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    • 9. 发明申请
    • METHODS FOR PREVENTING OR REMEDIATING XANTHAN DEPOSITION
    • 防止或补救西藏沉积物的方法
    • WO2009091652A2
    • 2009-07-23
    • PCT/US2009/030378
    • 2009-01-08
    • M-I L.L.C.HORTON, Robert, L.DARRING, Michael, T.MOLINA, Hiram
    • HORTON, Robert, L.DARRING, Michael, T.MOLINA, Hiram
    • C09K8/52C09K8/524
    • C09K8/524
    • Methods for remediation and/or prevention of polymer deposition on surfaces, in particular, on surfaces of drilling machinery and earth formations in the petroleum industry are described herein. Embodiments disclosed herein relate to a method of remediating xanthan deposition, the method including the steps of contacting xanthan deposition, including xanthan complexed with polyvalent metal ions, with a remediation fluid containing at least one chelating agent; and allowing the fluid to dissolve the xanthan deposition. Also disclosed is a method of preventing polymer deposition, including emplacing a wellbore fluid including a crosslinkable polymer and at least one chelating agent in a wellbore; wherein the at least one chelating agent complexes with polyvalent metal ions present in the wellbore. Also disclosed is an improved wellbore fluid including a base fluid; a polymer comprising chemical groups reactive to polyvalent metal ions found downhole; and at least one chelating agent; wherein the least one chelating agent complexes with polyvalent metal ions downhole.
    • 本文描述了用于修复和/或防止聚合物沉积在表面上,特别是在石油工业中的钻井机械和地层的表面上的方法。 本文公开的实施方案涉及一种补救黄原胶沉积的方法,该方法包括将包含与多价金属离子络合的黄原胶的黄原胶沉积物与含有至少一种螯合剂的修复液接触的步骤; 并允许流体溶解黄原胶沉积物。 还公开了一种防止聚合物沉积的方法,包括在井筒中放置包括可交联聚合物和至少一种螯合剂的井眼流体​​; 其中所述至少一种螯合剂与存在于所述井筒中的多价金属离子络合。 还公开了一种改进的井筒流体,其包括基础流体; 包含与在井下发现的多价金属离子反应的化学基团的聚合物; 和至少一种螯合剂; 其中所述至少一种螯合剂与井下的多价金属离子络合。
    • 10. 发明申请
    • DELAYED PHASE CHANGING AGENT FOR INVERT EMULSION DRILLING FLUID
    • 延迟相变化剂用于反相乳液钻井液
    • WO2004069958A1
    • 2004-08-19
    • PCT/US2004/002969
    • 2004-02-03
    • M-I L.L.C.HORTON, Robert, L.PRASEK, Bethica, B.EVANS, Frank, E.LUYSTER, MarcMASON, SteveGREEN, Taylor
    • HORTON, Robert, L.PRASEK, Bethica, B.EVANS, Frank, E.LUYSTER, MarcMASON, SteveGREEN, Taylor
    • C09K7/06
    • C09K8/36C09K8/28Y10S507/929
    • A method of controlling and delaying the inversion of a drilling fluid and the wettability s of a filtercake by using a delayed phase changing agent. The filtercake is preferably formed while drilling a subterranean formation using a drilling fluid includes: an oleaginous fluid; a nono-leaginous fluid; an amine surfactant having the structure: wherein R is a C 12 -C 22 aliphatic hydrocarbon; R' is an independently selectable from hydrogen or C 1 to C 3 alkyl; A is NH or O, and 1 ≤ x+y ≤ 3. In the method, the filter cake is exposed to a delayed phase changing agent selected from the group consisting of aliphatic amine acids, salts of aliphatic amine acids and combinations thereof. In one preferred illustrative embodiment, the delayed phase changing agent is delivered in the form of a pill, the pill including a carrier fluid, a viscosifier and the delayed phase changing agent. The delayed phase changing agent may be selected from ethylene diamine tetraacetic acid, alkali metal salts of ethylene diamine tetraacetic acid and combinations of these and similar compounds.
    • 通过使用延迟相变剂控制和延迟钻井液的倒置和滤饼的润湿性的方法。 滤饼优选地在使用钻井液钻地层时形成,包括:含油液体; 非致命的流体; 具有以下结构的胺表面活性剂:其中R是C 12 -C 22脂族烃; R'可独立地选自氢或C 1至C 3烷基; A是NH或O,1 <= x + y <= 3.在该方法中,滤饼暴露于选自脂族胺酸,脂族胺酸盐和其组合的延迟相变剂 。 在一个优选的说明性实施方案中,延迟相变剂以丸剂的形式递送,丸剂包括载体流体,增粘剂和延迟相变剂。 延迟相变剂可以选自乙二胺四乙酸,乙二胺四乙酸的碱金属盐,以及这些和类似化合物的组合。