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    • 2. 发明申请
    • NON-HALOGEN FLAME RETARDANT POLYMERS
    • 非卤化物阻燃聚合物
    • WO2014193754A1
    • 2014-12-04
    • PCT/US2014/039353
    • 2014-05-23
    • LUBRIZOL ADVANCED MATERIALS, INC.
    • LAI, John Ta-YuanCHOU, Ti
    • C09K21/14C08F230/02
    • C08F30/02C07F9/091C08F230/02C08K5/34924C08L33/08C08L43/02C08L75/02C08L75/04C08L77/00C09D143/02C09K21/14C08F212/08C08F2220/1858C08F220/58
    • Non-halogenated monomers that can be polymerized into flame retardant polymers, and processes to produce the monomers and polymers is provided. In a simplest aspect, there is provided a monomer composition that can comprise a) a group derived from one of a (meth)acrylic acid, (meth)acrylamide, or vinylbenzene, b) a polyphosphate moiety, and c) an amine species. In the monomer composition, the ethylenically unsaturated monomer of (a) is covalently bonded directly or through a linking group to the moiety of b), forming a precursor monomer unit. The amine species of c) is in complex with the precursor monomer unit. The polymer can be a homopolymer of the monomer composition, or a copolymer of the monomer composition having varying a), b) and c). In one embodiment, the polymer can additionally comprise ethylenically unsaturated monomers not covalently bonded to a polyphosphate moiety and/or can be cross-linked with a cross-linking agent such as resorcinol.
    • 提供可以聚合成阻燃聚合物的非卤代单体,以及制备单体和聚合物的方法。 在最简单的方面,提供了一种单体组合物,其可以包含a)衍生自(甲基)丙烯酸,(甲基)丙烯酰胺或乙烯基苯之一的基团,b)聚磷酸酯部分,和c)胺类。 在单体组合物中,(a)的烯属不饱和单体直接或通过连接基团与b)的部分共价键合,形成前体单体单元。 c)的胺类与前体单体单元复合。 聚合物可以是单体组合物的均聚物,或具有变化a),b)和c)的单体组合物的共聚物。 在一个实施方案中,聚合物可以另外包含不共价键合到多磷酸酯部分的烯属不饱和单体和/或可以与交联剂如间苯二酚交联。