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    • 8. 发明申请
    • MODIFIED POLYLACTIC ACID FIBERS
    • 改性聚酰胺纤维
    • WO2012020335A2
    • 2012-02-16
    • PCT/IB2011/053009
    • 2011-07-06
    • KIMBERLY-CLARK WORLDWIDE, INC.TOPOLKARAEV, Vasily, A.MCENEANY, Ryan, J.EBY, TomLARK, Tyler, J.
    • TOPOLKARAEV, Vasily, A.MCENEANY, Ryan, J.EBY, TomLARK, Tyler, J.
    • D01F6/92D01F6/62D01D5/08D01F1/10D04H1/42
    • D01F6/625B29C47/04B29K2063/00B29K2067/046B29K2105/0005B29K2995/006B29K2995/0088C08G63/08C08L67/04C08L2203/12D01D5/38D01F1/02D01F6/92D04H3/011D04H3/16Y10T428/298Y10T442/608Y10T442/615C08L23/0884
    • A method for forming biodegradable fibers is provided. The method includes blending polylactic acid with a polyepoxide modifier to form a thermoplastic composition, extruding the thermoplastic composition through a die, and thereafter passing the extruded composition through a die to form a fiber. Without intending to be limited by theory, it is believed that the polyepoxide modifier reacts with the polylactic acid and results in branching of its polymer backbone, thereby improving its melt strength and stability during fiber spinning without significantly reducing glass transition temperature. The reaction-induced branching can also increase molecular weight, which may lead to improved fiber ductility and the ability to better dissipate energy when subjected to an elongation force. To minimize premature reaction, the polylactic acid and polyepoxide modifier are first blended together at a relatively low temperature(s). Nevertheless, a relatively high shear rate may be employed during blending to induce chain scission of the polylactic acid backbone, thereby making more hydroxyl and/or carboxyl groups available for subsequent reaction with the polyepoxide modifier. Once blended, the temperature(s) employed during extrusion of the blended composition can be selected to both melt the composition and initiate a reaction of the polyepoxide modifier with hydroxyl and/or carboxyl groups of the polylactic acid. Through selective control over this method, the present inventors have discovered that the resulting fibers may exhibit good mechanical properties, both during and after melt spinning.
    • 提供了一种用于形成可生物降解的纤维的方法。 该方法包括将聚乳酸与聚环氧化物改性剂混合以形成热塑性组合物,通过模具挤出热塑性组合物,然后使挤出的组合物通过模头形成纤维。 不期望受理论限制,认为聚环氧化物改性剂与聚乳酸反应并导致其聚合物主链的支化,从而在纤维纺丝期间提高其熔体强度和稳定性,而不显着降低玻璃化转变温度。 反应诱导的分支也可以增加分子量,这可能导致改善的纤维延展性和当受到伸长力时更好地耗散能量的能力。 为了最小化过早反应,首先将聚乳酸和聚环氧化物改性剂在相对较低的温度下共混在一起。 然而,在共混期间可以采用相对高的剪切速率来诱导聚乳酸主链的断链,从而使得更多的羟基和/或羧基可用于随后与聚环氧化物改性剂的反应。 一旦共混,可以选择在共混组合物的挤出期间使用的温度以使组合物熔融并引发聚环氧化物改性剂与聚乳酸的羟基和/或羧基的反应。 通过对该方法的选择性控制,本发明人已经发现,在熔融纺丝过程中和之后,所得到的纤维可能表现出良好的机械性能。
    • 9. 发明申请
    • METHOD FOR FORMING POLYLACTIC ACID FIBERS
    • 形成聚酰亚胺纤维的方法
    • WO2009024837A1
    • 2009-02-26
    • PCT/IB2007/053353
    • 2007-08-22
    • KIMBERLY-CLARK WORLDWIDE, INC.HE, AiminWIDEMAN, Gregory, J.TOPOLKARAEV, Vasily, A.
    • HE, AiminWIDEMAN, Gregory, J.TOPOLKARAEV, Vasily, A.
    • D01F6/92
    • D01F6/92D01F1/10
    • A method of forming a polylactic acid fiber that involves the use of a macrocyclic ester oligomer to improve the crystallization properties of polylactic acid is provided. Without intending to be limited by theory, it is believed that the macrocyclic ester oligomer undergoes a ring-opening reaction during melt processing and thus converts to a low molecular weight linear crystal structure. These linear crystals may act as a nucleating "seed" for increasing the degree and rate of crystallization of polylactic acid, which improves its ability to be formed into fibers and webs. That is, polymers having a higher degree of melt and crystallization enthalpy are more readily able to bond at higher speeds and also have a lower degree of shrinkage, thereby improving web stability, tensile strength, and web aesthetics.
    • 提供了一种形成包含使用大环酯低聚物以改善聚乳酸的结晶性能的聚乳酸纤维的方法。 不期望受理论的限制,相信大环酯低聚物在熔融加工过程中经历开环反应,因此转化为低分子量线性晶体结构。 这些线性晶体可以作为成核“种子”,用于增加聚乳酸的结晶度和速率,这提高了其形成纤维和纤维网的能力。 也就是说,具有较高熔体和结晶焓的聚合物更容易能够以更高的速度粘合并且还具有较低的收缩率,从而提高幅材稳定性,拉伸强度和纤维网美观性。