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    • 1. 发明申请
    • CHEMICAL MECHANICAL PLANARIZATION OF LOW DIELECTRIC CONSTANT MATERIALS
    • 低介电常数材料的化学机械平面化
    • WO2003098680A1
    • 2003-11-27
    • PCT/US2003/015224
    • 2003-05-13
    • HONEYWELL INTERNATIONAL INC.ZHANG, FanTOWERY, DanielLIU, Feng Quan
    • ZHANG, FanTOWERY, DanielLIU, Feng Quan
    • H01L21/461
    • C09K3/1472C09G1/02C09K3/1436C09K3/1463H01L21/31053H01L21/31058
    • The present invention relates to apparatus, procedures, and compositions for avoiding and reducing damage to low dielectric constant materials and other soft materials, such as Cu and Al, used in fabricating semiconductor devices. Damage reduction can be achieved by decreasing the role of mechanical abrasion in the CMP of these materials and increasing the role of chemical polishing, which can improve material removal rates. Increasing the role of chemical polishing can be accomplished by creating a polishing slurry, (5) which contains components that interact chemically with the surface (1) to be polished. This slurry (5) may or may not also contain soft abrasive particles, which replace the hard abrasive particles of conventional slurries. Use of soft abrasive particles can reduce the role of mechanical abrasion in the CMP process. Use of this slurry (5) in CMP can reduce surface scratches and device damage.
    • 本发明涉及用于避免和减少用于制造半导体器件的低介电常数材料和其它软材料(例如Cu和Al)的损伤的装置,程序和组合物。 通过减少这些材料的CMP中的机械磨损的作用并增加化学抛光的作用可以减少损伤,这可以提高材料去除率。 增加化学抛光的作用可以通过产生抛光浆料(5)来实现,该抛光浆料包含与要抛光的表面(1)化学反应的成分。 该浆料(5)可以含有也可以不含有软磨料颗粒,其代替常规浆料的硬磨料颗粒。 使用软磨粒可以减少CMP工艺中机械磨损的作用。 在CMP中使用这种浆料(5)可以减少表面划痕和器件损坏。
    • 2. 发明申请
    • REACTIVE AQUEOUS METAL OXIDE SOLS AS POLISHING SLURRIES FOR LOW DIELECTRIC CONSTANT MATERIALS
    • 反应性水性金属氧化物溶液作为低介电常数材料的抛光液
    • WO2004015018A1
    • 2004-02-19
    • PCT/US2003/019727
    • 2003-06-19
    • HONEYWELL INTERNATIONAL INC.TOWERY, DanielFURY, Michael
    • TOWERY, DanielFURY, Michael
    • C09G1/02
    • C09K3/1463C09G1/02H01L21/31058
    • An aqueous metal oxide sol slurry has been developed for removal of low dielectric constant materials. The slurry is formed directly in solution utilizing non-dehydrated chemically active metal oxide sols which are formed in a colloidal suspension or dispersion. The oxide sols have not undergone any subsequent drying and the particles are believed to be substantially spherical in structure, dimensionally stable and do not change shape over time. The sol particles are mechanically soft and heavily hydrated which reduces surface damage even in the case where soft polymer or porous dielectric films are polished. The sol particles are formed of a chemically active metal oxide material, or combinations thereof, or can be coated on chemically inactive oxide material such as silicon dioxide or can be coformed therewith. The oxide sols can include a bi-modal particle distribution. The slurry can be utilized in CMP processes, with or without conditioning.
    • 已经开发了用于去除低介电常数材料的金属氧化物溶胶浆料水溶液。 使用以胶体悬浮液或分散体形成的非脱水化学活性金属氧化物溶胶,直接在溶液中形成浆液。 氧化物溶胶没有经历任何随后的干燥,并且所述颗粒被认为在结构上基本上是球形的,尺寸稳定的并且不随时间改变形状。 溶胶颗粒机械柔软并且水分高,即使在软质聚合物或多孔电介质膜被抛光的情况下也能降低表面损伤。 溶胶颗粒由化学活性金属氧化物材料或其组合形成,或者可以涂覆在化学惰性氧化物材料如二氧化硅上,或者可与其共形。 氧化物溶胶可以包括双模态粒子分布。 浆料可用于CMP工艺,有或没有调理。