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    • 9. 发明申请
    • METHOD FOR FORMING POLYLACTIC ACID FIBERS
    • 形成聚酰亚胺纤维的方法
    • WO2009024837A1
    • 2009-02-26
    • PCT/IB2007/053353
    • 2007-08-22
    • KIMBERLY-CLARK WORLDWIDE, INC.HE, AiminWIDEMAN, Gregory, J.TOPOLKARAEV, Vasily, A.
    • HE, AiminWIDEMAN, Gregory, J.TOPOLKARAEV, Vasily, A.
    • D01F6/92
    • D01F6/92D01F1/10
    • A method of forming a polylactic acid fiber that involves the use of a macrocyclic ester oligomer to improve the crystallization properties of polylactic acid is provided. Without intending to be limited by theory, it is believed that the macrocyclic ester oligomer undergoes a ring-opening reaction during melt processing and thus converts to a low molecular weight linear crystal structure. These linear crystals may act as a nucleating "seed" for increasing the degree and rate of crystallization of polylactic acid, which improves its ability to be formed into fibers and webs. That is, polymers having a higher degree of melt and crystallization enthalpy are more readily able to bond at higher speeds and also have a lower degree of shrinkage, thereby improving web stability, tensile strength, and web aesthetics.
    • 提供了一种形成包含使用大环酯低聚物以改善聚乳酸的结晶性能的聚乳酸纤维的方法。 不期望受理论的限制,相信大环酯低聚物在熔融加工过程中经历开环反应,因此转化为低分子量线性晶体结构。 这些线性晶体可以作为成核“种子”,用于增加聚乳酸的结晶度和速率,这提高了其形成纤维和纤维网的能力。 也就是说,具有较高熔体和结晶焓的聚合物更容易能够以更高的速度粘合并且还具有较低的收缩率,从而提高幅材稳定性,拉伸强度和纤维网美观性。