专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

2. 发明申请

WO1988002879A1 VISIBLE LIGHT CURABLE FREE RADICAL COMPOSITIONS CONTAINING 'pi'-ARENE METAL COMPLEXES 审中-公开
标题翻译：可见光可固化自由基组合物，含有金属复合物
公开(公告)号：WO1988002879A1
公开(公告)日：1988-04-21
申请号：PCT/US1987002619
申请日：1987-10-13
申请人： LOCTITE CORPORATION
发明人： LOCTITE CORPORATION , WOODS, John , ROONEY, John, M. , COAKLEY, Mary, P.
IPC分类号： G03C01/68
CPC分类号： C08G75/045 , C08F2/50 , G03F7/029
摘要： A visible light polymerisable composition comprises 1) free radically polymerisable material such as one or more monomers and/or prepolymers containing acrylate or methacrylate groups or a copolymerisable monomer combination based on a polythiol and a polyene. 2) a p-arene metal complex of formula (I), where a stands for 1 or 2 and n and q independently of each other each stand for an integer from 1 to 3, M is the cation of a monovalent to trivalent metal from groups IVb, VIIb, VIII or Ib of the periodic system, m is an integer corresponding to the valence of L + q, Q is a halogen and L is a metal or nonmetal with a valence of 2 to 7, R is a pi -arene and R is a pi -arene or the anion of a pi -arene. 3) a free radical rate accelerator such as a peroxide or hydroperoxide compound. More particularly, the pi -arene metal complex is a complex salt of a eta , eta iron arene cation and a non-nucleophilic anion, which is of formula (VII), where R is a eta arene selected from benzene, alkyl benzenes, alkyloxybenzenes, halobenzenes, haloalkylbenzenes, naphthalene, alkoxynaphthalenes, alkylnaphthalenes, halonaphthalenes, biphenyl, indene, pyrene or diphenylsulphide; R is the anion of a cyclopentadienyl compound, L is di- to heptavalent metal or metaloid, Z is a halogen and k is equal to 1 plus the valence of L.
摘要翻译：可见光可聚合组合物包含1）可自由基聚合的材料，例如含有丙烯酸酯或甲基丙烯酸酯基团的一种或多种单体和/或预聚物或基于多硫醇和多烯的可共聚单体组合。 2）式（I）的对芳族金属络合物，其中a代表1或2，n和q彼此独立地代表1至3的整数，M是一价至三价金属的阳离子第IVb，VIIb，VIII或Ib族，m是对应于L + q的化合价的整数，Q是卤素，L是金属或非金属，价数为2至7，R 1为一个芳基和一个R 2是一个仲芳基或一个芳香族的阴离子。 3）自由基速率促进剂如过氧化氢或过氧化氢化合物。更具体地，所述π-芳族金属络合物是η6，η5铁芳族阳离子和非亲核阴离子的复合盐，其具有式（VII），其中R 6是η 选自苯，烷基苯，烷氧基苯，卤代苯，卤代烷基苯，萘，烷氧基萘，烷基萘，卤萘，联苯，茚，芘或二苯硫醚的芳烃; R 7是环戊二烯基化合物的阴离子，L是二价至七价金属或金属络合物，Z是卤素，k等于1加上L的化合价。

IPRDB

热门服务

关于我们

友情链接

联系方式