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    • 3. 发明申请
    • SPIN-ON ANTI-REFLECTIVE COATINGS FOR PHOTOLITHOGRAPHY
    • 用于光刻胶的旋转抗反射涂层
    • WO2003044600A1
    • 2003-05-30
    • PCT/US2001/045306
    • 2001-11-15
    • HONEYWELL INTERNATIONAL INC.BALDWIN, TeresaKENNEDY, Joseph
    • BALDWIN, TeresaKENNEDY, Joseph
    • G03C1/492
    • G03F7/091C08G77/04C09D5/006C09D183/04Y10T428/31663
    • Anti-reflective coating materials for ultraviolet photolithography include at least one absorbing compounds and at least one pH tuning agent that are incorporated into spin-on materials. Suitable absorbing compounds are those that absorb around wavelengths such as 365 nm, 248 nm, 193 nm and 157 nm that may be used in photolithography. Suitable pH tuning agents not only adjust the pH of the final spin-on composition, but also influence the chemical performance and characteristics, mechanical performance and structural makeup of the final spin-on composition that is part of the layered material, electronic component or semiconductor component, such that the final spin-on composition is more compatible with the resist material that is coupled to it. More specifically, the pH tuning agent strong influences the polymeric characteristics, the structural makeup and the spatial orientation that results in increasing the surface properties of the anti-reflective coating for optimal resist performance. In other words, a pH tuning agent that merely adjusts the pH of the spin-on material without influencing the mechanical properties and structural makeup of the spin-on composition or the coupled resist material is not contemplated herein. A method of making absorbing and pH tuned spin-on materials includes combining at least one organic absorbing compound and at least one pH tuning agent with at least one silane reactant during synthesis of the spin-on materials and compositions.
    • 用于紫外光刻的抗反射涂层材料包括至少一种吸收化合物和至少一种掺入旋涂材料中的pH调节剂。 合适的吸收化合物是可以在光刻中使用的波长如365nm,248nm,193nm和157nm的那些吸收化合物。 合适的pH调节剂不仅调节最终旋涂组合物的pH,而且还影响作为层状材料,电子部件或半导体的一部分的最终旋涂组合物的化学性能和特性,机械性能和结构组成 使得最终的旋涂组合物与与其偶联的抗蚀剂材料更相容。 更具体地,pH调节剂强烈影响聚合物特性,结构组成和空间取向,导致抗反射涂层的表面性质增加,以获得最佳抗蚀剂性能。 换句话说,仅调节旋涂材料的pH而不影响旋涂组合物或偶联的抗蚀剂材料的机械性能和结构组成的pH调节剂在本文中未考虑。 制备吸收和pH调节旋涂材料的方法包括在合成旋涂材料和组合物期间将至少一种有机吸收化合物和至少一种pH调节剂与至少一种硅烷反应物组合。