resin compositions. More particularly, the invention relates to compositions and methods for improving the adhesion of ring opening metathesis polymerization (ROMP) compositions to substrate materials using adhesion promoters containing isocyariate groups in a resin composition. The invention also relates to methods for improving the adhesion of resin compositions to substrate materials by pre-treating substrate materials with adhesion promoters containing isocyanate groups. The invention further relates to a method of providing a gel- modified ROMP composition, in which a hydroperoxide is added to a ROMP polymerizable resin composition in order to control gel formation of the polymerizing resin. An improved ROMP composition is further disclosed, comprising a cyclic olefin, a ROMP metathesis catalyst, an adhesion promoter, and an added hydroperoxide gel modifier. The polymer products produced via ROMP reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of catalysis, organic synthesis, and polymer and materials chemistry and manufacture.
摘要翻译：本发明涉及用于改善树脂组合物与基材的粘合性，预处理基材以改善树脂组合物与基材的粘合性和/或控制树脂组合物凝胶形成的组合物和方法。更具体地，本发明涉及使用在树脂组合物中含有异质基团的粘合促进剂来改善开环易位聚合（ROMP）组合物与基材的粘合性的组合物和方法。本发明还涉及通过用含有异氰酸酯基团的粘合促进剂预处理底物材料来改善树脂组合物对基材的粘附性的方法。本发明还涉及提供凝胶改性的ROMP组合物的方法，其中向ROMP可聚合树脂组合物中加入过氧化氢以控制聚合树脂的凝胶形成。进一步公开了改进的ROMP组合物，其包含环烯烃，ROMP复分解催化剂，粘合促进剂和加入的氢过氧化物凝胶改性剂。通过本发明的ROMP反应生产的聚合物产品可用于广泛的材料和复合材料应用。本发明可用于催化，有机合成，聚合物和材料的化学和制造领域。

3. 发明申请

WO2015003147A1 LIQUID MOLDING COMPOSITIONS 审中-公开
标题翻译：液体成型组合物
公开(公告)号：WO2015003147A1
公开(公告)日：2015-01-08
申请号：PCT/US2014/045440
申请日：2014-07-03
申请人： MATERIA, INC.
发明人： CRUCE, Christopher, J. , GIARDELLO, Michael, A. , TRIMMER, Mark, S. , STEPHEN, Anthony, R. , BOOTHE, Paul, W. , EDGECOMBE, Brian , MOORE, Jason, L.
IPC分类号： C08G61/08 , C08F4/80
CPC分类号： C08G61/08 , C07C13/38 , C07C13/61 , C08F4/80 , C08G2261/3325 , C08G2261/418 , C08J5/043 , C08J2323/20 , C08K7/14 , C08L65/00
摘要： The present invention relates to methods and compositions for olefin metathesis. More particularly, the present invention relates to methods and compositions for ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles and/or polymer composite articles via ROMP Polymer products produced via the metathesis reactions of the invention may be utilized in a wide range of materials and composite applications. The invention has utility in the fields of polymer and materials chemistry and manufacture.
摘要翻译：本发明涉及烯烃复分解的方法和组合物。更具体地说，本发明涉及用于开环易位聚合（ROMP）反应的方法和组合物以及通过ROMP制备聚合物制品和/或聚合物复合制品通过本发明的复分解反应生产的聚合物产品可用于宽材料和复合材料应用范围。本发明在聚合物和材料化学和制造领域具有实用性。

4. 发明申请

WO2017053690A1 METAL CARBENE OLEFIN METATHESIS CATALYSTS 审中-公开
标题翻译： METAL CARBENE OLEFIN METATHESIS催化剂
公开(公告)号：WO2017053690A1
公开(公告)日：2017-03-30
申请号：PCT/US2016/053288
申请日：2016-09-23
申请人： MATERIA, INC.
发明人： GIARDELLO, Michael, A. , TRIMMER, Mark, S. , WANG, Li-Sheng , DUFFY, Noah, H. , JOHNS, Adam, M. , RODAK, Nicholas, J. , FIAMENGO, Bryan, A. , PHILLIPS, John, H.
IPC分类号： C07F15/00 , C08F4/80 , C08G61/06 , C08G61/08
CPC分类号： C07F15/0046 , C08G61/08 , C08G2261/3325 , C08G2261/418 , C08L65/00
摘要： This invention relates generally to metal carbene olefin metathesis catalyst compounds, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, articles of manufacture comprising such compounds, and the use of such compounds in the metathesis of olefins and olefin compounds. The invention has utility in the fields of catalysts, organic synthesis, polymer chemistry, and industrial and fine chemicals industry.
摘要翻译：本发明一般涉及金属卡宾烯烃复分解催化剂化合物，这些化合物的制备，包含这些化合物的组合物，使用这些化合物的方法，包含这些化合物的制品，以及这些化合物在烯烃和烯烃的复分解中的用途化合物。本发明可用于催化剂，有机合成，高分子化学，工业和精细化工等领域。

5. 发明申请

WO2014210076A1 THERMAL INSULATION 审中-公开
标题翻译：热绝缘
公开(公告)号：WO2014210076A1
公开(公告)日：2014-12-31
申请号：PCT/US2014/043968
申请日：2014-06-24
申请人： MATERIA, INC.
发明人： CRUCE, Christopher, J. , GIARDELLO, Michael, A. , CONLEY, Brain, L. , STEPHEN, Anthony R.
IPC分类号： C08G61/08
CPC分类号： C08G61/02 , B05D7/222 , C08G61/08 , C08G2261/122 , C08G2261/135 , C08G2261/1412 , C08G2261/3324 , C08G2261/3325 , C08G2261/418 , C08G2261/58 , C08G2261/592 , C08G2261/596 , C08G2261/62 , C08G2261/76 , C08G2261/90 , C08L65/00 , C09D165/00 , F16L58/1054 , F16L58/181 , F16L59/028 , F16L59/14 , F16L59/143 , F16L59/20
摘要： The present invention is directed to addressing one or more of the aforementioned concerns and relates to thermal insulation materials and thermal insulation material compositions and methods for thermally insulating pipelines and associated equipment, structures, and objects used in offshore drilling. The present invention is directed to articles of manufacture comprising the thermal insulation materials and/or thermal insulation material compositions of the invention. More particularly the present invention relates to the use of ring opening metathesis polymerization polymers (ROMP polymers) and/or ROMP polymer composites for thermally insulating pipelines and associated equipment, structures, and objects used in offshore oil drilling.
摘要翻译：本发明涉及解决上述问题中的一个或多个，并且涉及隔热材料和绝热材料组合物和用于隔热管道的相关设备，结构和海上钻井中使用的物体的方法。本发明涉及包含本发明的隔热材料和/或绝热材料组合物的制品。更具体地说，本发明涉及开环易位聚合聚合物（ROMP聚合物）和/或ROMP聚合物复合材料用于隔热管道及相关设备，结构和用于海上石油钻井中的物体的用途。

6. 发明申请

WO2018034931A1 METATHESIS CATALYSTS 审中-公开
标题翻译： METATHESIS催化剂
公开(公告)号：WO2018034931A1
公开(公告)日：2018-02-22
申请号：PCT/US2017/046262
申请日：2017-08-10
申请人： MATERIA, INC.
发明人： HERRON, Jessica, R. , PEDERSON, Richard, L. , JOHNS, Adam, M. , GIARDELLO, Michael, A.
IPC分类号： B01J35/10 , C07F7/02 , B01J21/08
摘要： This invention relates generally to olefin metathesis catalysts, to the preparation of such compounds, compositions comprising such compounds, methods of using such compounds, and the use of such compounds in the metathesis of olefins and in the synthesis of related olefin metathesis catalysts. The invention has utility in the fields of catalysis, organic synthesis, polymer chemistry, and in industrial applications such as oil and gas, fine chemicals and pharmaceuticals.
摘要翻译：本发明一般涉及烯烃复分解催化剂，涉及这些化合物的制备，包含此类化合物的组合物，使用此类化合物的方法以及这些化合物在烯烃复分解反应和合成中的用途的相关烯烃复分解催化剂。本发明在催化，有机合成，高分子化学以及石油和天然气，精细化学品和药物等工业应用领域具有实用性。

7. 发明申请

WO2003020504A1 INFUSION OF CYCLIC OLEFIN RESINS INTO POROUS MATERIALS 审中-公开
标题翻译：将环烯烃树脂浸入多孔材料中
公开(公告)号：WO2003020504A1
公开(公告)日：2003-03-13
申请号：PCT/US2002/027654
申请日：2002-08-30
申请人： MATERIA, INC.
发明人： CRUCE, Christopher, J. , FILICE, Gary, W. , GIARDELLO, Michael, A. , STEPHEN, Anthony, R. , TRIMMER, Mark, S.
IPC分类号： B32B3/26
CPC分类号： C08L65/00 , C04B41/009 , C04B41/4857 , C04B41/63 , C04B2111/27 , C08J9/42 , C08J2423/00 , C08K3/01 , C08K5/098 , C08K5/5425 , C08L23/02 , C08L79/02 , C08L97/02 , Y10T428/249925 , C04B41/4521 , C04B28/02 , C08L2666/26 , C08L2666/02 , C08L2666/22 , C08L2666/06
摘要： The present invention relates to novel compositions comprising porous materials infused with polymers obtained from metathesis reactions, for example ROMP derived polymers and ADMET derived polymers. The invention further relates to cyclic olefin monomer formulations, including ruthenium or osmium carbene metathesis catalysts, useful for the infusion of porous materials. Also disclosed are methods for preparing the porous materials infused with cyclic olefin resin formulations.
摘要翻译：本发明涉及包含由复分解反应物获得的聚合物（例如ROMP衍生的聚合物和ADMET衍生的聚合物）注入的多孔材料的新型组合物。本发明还涉及可用于输注多孔材料的环烯烃单体制剂，包括钌或咔啉易位催化剂。还公开了制备注入环状烯烃树脂配方的多孔材料的方法。

8. 发明申请

WO2015106210A1 METHOD AND COMPOSITION FOR IMPROVING ADHESION OF METATHESIS COMPOSITIONS TO SUBSTRATES 审中-公开
标题翻译：用于改善基材组成的粘合的方法和组合物
公开(公告)号：WO2015106210A1
公开(公告)日：2015-07-16
申请号：PCT/US2015/011048
申请日：2015-01-12
申请人： MATERIA, INC.
发明人： STEPHEN, Anthony, R. , CRUCE, Christopher, J. , TRIMMER, Mark, S. , GIARDELLO, Michael, A.
IPC分类号： C03C25/30
CPC分类号： C08G61/02 , B29B15/122 , B29K2309/08 , C03C17/328 , C03C25/30 , C08G61/08 , C08G2261/3325 , C08G2261/964 , C08J5/043 , C08J2323/20 , C08K3/36 , C08K3/40 , C08K5/14 , C08K5/5419 , C08K5/5425 , C08K7/14 , C08K7/28 , C08L65/00 , C09D165/00
摘要： A method of improving the adhesion of metathesis compositions, such as ring-opening metathesis polymerization (ROMP) compositions, to a substrate is disclosed, in which an adhesion promoter is added to a polymerizable resin composition in order to improve the adhesion of the polymerizing resin to a substrate material. The addition of the adhesion promoter has been found to provide beneficial improvements in the adhesion of metathesis, especially ROMP, compositions to substrates, particularly glass surfaces, leading to improved characteristics in ROMP materials formed therefrom. The adhesion promoter generally comprises a functionalized silane compound and a peroxide compound. A ROMP composition is further disclosed comprising a cyclic olefin, a ROMP metathesis catalyst, and the adhesion promoter.
摘要翻译：公开了一种改善复分解组合物如开环易位聚合（ROMP）组合物对基材的粘合性的方法，其中向可聚合树脂组合物中加入粘合促进剂以改善聚合树脂的粘合性涉及基材。已经发现添加粘合促进剂对复分解素，特别是ROMP，组合物对基材，特别是玻璃表面的粘附性提供有益的改进，导致由其形成的ROMP材料的改进的特性。粘合促进剂通常包含官能化的硅烷化合物和过氧化物。还公开了一种ROMP组合物，其包含环烯烃，ROMP复分解催化剂和粘合促进剂。

9. 发明申请

WO2014144634A1 IN-MOLD COATING OF ROMP POLYMERS 审中-公开
标题翻译： ROMP聚合物的模内涂层
公开(公告)号：WO2014144634A1
公开(公告)日：2014-09-18
申请号：PCT/US2014/029130
申请日：2014-03-14
申请人： MATERIA, INC.
发明人： STEPHEN, Anthony, R. , CRUCE, Christopher, J. , TRIMMER, Mark, S. , GIARDELLO, Michael, A.
IPC分类号： C08F4/80
CPC分类号： C08G61/08 , B29C37/0032 , B29C41/00 , B29C41/22 , B29K2075/00 , C08G2261/3325 , C08G2261/418 , C08K5/05 , C08K5/053 , C08K5/101 , C08L65/00 , Y10T428/31938
摘要： The present invention relates to in-mold coating of a cyclic olefin polymer. More particularly, the present invention relates to methods and compositions for in-mold coating cyclic olefin polymers prepared by ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. Polymer products produced via the metathesis reactions of the invention may be utilized for a wide range of materials and composite applications. The invention has utility in the fields of polymer and material chemistry and manufacture.
摘要翻译：本发明涉及环状烯烃聚合物的模内涂覆。更具体地，本发明涉及通过开环易位聚合（ROMP）反应制备的环烯烃聚合物的模内涂布方法和组合物，以及通过ROMP制备聚合物制品。通过本发明的复分解反应产生的聚合物产物可用于广泛的材料和复合材料应用。本发明在聚合物和材料化学和制造领域具有实用性。

10. 发明申请

WO2014134333A1 METAL CARBENE OLEFIN METATHESIS TWO CATALYST COMPOSITION 审中-公开
标题翻译： METAL CARBENE OLEFIN METATHESIS两种催化剂组合物
公开(公告)号：WO2014134333A1
公开(公告)日：2014-09-04
申请号：PCT/US2014/019082
申请日：2014-02-27
申请人： MATERIA, INC.
发明人： STEPHEN, Anthony, R. , CRUCE, Christopher, J. , GIARDELLO, Michael, A.
IPC分类号： C08F4/80 , C08F132/08 , C08K9/06
CPC分类号： C08F32/00 , C08F4/80 , C08F132/08 , C08G61/08 , C08G2261/3325 , C08G2261/418
摘要： This invention relates to olefin metathesis catalysts and methods for controlling olefin metathesis reactions. More particularly, the present invention relates to methods and compositions for catalyzing and controlling ring opening metathesis polymerization (ROMP) reactions and the manufacture of polymer articles via ROMP. This invention also relates to olefin metathesis catalyst compositions comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a ROMP composition comprising a resin composition comprising at least one cyclic olefin, and an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts. This invention also relates to a method of making an article comprising combining an olefin metathesis catalyst composition comprising at least two metal carbene olefin metathesis catalysts with a resin composition comprising at least one cyclic olefin, thereby forming a ROMP composition, and subjecting the ROMP composition to conditions effective to polymerize the ROMP composition.
摘要翻译：本发明涉及烯烃复分解催化剂和控制烯烃复分解反应的方法。更具体地说，本发明涉及用于催化和控制开环易位聚合（ROMP）反应和通过ROMP制备聚合物制品的方法和组合物。本发明还涉及包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物。本发明还涉及包含至少一种环烯烃的树脂组合物和包含至少两种金属卡宾烯烃复分解催化剂的烯烃易位催化剂组合物的ROMP组合物。本发明还涉及一种制备制品的方法，包括将包含至少两种金属卡宾烯烃复分解催化剂的烯烃复分解催化剂组合物与包含至少一种环烯烃的树脂组合物组合，从而形成ROMP组合物，并将ROMP组合物有效聚合ROMP组合物的条件。

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