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1. 发明申请

WO1996010598A1 NITROGENOUS POLYMERS USED AS ELECTROLUMINESCENT MATERIALS 审中-公开
标题翻译：含氮聚合物作为电
公开(公告)号：WO1996010598A1
公开(公告)日：1996-04-11
申请号：PCT/EP1995003836
申请日：1995-09-28
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , HÖRHOLD, Hans-Heinrich , ROST, Henning
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08G73/06
CPC分类号： H01L51/0038 , C07C43/215 , C07C43/285 , C07D495/22 , C08G61/00 , C08G73/0627 , C08G73/0633 , C08G73/0672 , C08G73/0694 , C09K11/00 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , C09K2211/1425 , C09K2211/1466 , H01L51/0035 , H05B33/14 , Y10S428/917
摘要： The invention concerns nitrogenous polymers containing structural units of formula (I), wherein the symbols and indices have the following meanings: Ar , Ar and Ar are identical or different and designate mono and/or polynuclear aryl and/or heteroaryl groups, or carbon atoms, which are optionally linked via one or a plurality of bridges and/or condensed, it further being possible for these groups to be optionally substituted; X is a single bond, -O-, -S-, -SO-, -SO2-, NR , -CR R -, -CO-, -CR =CR , CR R -CR R or SiR R ; R -R are identical or different and designate H, a hydrocarbon residue with 1 to 22 carbon atoms or Ar , where Ar is the same as or different from Ar and has the same meanings as Ar ; and n is 1, 2 or 3.
摘要翻译：本发明涉及含有式（I）其中各符号和指数具有以下含义的结构单元含氮聚合物：氩<1>中，Ar <2>中，Ar <3>是相同的或不同的单 - 和/或多核，任选通过一个或多个桥联的，和/或缩合芳基和/或杂芳基，碳原子，其可任选被取代; X是单键，-O - ， - S - ， - SO - ， - SO 2 - ，NR <3>，-CR <4> - [R <5> - ， - CO - ， - CR <6> = CR <7 >，CR <8> - [R <9>是-CR <10> - [R <11>或SIR <12> - [R <13>; [R <1> -R <13>为碳原子数1〜22的相同或不同，H，烃基，或Ar <4>，其中Ar <4>的Ar <1>具有相同或不同的具有相同含义的Ar <1> ; n是1，2或第三

2. 发明申请

WO1996010617A1 POLY(PARAPHENYLENE VINYLENE) DERIVATIVES AND THEIR USE AS ELECTROLUMINESCENT MATERIALS 审中-公开
标题翻译：聚对苯撑衍生物及其作为电
公开(公告)号：WO1996010617A1
公开(公告)日：1996-04-11
申请号：PCT/EP1995003835
申请日：1995-09-28
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , LUPO, Donald , SALBECK, Josef , SCHENK, Hermann , STEHLIN, Thomas , HÖRHOLD, Hans-Heinrich , LUX, Andrea , TEUSCHEL, Annett , WIEDUWILT, Martina
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C09K11/06
CPC分类号： H01L51/0038 , C07C43/215 , C07C43/285 , C07D495/22 , C08G61/00 , C08G73/0627 , C08G73/0633 , C08G73/0672 , C08G73/0694 , C09K11/00 , C09K11/06 , C09K2211/1408 , C09K2211/1416 , C09K2211/1425 , C09K2211/1466 , H01L51/0035 , H05B33/14 , Y10S428/917
摘要： The invention concerns the use, as electroluminescent materials, of polymers containing structural units of general formula (I) -[A -(A )C=CH-A -CH=C(A )]-, wherein A , A and A , which are identical or different, designate mono and/or polynuclear aryl and/or heteroaryl groups which are optionally linked via one or a plurality of bridges, and preferably via one bridge, and/or are condensed and can be optionally substituted, and wherein A and A each have two bonds and A has one bond. The polymers of formula (I) according to the invention are distinguished above all by their high degree of stability at high fluorescence quantum yields.
摘要翻译：含有通式（I）的结构单元的聚合物的用途 - [A <1> - （A <2>）C = CH-A <3> -CH = C（A <2>）] - ，其中A <1 >，一个<2>和<3>多核相同或不同的单 - 和/或，任选地通过一个或多个，优选相关联的桥和/或缩合芳基，其可任选地被取代和/或杂芳基，并且其中<1>和<3> 2和<2>每造成结合的，作为电致发光材料。式（I）的新聚合物特别高稳定性分辨以高荧光量子产率。

3. 发明申请

WO1997014739A1 CHOLESTERIC PHASE-FORMING POLYMERS, PROCESS FOR THEIR PREPARATION AND THEIR USE 审中-公开
标题翻译：胆甾相精细高分子，方法的生产和使用
公开(公告)号：WO1997014739A1
公开(公告)日：1997-04-24
申请号：PCT/EP1996004549
申请日：1996-10-18
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , SCHÖNFELD, Axel , CALUNDANN, Gordon
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08G63/60
CPC分类号： C09K19/3809 , C08G63/60 , C08G63/66 , C08L2205/12 , C09B67/0098 , C09D5/36 , C09K19/00 , Y10T428/10 , Y10T428/1041 , Y10T428/29 , Y10T428/2967 , Y10T428/2969 , Y10T428/31786
摘要： The invention concerns cholesteric phase-forming polymers, a process for their preparation and their use. Cholesteric phase-forming polymers and oligomers according to the invention substantially comprise as molecular units: A. at least one duofunctional chiral molecular unit comprising at least one cyclic structural element which is different from the monosubstituted p-phenylene group; B. at least one duofunctional achiral or racemic molecular unit which comprises at least one cyclic structural element containing at least four ring members; and C. at least one duofunctional molecular unit which can optionally be chiral or achiral and cyclic or acyclic and is different from the molecular units A and B actually used. The molecular units are connected by ester groups with (C=O)= and O-C=O, carbonic ester with O-(C=O)-O, amide groups CONH, N-substituted amide CONR, cyclic imide with six ring members, azomethines CH=N and CR=N. The groups R, which may be identical or different, can be C1-C22 alkyl, aryl, aralkyl and the non-cyclic portion can be linear or branched if the group is non-cyclic or if a combination with a non-cyclic group is present, and linear, branched and/or cyclic groups can optionally comprise at least one heteroatom which is different from C and H, and/or can optionally be substituted or even heteroatom-substituted. The substituent can in particular also carry one or a plurality of halogens, provided that the molecular unit A is not derived exclusively from camphoric acid. The polymers and oligomers according to the invention are obtained by replacing between 0.01 and 50 mol % of one or a plurality of the monomers corresponding to the molecular units B and/or C by monomers producing the chiral units A according to the invention in the prescription formula of any (nematic) liquid crystal polymer (LCP). The cholesteric phase-forming polymers and oligomers according to the invention are suitable as moulding compound granulates for further processing in known shaping processes, e.g. injection moulding. They can also be processed to form pigments for iridescent paints.
摘要翻译：公开的胆甾相形成性聚合物，它们的制备方法和它们的使用方法。本发明的胆甾相形成聚合物和低聚物具有基本上的分子结构单元：A.至少一种双官能的手性分子构建块，其具有至少一个从单取代的对亚苯基环状结构要素不同，B.至少一种双官能的非手性或外消旋的分子结构单元，其中至少一个环状具有含至少四个环成员，和C.至少一种双官能分子构建块，其可以是从实际使用的分子结构单元A和B，手性或非手性的，环状的或无环的任意的和不同的，其中通过酯基团的分子结构单元（C = O的结构元件）=和OC = O，含有O-（C = O）-O，酰胺基CONH，N-取代的酰胺CONR，含六个环成员的环状酰亚胺，偶氮甲碱CH = N和CR = N碳酸酯与所述余数R连接是等于是或不同的C1-C22烷基，芳基，芳可能，其中的无环基团的情况下，或在一个组合的存在的情况下，可以是直链或具有非环状基团的非环状部分，并且其中支链线性，支链和/或环状基团C和H的任选的至少一种可以含有各种杂原子和/或任选被取代的 - 和杂原子取代的 - 可以是，其中取代基可以，特别是还带有一个或多个卤素（S），条件是所述分子积木一个不仅从樟脑酸衍生的条件。该新型聚合物和低聚物可以通过使得到的，在一个任意的（向列型）的制剂LCP 0.01〜50摩尔％的一种或多种产生的与所述分子结构单元B和/或C由新颖的手性结构单元的单体A相应的单体更换。胆甾醇相形成的本发明的聚合物和低聚物是合适的，如公知的成型方法进行进一步的处理的模塑材料的颗粒，例如注塑成型。它们可以被加工成颜料虹彩颜料为好。

4. 发明申请

WO1996017035A1 HETEROSPIRO-COMPOUNDS AND THEIR USE AS ELECTROLUMINESCENT MATERIALS 审中-公开
标题翻译：异质螺环化合物及其作为电
公开(公告)号：WO1996017035A1
公开(公告)日：1996-06-06
申请号：PCT/EP1995004593
申请日：1995-11-22
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , LUPO, Donald , SALBECK, Josef , SCHENK, Hermann , STEHLIN, Thomas
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C09K11/06
CPC分类号： H05B33/14 , C07F7/081 , C07F7/0812 , C07F7/30 , C08G61/00 , C09K11/06 , H01L51/0052 , H01L51/0059 , H01L51/0069 , H01L51/007 , H01L51/0094 , H01L2251/308 , Y10S428/917
摘要： The invention concerns the use in electroluminescent devices of heterospiro-compounds of formula (I), in which PSI means an element of the fourth main group of the periodic system of elements, with the exception of carbon, and is preferably Sn, Ge or Si, particularly preferably Ge or Si, and K and K , independently of each other, mean conjugated systems. The compounds of formula (I) are distinguished by good solubility in common organic solvents, improved film-forming properties and a considerably reduced tendency towards crystallization.
摘要翻译：本发明涉及使用式（I），其中PSI是与碳除外，优选锡，锗或硅，特别优选的Ge或Si，和K <1>和K <周期系的第4主族的元素的杂螺环化合物的 2>独立地意味着共轭体系，在电致发光器件。式（I）的化合物是通过在普通有机溶剂中具有良好的溶解性，改善的成膜性能和结晶显著倾向减少表征。

5. 发明申请

WO1992009648A1 THERMOPLASTICALLY PROCESSABLE AROMATIC POLYETHER AMIDE 审中-公开
标题翻译：热塑性可加工芳香族聚酰胺酰胺
公开(公告)号：WO1992009648A1
公开(公告)日：1992-06-11
申请号：PCT/EP1991002112
申请日：1991-11-16
申请人： HOECHST AKTIENGESELLSCHAFT , CHERDRON, Harald , KREUDER, Willi , SCHNELLER, Arnold , HERRMANN-SCHÖNHERR, Otto
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08G69/32
CPC分类号： C08G69/32
摘要： Thermoplastically processable aromatic polyether amide of formula (I) in which the symbols Ar, Ar', Ar1, Ar2, R, R', Y, x, y and z have the meanings given below: Ar is a divalent substituted or unsubstitued aromatic or heteroaromatic radical or an -Ar* - Q - Ar* - group where Q is a bond or -O-, -C(CH3)2-, -CO- -S-, -SO- or -SO2 bridge and Ar* is an aromatic radical. The carbonyl groups of the Ar radical are in non-adjacent carbon atom rings. Ar is up to three different radicals. Ar' has the meaning given for Ar or is an Ar-Z-Ar group. Here Z is a -C(CH3)2- or -O-Ar*-O bridge. Y is a -C(CH3)2-, -SO2-, -S- or a -C(CF3)2- bridge and has up to two different meanings in the same polymer. Ar1 and Ar2 are the same or different and stand for a substituted or unsubstituted para or meta arylene radical. The sum of the mole fractions x, y and z is one. The sum of x and z may not be equal to y and x may assume the value zero. In a preferred embodiment z is greater than x.
摘要翻译：其中符号Ar，Ar'，Ar1，Ar2，R，R'，Y，x，y和z具有以下含义的式（I）的热塑性加工性芳族聚醚酰胺：Ar是二价取代或未取代的芳族或其中Q是键或-O - ， - C（CH 3）2 - ， - SO-S - ， - SO-或-SO 2桥，Ar *是杂芳族基团或-Ar * -Q- 芳香族基团。 Ar基团的羰基在不相邻的碳原子环中。 Ar最多有三个不同的激进分子。 Ar'具有给Ar的含义或Ar-Z-Ar组。这里Z是-C（CH 3）2 - 或-O-Ar * -O桥。 Y是-C（CH 3）2 - ，-SO 2 - ， - S-或-C（CF 3）2 - 桥，并且在同一聚合物中具有多达两个不同含义。 Ar1和Ar2相同或不同，代表取代或未取代的对或亚芳基。摩尔分数x，y和z之和为1。 x和z的和可以不等于y，x可以取值为零。在优选实施方案中，z大于x。

6. 发明申请

WO1997031048A1 PARTY CONJUGATED POLYMERS WITH SPIRO CENTRES AND THEIR USE AS ELECTRO-LUMINESCENT MATERIALS 审中-公开
标题翻译： WITH SPIRO中心与部分共轭聚合物及其作为电致发光
公开(公告)号：WO1997031048A1
公开(公告)日：1997-08-28
申请号：PCT/EP1997000551
申请日：1997-02-07
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , SPREITZER, Hubert
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08G61/00
CPC分类号： C09K11/06 , C08G61/02 , Y10S428/917
摘要： A partly conjugated polymer contains repetitive units of formula (I) in which A is the same or different with zero to eight identical or different arylene and/or heteroarylene and/or vinylene and/or acetylene groups which, like the spiro-bifluorene structure, may be substituted. Polymers with repetitive units of formula (I) are suitable, for example, as electroluminescent materials. They are distinguished by high emission colour uniformity, good film-forming properties and high solubility.
摘要翻译：包含式（I）其中各符号具有以下含义的重复单元的部分共轭聚合物：A是相同或不同的每一个从零到八个相同的或不同的亚芳基和/或亚杂芳基和/或1,2-亚乙烯基和/或乙炔基团，如螺二芴的框架也可以任选被取代。聚合物具有重复通式（I）的单元是，例如，作为电致发光材料。它们的特点是，除其他外，由发射，良好的成膜特性和高溶解度的高颜色单元。

7. 发明申请

WO1996029356A2 OLIGO-p-PHENYLENE-UNIT-CONTAINING POLYMERS, PROCESS FOR THEIR PRODUCTION AND THEIR USE 审中-公开
标题翻译： OLIGO对苯单位含氯聚合物，生产和使用方法
公开(公告)号：WO1996029356A2
公开(公告)日：1996-09-26
申请号：PCT/EP1996001066
申请日：1996-03-13
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , NEHER, Dieter , REMMERS, Marcus
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08G61/10
CPC分类号： C09K11/06 , C08G61/02
摘要： A novel oligo-p-phenylene-unit-containing polymer containing at least one structural element of the general formula (AkB)n in which the symbols and indices have the following meanings: A is the same as or different from (a), B is the same as or different from (b), Y is the same as or different from (E)-CR =CR , -CC- or -CHR -CHR ; R , R , R , R , R , R , R , R , R , R , R , R are mutually independently the same or different in the individual structural elements, H is a straight-chained or branched alkyl chain with 1 to 22 C atoms, in which one or more non-adjacent CH2 groups may also be substituted by -O-, -S-, -SO2-, -COOC-, -OOC- and/or phenylene, aryl or aryloxy groups, in which the aromatic in said groups may be substituted by C1-C22 alkyl, C1-C22 alkoxy, Br, Cl, F and/or CN, Br, Cl, F, CN or alkoxycarbonyl with 2 to 23 atoms, k is 1 to 25 and n is 1 to 200, is suitable for use as electroluminescent material.
摘要翻译：包含通式（AKB）n，其中符号和标记具有以下含义的至少一个结构元件的新的含低聚 - 对 - 亚苯基 - 聚合物：A是相同或不同的（a）中，B是相同或不同的（b）中， Y是相同或不同的（E）-CR <9> = CR <10> - ， - CC-或-CHR <11> CHR <12>; [R <1>，R <2>，R <3>，R <4>，R <5> - [R <6> - [R <7> - [R <8>，R <9>，R <10>， [R <11>，R <12>独立地在相同或不同的单独的结构元素，它们是H，具有1至22个C原子，其中一个或多个非相邻的CH 2基团可以被-O - 的直链或支链烷基链， - S - ， - SO 2 - ，-COOC-，-OOC-和/或亚苯基可被取代，芳基或芳基，其中所述芳族在这些基团与C1-C22烷基，C1-C22烷氧基，溴，氯，F CN可以被取代，溴，氯，F，CN或具有2至23个C原子的烷氧羰基;和/或 k为1至25; n为1至200，是适合于用作电致发光材料。

8. 发明申请

WO1996017036A1 CONJUGATED POLYMERS WITH HETERO-SPIROATOMS AND THE USE OF SUCH POLYMERS AS ELECTROLUMINESCENT MATERIALS 审中-公开
标题翻译：与杂原子螺环和共轭聚合物及其作为电
公开(公告)号：WO1996017036A1
公开(公告)日：1996-06-06
申请号：PCT/EP1995004594
申请日：1995-11-22
申请人： HOECHST AKTIENGESELLSCHAFT , KREUDER, Willi , LUPO, Donald , SALBECK, Josef , SCHENK, Hermann , STEHLIN, Thomas
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C09K11/06
CPC分类号： C09K11/06 , C08G61/00 , H01L51/0035 , H01L51/0036 , H01L51/0043 , H01L51/0052 , H01L51/0059 , H01L51/0062 , H01L51/007 , H01L51/0094
摘要： The proposed conjugated polymers contain repeating units of formula I, in which the symbols and indices have the following meanings: psi is a group IV element other than carbon; D, E, F and G are identical or different, for example -O- or a chemical bond; U represents (for example) a chemical bond; V can have the same meaning as U or can represent -O-; the groups A are identical or different, and are (for example) H or a C1-C20 hydrocarbon group; T represents (for example) -O- or -CA=CA-, A having the meaning indicated above; K, L, M and Q are identical or different and represent hydrocarbon groups which can contain heteroatoms and are characterized by conjugated electron systems; m and n are identical or different integers 0, 1, 2, 3 or 4. The proposed polymers can be used as electroluminescent materials.
摘要翻译：包括重复式（I）其中符号和指数具有以下含义的单元的共轭聚合物：PSI是与碳除外的周期系统的第4主族的元素; D，E，F，G是相同的或不同的，例如，-O-或化学键; U是，例如，一个化学键; V代表例如具有U的含义或为-O-; A是相同或不同的，例如，H或C1-C20烃基; T是例如-O-或-CA = CA-，其中A具有上文给出的含义; K，L，M，Q是可以含有杂原子和共轭有电子系统的相同或不同的烃基; m，n是相同的或不同的，并且是0，1，2，3或4; 适合作为电致发光。

9. 发明申请

WO1992014775A1 AROMATIC COPOLYAMIDES, PROCESS FOR PRODUCING THE SAME AND THEIR USE FOR PRODUCING SHAPED STRUCTURES 审中-公开
标题翻译：芳香族共聚酰胺，其生产方法及其生产形状结构的用途
公开(公告)号：WO1992014775A1
公开(公告)日：1992-09-03
申请号：PCT/EP1992000392
申请日：1992-02-25
申请人： HOECHST AKTIENGESELLSCHAFT , DELIUS, Ulrich, M. , KREUDER, Willi , WIESNER, Matthias
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08G69/32
CPC分类号： C08G69/32 , C08G69/265 , C08G69/28
摘要： An aromatic copolyamide that can be dissolved in an organic solvent is disclosed, as well as a process for producing it. The copolyamide has at least 90 mol % repetitive structural units (I), (II), (III), and 0 to 5 mol % terminal groups having the structural units (IV). The sum of the molar proportions of (II) and (III) lies in a ratio comprised between 0.9:1 and 1.1:1 to the molar proportion of (I). At the same time the mutual ratio between the molar proportions of (II) and (III) is comprised between 60:40 and 10:90. These copolyamides are suitable for producing shaped bodies or coatings, as well as for producing fibres, membranes and foils.
摘要翻译：公开了可以溶解在有机溶剂中的芳香族共聚酰胺，以及其制造方法。共聚酰胺具有至少90摩尔％的重复结构单元（I），（II），（III）和具有结构单元（IV）的0至5摩尔％的末端基团。（II）和（III）的摩尔比例之和与（I）的摩尔比例在0.9:1至1.1:1之间。同时，（II）和（III）的摩尔比例之间的相互比例在60:40和10:90之间。这些共聚酰胺适用于生产成型体或涂层，以及用于生产纤维，膜和箔。

10. 发明申请

WO1992013919A1 TERNARY POLYMER ALLOYS BASED ON POLYARYL ETHER KETONES WITH ONE GLASS TEMPERATURE 审中-公开
标题翻译：基于具有一个玻璃温度的聚醚醚酮的第三聚合物合金
公开(公告)号：WO1992013919A1
公开(公告)日：1992-08-20
申请号：PCT/EP1992000082
申请日：1992-01-17
申请人： HOECHST AKTIENGESELLSCHAFT , FALK, Uwe , HERRMANN-SCHÖNHERR, Otto , KREUDER, Willi
发明人： HOECHST AKTIENGESELLSCHAFT
IPC分类号： C08L71/10
CPC分类号： C08L79/08 , C08L65/00 , C08L71/00 , C08L2666/18 , C08L2666/14 , C08L2666/22
摘要： Ternary alloys are produced from uniformly mixed polymers (a), (b) and (c) containing as component (a) at least one polyaryl ether ketone, (b) at least one polyimide and (c) at least one polyaryl ester. The limiting viscosity number of (a) is 0.2 to 5.0 dl/g, of (b) 0.1 to 3.0 dl/g and of (c) 0.1 to 2.0 dl/g and the proportions of the components are (a) 45 to 98, (b) 1 to 45 and (c) 1 to 45 % wt. in relation to the total quantity of components (a), (b) and (c) in the alloy. The alloys are especially useful in the production of solid solutions.
摘要翻译：三元合金由含有至少一种聚芳醚酮，（b）至少一种聚酰亚胺和（c）至少一种聚芳酯的组分（a））的均匀混合聚合物（a），（b）和（c）（a）的特性粘度数为0.2〜5.0dl / g，（b）为0.1〜3.0dl / g，（c）为0.1〜2.0dl / g，成分比例为（a）45〜98 ，（b）1〜45和（c）1〜45重量％相对于合金中组分（a），（b）和（c）的总量。该合金在固溶体的生产中特别有用。

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