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    • 3. 发明申请
    • ARYL-SUBSTITUTED POLY-P-ARYLENEVINYLENES
    • 芳基取代的聚丙烯酰亚胺
    • WO0162716A2
    • 2001-08-30
    • PCT/EP0101509
    • 2001-02-09
    • KONINKL PHILIPS ELECTRONICS NV
    • BERNTSEN ADRIANUS J MSCHOO HERMANNUS F MVAN TONGEREN HENRICUS F J J
    • H01L51/50C08G61/00C08G61/02C08G61/10C09K11/06H01L51/30H05B33/14C07C309/00
    • H05B33/14C08G61/00C08G61/02C08G61/10C09K11/06C09K2211/1425H01L51/0038H01L51/5012Y10S428/917
    • Aryl-substituted poly-p-arylenevinylenes comprising a repeating unit of formula (C1), in which one or more of the unsubstituted aromatic carbon atoms may be replaced by nitrogen atoms, -OCm and -OCn are alkoxy groups, m and n are integers from 2 to 6 with m + n = 8, p is 0, 1, 2 or 3 and in which R is CN, Cl, F, CF3, NO2, or SO3Z wherein Z is a monovalent cation such as Na , or in which R is -XR wherein the unit -X- represents a single bond, -O-, -S-, -CO-, -COO-, -OCO-, -SO-, -SO2-, -N(R )- or -N(R )CO-, and wherein R and R are the same or different and constitute a straight-chain branched or cyclic C1-C20 alkyl group or together an C1-C20 alkylene group, in which C1-C20 alkyl or C1-C20 alkylene group one or more hydrogens are optionally substituted by F or a C4-C12 aryl group and/or one or more non-adjacent -CH2- units are optionally substituted by C4-C12 arylene, -O-, -S-, -CO-, -COO-, -OCO-, -SO-, -SO2-, -N(R )- or -N(R )CO- where R is C1-C20 alkyl, or in which R is a C4-C12 aryl group which may or may not be substituted, polymers having viscosities at least equal to the viscosity of said aryl-substituted poly-p-arylenevinylenes and organic electroluminescent devices comprising such polymers.
    • 包含式(C1)重复单元的芳基取代的聚对亚芳基亚乙烯基,其中一个或多个未取代的芳族碳原子可以被氮原子代替,-OCm和-OCn是烷氧基,m和n是整数 2〜6,m + n = 8,p为0,1,2或3,其中R为CN,Cl,F,CF 3,NO 2或SO 3 Z,其中Z为单价阳离子,如Na + 或其中R是-XR 1,其中单元-X-表示单键,-O - , - S - , - CO-,-COO - , - OCO-, - SO - , - SO 2 - N(R 2) - 或-N(R 2)CO-,其中R 1和R 2相同或不同,构成直链支链或环状C 1 -C 20烷基 或一起为C1-C20亚烷基,其中C1-C20烷基或C1-C20亚烷基一个或多个氢任选被F或C 4 -C 12芳基取代,和/或一个或多个不相邻的-CH 2 - 单元 任选被C 4 -C 12亚芳基,-O - , - S - , - CO - , - COO-, - OCO - , - SO - , - SO 2 - , - N(R 3) - 或-N( R 3)CO-,其中R 3是C 1 -C 20烷基,或者是烷基 h R是可以或可以不被取代的C4-C12芳基,其粘度至少等于所述芳基取代的聚对亚芳基亚乙烯基的粘度和包含这种聚合物的有机电致发光器件的聚合物。