专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

1. 发明申请

WO2012054499A1 ACETIC ACID PRODUCTION PROCESS 审中-公开
标题翻译：醋酸生产工艺
公开(公告)号：WO2012054499A1
公开(公告)日：2012-04-26
申请号：PCT/US2011/056733
申请日：2011-10-18
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P. , SALISBURY, Brian, A. , HALLIMAN, Noel, C.
发明人： SALISBURY, Brian, A. , HALLIMAN, Noel, C.
IPC分类号： G01N21/65 , C07C51/12 , C07C13/08
CPC分类号： G01N21/65 , C07C51/12 , G01N2021/8416 , C07C53/08
摘要： Disclosed is a method for controlling an acetic acid production process. The method comprises: (i) reacting methanol and carbon monoxide in the presence of a carbonylation catalyst, a catalyst stabilizer, methyl iodide, water, and methyl acetate to produce a reactor mixture which comprises the catalyst, the catalyst stabilizer, methanol, carbon monoxide, carbon dioxide, methyl iodide, methyl acetate, water, and acetic acid; (ii) measuring the concentration of a component of the reactor mixture by Raman spectroscopic analysis; and (iii) adjusting the component concentration in the reactor mixture in response to the measured concentration. The method of the invention is particularly useful for measuring and controlling the concentration of carbon monoxide in the reactor liquid mixture.
摘要翻译：公开了一种控制乙酸生产方法的方法。该方法包括：（i）在羰基化催化剂，催化剂稳定剂，甲基碘，水和乙酸甲酯的存在下使甲醇和一氧化碳反应，生成包含催化剂，催化剂稳定剂，甲醇，一氧化碳，二氧化碳，甲基碘，乙酸甲酯，水和乙酸; （ii）通过拉曼光谱分析测量反应器混合物的组分浓度; 和（iii）响应于测量的浓度调节反应器混合物中的组分浓度。本发明的方法对于测量和控制反应器液体混合物中一氧化碳的浓度特别有用。

2. 发明申请

WO2016040318A1 METHODS OF USING HOMOGENOUS RHODIUM CATALYSTS WITH N-HETEROCYCLIC CARBENE LIGANDS FOR THE HYDROFORMYLATION OF OLEFINS AND SUBSTITUTED OLEFINS 审中-公开
标题翻译：使用均相硫酸镍催化剂与N-杂环碳酸酯配体进行烯烃和取代的烯烃的氢化反应的方法
公开(公告)号：WO2016040318A1
公开(公告)日：2016-03-17
申请号：PCT/US2015/048931
申请日：2015-09-08
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.
发明人： MANDIMUTSIRA, Beaven, S. , WHITE, Daniel, F. , SALISBURY, Brian, A.
IPC分类号： C07C45/50 , C07C47/04 , C07D233/02 , B01J31/22 , B01J23/46
CPC分类号： C07C45/50 , B01J31/20 , B01J31/2213 , B01J31/2295 , B01J2231/321 , B01J2531/822 , C07C47/02 , C07C47/19
摘要： A method of using homogenous rhodium catalysts comprising N-heterocyclic carbene ligands for the hydroformylation of olefins and substituted olefins is provided. In some aspects, the methods provided herein relate to the hydroformylation of allyl alcohol to 4-hydroxybutaldehyde in the presence of a rhodium catalyst which contains one or more N-heterocyclic carbene ligands of the formula: (I) wherein R 1 , R 2 , R 3 and R 4 are defined herein.
摘要翻译：提供了使用包含N-杂环卡宾配体的均匀铑催化剂用于烯烃和取代的烯烃的加氢甲酰基化的方法。在一些方面，本文提供的方法涉及在含有一种或多种下式的N-杂环卡宾配体的铑催化剂存在下将烯丙醇加氢甲酰化为4-羟基丁醛：其中R1，R2，R3和 R4在本文中定义。

3. 发明申请

WO2014070739A1 REMOVAL OF ALDEHYDES IN ACETIC ACID PRODUCTION 审中-公开
标题翻译：去除乙酸生产中的醛类
公开(公告)号：WO2014070739A1
公开(公告)日：2014-05-08
申请号：PCT/US2013/067266
申请日：2013-10-29
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P. , HALLINAN, Noel, C. , SALISBURY, Brian, A.
发明人： HALLINAN, Noel, C. , SALISBURY, Brian, A.
IPC分类号： C07C51/42 , C07C57/04 , B01J19/24
CPC分类号： C07C51/44 , C07C51/47 , C07C53/08
摘要： A system and method for removing acctaldchydc from an acetic acid system, including providing a solution from the acetic acid system, the stream having methyl iodide and acetaldehyde, and contacting the solution with an ion-exchange resin and/or liquid catalyst.
摘要翻译：一种用于从乙酸系统中去除acctaldchydc的系统和方法，包括提供来自乙酸系统的溶液，具有甲基碘和乙醛的流，并使该溶液与离子交换树脂和/或液体催化剂接触。

4. 发明申请

WO2014004307A1 PROCESS FOR THE PRODUCTION OF ACETIC ACID 审中-公开
标题翻译：生产乙酸的方法
公开(公告)号：WO2014004307A1
公开(公告)日：2014-01-03
申请号：PCT/US2013/047085
申请日：2013-06-21
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P. , HALLINAN, Noel, C. , SALISBURY, Brian, A. , BRTKO, Wayne, J. , FITZPATRICK, Michael, E.
发明人： HALLINAN, Noel, C. , SALISBURY, Brian, A. , BRTKO, Wayne, J. , FITZPATRICK, Michael, E.
IPC分类号： C07C51/573 , C07C53/08 , B01J23/46 , B01J19/24
CPC分类号： C07C51/50 , C07C51/12 , C07C53/08
摘要： A process for producing acetic acid includes: obtaining hydrogen iodide in an acetic acid production system; and continually introducing a complexing agent into the system, wherein the complexing agent and hydrogen iodide interact to form a complex.
摘要翻译：制备乙酸的方法包括：在乙酸生产系统中获得碘化氢; 并且将络合剂持续引入该体系中，其中络合剂和碘化氢相互作用形成络合物。

5. 发明申请

WO2008016502A3 PREPARATION OF ACETIC ACID 审中-公开
公开(公告)号：WO2008016502A3
公开(公告)日：2008-02-07
申请号：PCT/US2007/016563
申请日：2007-07-23
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P. , MILLENNIUM PETROCHEMICALS INC.
发明人： HARRIS, Stephen, H. , SALISBURY, Brian, A. , HANES, Ronnie, M.
IPC分类号： C07C51/12 , C07C51/44 , C07C51/487 , C07C53/08
摘要： A method for removing aldehyde impurities from an acetic acid stream is disclosed. The method comprises reacting an acetic acid stream containing aldehyde impurities with a hydroxyl compound to form corresponding acetals. The acetals are subsequently removed from the acetic acid by, e.g., distillation.

6. 发明申请

WO2014078310A1 PROCESS CONTROL WITH RAMAN SPECTROSCOPY 审中-公开
标题翻译：具有拉曼光谱的过程控制
公开(公告)号：WO2014078310A1
公开(公告)日：2014-05-22
申请号：PCT/US2013/069690
申请日：2013-11-12
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P. , WHITE, Daniel, F. , SALISBURY, Brian, A. , ORAN OSMENT, Jenny, M.
发明人： WHITE, Daniel, F. , SALISBURY, Brian, A. , ORAN OSMENT, Jenny, M.
IPC分类号： C07C29/94 , C07C31/20 , B01J19/24
CPC分类号： C07C29/16 , C07C29/141 , C07C29/172 , C07C29/44 , C07C29/48 , C07C31/207
摘要： Embodiments of the present disclosure include methods of effecting process control in a reaction system for the production of 1,4-butanediol, the method including determining at least one property of a sample from the reaction system using Raman spectroscopy, and adjusting at least one parameter of the reaction system in response to the at least one determined property. Embodiments may also include methods of producing 1,4-butanediol, the method including reacting allyl alcohol with carbon monoxide and hydrogen in the presence of a solvent and a catalyst to produce a reactor fluid, sampling the reaction, determining at least one property of the sample using Raman spectroscopy, and adjusting the reaction in response to the at least one determined property.
摘要翻译：本公开的实施方案包括在用于生产1,4-丁二醇的反应体系中进行过程控制的方法，所述方法包括使用拉曼光谱测定来自反应体系的样品的至少一种性质，以及调整至少一个参数的响应于所述至少一个确定的性质。实施方案还可以包括生产1,4-丁二醇的方法，所述方法包括在溶剂和催化剂存在下使烯丙醇与一氧化碳和氢反应以产生反应器流体，对反应进行取样，确定反应器的至少一种性质样品使用拉曼光谱，并且响应于至少一个确定的性质来调节反应。

7. 发明申请

WO2012148554A1 ACETIC ACID PRODUCTION PROCESS 审中-公开
标题翻译：醋酸生产工艺
公开(公告)号：WO2012148554A1
公开(公告)日：2012-11-01
申请号：PCT/US2012/026693
申请日：2012-02-27
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P. , SALISBURY, Brian, A. , HALLINAN, Noel, C.
发明人： SALISBURY, Brian, A. , HALLINAN, Noel, C.
IPC分类号： C07C51/12 , C07C53/08 , C07C51/44 , C07C51/48 , B01J19/00 , G01N21/65
CPC分类号： C07C51/12 , C07C51/44 , C07C51/48 , G01N21/65 , G01N2021/8416 , C07C53/08
摘要： A method for determining the characteristic of one or more components in a step of an acetic acid production process using Raman spectroscopy. The process includes providing a feed stream comprising multiple components to a separations unit, one of the components being acetic acid, the separations unit separating the feed stream into two or more exit streams having a different composition from one another, and measuring a characteristic of one or more of the components by Raman spectroscopic analysis.
摘要翻译：一种使用拉曼光谱法测定乙酸生产工艺步骤中一种或多种组分特征的方法。该方法包括向分离单元提供包含多个组分的进料流，其中一个组分是乙酸，分离单元将进料流分离成具有彼此不同组成的两个或更多个出口流，并测量一个或更多的组分通过拉曼光谱分析。

8. 发明申请

WO2011071652A1 VINYL ACETATE PRODUCTION PROCESS 审中-公开
标题翻译：醋酸乙烯酯生产工艺
公开(公告)号：WO2011071652A1
公开(公告)日：2011-06-16
申请号：PCT/US2010/056236
申请日：2010-11-10
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.
发明人： BRTKO, Wayne, J. , SALISBURY, Brian, A. , HALLINAN, Noel
IPC分类号： C07C67/055 , C07C69/15
CPC分类号： C07C67/055 , Y02P20/127 , C07C69/01 , C07C69/15
摘要： A process for the production of vinyl acetate is disclosed. The process comprises reacting ethylene, acetic acid, and oxygen in the presence of a catalyst to produce a reaction mixture comprising vinyl acetate, ethylene, carbon dioxide, acetic acid, water and ethylene glycol diacetate. The reaction mixture is separated to a gas stream comprising ethylene, and carbon dioxide and a crude vinyl acetate stream comprising vinyl acetate, acetic acid, water and ethylene glycol diacetate. An ethylene glycol diacetate stream is isolated from the crude vinyl acetate stream and subjected to a reactive distillation to recover acetic acid.
摘要翻译：公开了一种生产乙酸乙烯酯的方法。该方法包括在催化剂存在下使乙烯，乙酸和氧气反应以产生包含乙酸乙烯酯，乙烯，二氧化碳，乙酸，水和乙二醇二乙酸酯的反应混合物。将反应混合物分离成包含乙烯和二氧化碳的气流以及包含乙酸乙烯酯，乙酸，水和乙二醇二乙酸酯的粗乙酸乙烯酯料流。从粗乙酸乙烯酯流中分离乙二醇二乙酸物流，并进行反应蒸馏以回收乙酸。

9. 发明申请

WO2008153624A1 PREPARATION OF ACETIC ACID 审中-公开
标题翻译：醋酸的制备
公开(公告)号：WO2008153624A1
公开(公告)日：2008-12-18
申请号：PCT/US2008/005203
申请日：2008-04-23
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.
发明人： HALLINAN, Noel, C. , SALISBURY, Brian, A.
IPC分类号： C07C51/12 , C07C51/48 , C07C53/10
CPC分类号： C07C51/12 , C07C51/48 , C07C53/10
摘要： A method for removing aldehyde impurities from acetic acid is disclosed. The method comprises extracting the aldehyde impurities from a methyl iodide solution such as the decanter heavy phase with a polyol. After the aldehyde impurities are removed, the methyl iodide heavy phase can be recycled to the carbonylation.
摘要翻译：公开了一种从乙酸中除去醛杂质的方法。该方法包括用多元醇从甲基碘溶液例如倾析器重相萃取醛杂质。除去醛杂质后，可将甲基碘重相循环至羰基化。

10. 发明申请

WO2011043798A1 VINYL ACETATE PRODUCTION PROCESS 审中-公开
标题翻译：醋酸乙烯酯生产工艺
公开(公告)号：WO2011043798A1
公开(公告)日：2011-04-14
申请号：PCT/US2010/002666
申请日：2010-10-01
申请人： LYONDELL CHEMICAL TECHNOLOGY, L.P.
发明人： HALLINAN, Noel , BRTKO, Wayne, J. , SALISBURY, Brian, A.
IPC分类号： C07C67/055 , C07C69/15
CPC分类号： C07C67/055 , C07C69/01 , C07C69/15
摘要： A process for the production of vinyl acetate is disclosed. The process comprises reacting ethylene, acetic acid, and oxygen in the presence of a catalyst to produce a reaction mixture comprising vinyl acetate, ethylene, carbon dioxide, acetic acid and ethylene glycol diacetate. The reaction mixture is separated to a gas stream comprising ethylene, oxygen, and carbon dioxide and a crude vinyl acetate stream comprising vinyl acetate, acetic acid and ethylene glycol diacetate. An ethylene glycol diacetate stream, which comprises at least 50 wt% of ethylene glycol diacetate, is isolated from the crude vinyl acetate stream and hydrolyzed to recover acetic acid. Recovered acetic acid may be recycled to the acetoxidation reaction.
摘要翻译：公开了一种生产乙酸乙烯酯的方法。该方法包括在催化剂存在下使乙烯，乙酸和氧气反应，以产生包含乙酸乙烯酯，乙烯，二氧化碳，乙酸和乙二醇二乙酸酯的反应混合物。将反应混合物分离成包含乙烯，氧气和二氧化碳的气流和包含乙酸乙烯酯，乙酸和乙二醇二乙酸酯的粗乙酸乙烯酯流。包含至少50重量％的乙二醇二乙酸酯的乙二醇二乙酸酯流从粗乙酸乙烯酯流中分离并水解回收乙酸。回收的乙酸可以再循环到乙酰化反应中。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式