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1. 发明申请

WO1997023653A1 USE OF SILICON-CONTAINING TERPOLYMERS FOR RETANNING LEATHER 审中-公开
标题翻译：含硅三元复鞣对皮革使用
公开(公告)号：WO1997023653A1
公开(公告)日：1997-07-03
申请号：PCT/EP1996005554
申请日：1996-12-12
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , BEHR, Arno , RITTER, Wolfgang , PIETSCH, Oliver , SCHENKER, Gilbert , ZAUNS-HUBER, Rudolf , MAINX, Hans-Georg , WOLTER, Fredi , MÖCKEL, Rainer
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C03/22
CPC分类号： C08F230/08 , C14C3/08
摘要： The invention relates to silicon-containing terpolymers which contain as constitutive polymerized elements: (a) one or several olefinically unsaturated compounds having each one or several carboxyl groups and/or anydride groups; (b) one or several olefinically unsaturated esters of general formula (I) R - COOR , in which R is an alkyl group with 8 to 22 C atoms and R is an alkenyl group with 1 to 21 C atoms; and (c) one or several olefinically unsaturated compounds bearing each a substituent which contains a silicon atom. These terpolymers are used for retanning leather and for conferring low fogging properties to leather.
摘要翻译：描述了使用包含共聚形式作为分量含硅三元共聚物：a）一种或多种烯属不饱和化合物每一个都具有一个或多个羧基和/或酸酐; B）通式的一种或多种烯属不饱和酯（I）R <1> - COOR <2>，其中R <2>是具有8至22个碳原子的烷基基团R <1>是具有2至21℃的链烯基意味着-atoms; 和c）每一个具有含有硅原子的取代基的一种或多种烯属不饱和化合物; 对于复鞣革和皮革传授的低雾度特性。

2. 发明申请

WO1995033076A1 USE OF SULPHATED COMPOUNDS FOR STUFFING LEATHER 审中-公开
标题翻译： USE磺化物质用于皮革加脂
公开(公告)号：WO1995033076A1
公开(公告)日：1995-12-07
申请号：PCT/EP1995000508
申请日：1995-02-13
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , MAINX, Hans-Georg , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/02
CPC分类号： C14C9/02 , C07C303/06 , C07C303/32 , C07C309/62
摘要： Proposed are sulphated compounds obtained by reacting at least partially unsaturated hydrocarbons a) having 8 to 72 C-atoms with a sulphating reagent b) and subsequently neutralizing. Such sulphated compounds are suitable for use in the stuffing finish of leather. Used as the sulphating reagent b) is a combination of at least one organic sulphonic acid b1) and sulphuric acid b2), the proportion of sulphuric acid, relative to the sum of the organic sulphonic acid and the sulphuric acid, being 0.5 to 80 % by wt.
摘要翻译：由含有8至72个碳原子，并与磺化剂b。至少部分不饱和的烃的）的反应获得的物质的磺化），其中随后的中和在一起，适合用于皮革的注油。作为磺化剂b）的使用，至少一种有机磺酸b1）和硫酸b2）中，其中硫酸的含量的组合 - 是0.5〜80重量％ - 基于有机磺酸和硫酸的总和。

3. 发明申请

WO1995022631A1 USE OF SULFONATED SUBSTANCES FOR STUFFING LEATHER 审中-公开
标题翻译： USE磺化物质用于皮革加脂
公开(公告)号：WO1995022631A1
公开(公告)日：1995-08-24
申请号：PCT/EP1995000510
申请日：1995-02-13
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , MAINX, Hans-Georg , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/02
CPC分类号： C07C303/06 , C07C303/04 , C07C303/24 , C14C9/02 , C07C305/14 , C07C309/20
摘要： Sulfonated substances useful for stuffing leather are obtained by reacting monohydric or polyhydric alcohols (a) with 12 to 36 C atoms with a sulfonating reactive (b), then by neutralising them. As sulfonating reactive (b) a combination of at least one organic sulphonic acid (b1) and sulphuric acid (b2) is used, the proportion of sulphuric acid in relation to the sum of organic sulphonic acid and sulphuric acid amounting to 0.5 to 80% by weight.
摘要翻译：由含有12至36个碳原子，并与磺化剂b元或多元醇A）的反应而得到的磺化物质）中，用随后的中和在一起，适合用于皮革的注油。作为磺化剂b）的使用，至少一种有机磺酸b1）和硫酸b2）中，其中硫酸的含量的组合 - 是0.5〜80重量％ - 基于有机磺酸和硫酸的总和。

4. 发明申请

WO1995022632A1 USE OF SULPHITED SUBSTANCES FOR STUFFING LEATHER 审中-公开
标题翻译： USE磺化物质用于皮革加脂
公开(公告)号：WO1995022632A1
公开(公告)日：1995-08-24
申请号：PCT/EP1995000511
申请日：1995-02-13
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , MAINX, Hans-Georg , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/02
CPC分类号： C14C9/02
摘要： Sulphited substances useful for stuffing leather are obtained by reacting monobasic or polybasic carboxylic acids (a) with 12 to 72 C atoms with a sulphiting reactive (b), then by neutralisation. As sulphiting reactive (b) a combination of at least one organic sulphonic acid (b1) and sulphuric acid (b2) is used, the proportion of sulphuric acid in relation to the sum of organic sulphonic acid and sulphuric acid amounting to 0.5 to 80 % by weight.
摘要翻译：由含有12至72个碳原子，与磺化剂b的单 - 或多元羧酸的）反应获得磺化物质）中，用随后的中和在一起，适合用于皮革的注油。作为磺化剂b）的使用，至少一种有机磺酸b1）和硫酸b2）中，其中硫酸的含量的组合 - 是0.5〜80重量％ - 基于有机磺酸和硫酸的总和。

5. 发明申请

WO1995022630A1 USE OF SULPHITED SUBSTANCES FOR STUFFING LEATHER 审中-公开
标题翻译： USE磺化物质用于皮革加脂
公开(公告)号：WO1995022630A1
公开(公告)日：1995-08-24
申请号：PCT/EP1995000509
申请日：1995-02-13
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , MAINX, Hans-Georg , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/02
CPC分类号： C14C9/02 , C07C303/04 , C07C303/06 , C07C309/17
摘要： Sulphited substances useful for stuffing leather are obtained by reacting esters (a) of monohydric or polyhydric alcohols with 1 to 24 C atoms and dicarboxylic acids with 2 to 24 C atoms, the sum of C atoms in the alcohol and fatty acid components of the esters being equal to at least 16, with a sulphiting reactive (b), then by neutralisation. As sulphiting reactive (b) a combination of at least one organic sulphonic acid (b1) and sulphuric acid (b2) is used, the proportion of sulphuric acid in relation to the sum of organic sulphonic acid and sulphuric acid amounting to 0.5 to 80 % by weight.
摘要翻译：通过酯的反应获得的磺化物质a）具有碳原子数为1〜24的一元醇与碳原子数2〜24的二羧酸，其中，在所述酯的醇与脂肪酸组分的碳原子的总数至少为16，与磺化剂的 b）连同随后的中和，是适用于皮革的注油。作为磺化剂b）的使用，至少一种有机磺酸b1）和硫酸b2）中，其中硫酸的含量的组合 - 是0.5〜80重量％ - 基于有机磺酸和硫酸的总和。

6. 发明申请

WO1995022629A1 USE OF SULPHURED SUBSTANCES FOR STUFFING LEATHER 审中-公开
标题翻译： USE磺化物质用于皮革加脂
公开(公告)号：WO1995022629A1
公开(公告)日：1995-08-24
申请号：PCT/EP1995000507
申请日：1995-02-13
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , MAINX, Hans-Georg , SCHENKER, Gilbert , WOLTER, Fredi
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/02
CPC分类号： C14C9/02 , C07C303/06 , C07C303/32 , C07C309/17 , C07C309/62
摘要： Sulphured substances useful for stuffing leather are obtained by reacting esters (a) of monohydric or polyhydric alcohols with 1 to 24 C atoms and fatty acids with 1 to 30 C atoms, the sum of C atoms in the alcohol and fatty acid components of the esters being equal to at least 19, with a sulphuring reactive (b), then by neutralising them. As sulphuring reactive (b) a combination of at least one organic sulphonic acid (b1) and sulphuric acid (b2) is used, the proportion of sulphuric acid in relation to the sum of organic sulphonic acid and sulphuric acid amounting to 0.5 to 40 %by weight. The esters (a) used are preferably at least partially ethylenically unsaturated in relation to their alcohol and/or fatty acid components.
摘要翻译：通过酯的反应而得到的磺化物质（a）具有碳原子数为1〜24的单或多元醇与碳原子数为1〜30的脂肪酸，其中，在所述酯的醇与脂肪酸组分的碳原子的总数至少为19的与磺化剂（b）中，用随后的中和在一起，适合用于皮革的注油。作为磺化剂被使用（b）中，至少一种有机磺酸（b1）和硫酸（B2）的组合，其特征在于，硫酸的含量 - 基于有机磺酸和硫酸的总和， - 0.5至40wt％的（重量）。优选地，这种酯的）被用于其在关于其醇和/或脂肪酸组分的至少部分烯属不饱和。

7. 发明申请

WO1995025816A1 USE OF ALKYLENE DIAMINE TETRAPROPIONIC ACIDS FOR THE OILING OFF OF LEATHERS 审中-公开
标题翻译： ALKYLENDIAMINTETRAPROPIONSÄUREN对皮革的注油使用
公开(公告)号：WO1995025816A1
公开(公告)日：1995-09-28
申请号：PCT/EP1995000946
申请日：1995-03-14
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , WOLTER, Fredi , UPHUES, Günter , PRINZ, Wolfgang , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/00
CPC分类号： C07C229/16 , C14C9/00
摘要： Alkylene diamine tetrapropionic acids of the general formula (I) in which the radicals R to R are mutually independently hydrogen or a methyl group and the radicals M to M are mutually independently hydrogen,alkaline metal, alkaline earth metal, ammonium, alkyl ammonium or alkanol ammonium and x is a number from 12 to 36, and in which the alkylene group -(CH2)x- may be substituted by one or more alkyl, aryl or alkaryl groups, provided that the total number of C atoms in these substituents is 1 to 40, are suitable for the oiling off of leathers. The leathers thus treated are particularly distinguished by their good washing and cleaning, fogging and water resistance.
摘要翻译： Alkylendiamintetrapropionsäuren通式（I）其中R <4>至R <7>独立地是氢或甲基且基团中号<1>到M <4>独立地是氢，碱金属，碱土金属，铵，烷基铵或意味着链烷醇铵和x为12的数至36且在亚烷基 - 可以被取代，条件（CH 2）x任选地被一个或多个烷基，芳基或烷芳基取代的，这些取代基1个碳原子的总数目 40，适合用于皮革的注油。在此，与其皮革处理通过洗涤和清洁牢度，雾化牢度和耐水性良好的特征特别。

8. 发明申请

WO1996001330A1 USE OF OLIGOESTERS AND/OR POLYESTERS WITH TERMINAL CARBOXYL GROUPS IN THE OILING OFF OF LEATHER 审中-公开
标题翻译： USE羧基封端的低聚物和/或聚酯用于皮革的注油
公开(公告)号：WO1996001330A1
公开(公告)日：1996-01-18
申请号：PCT/EP1995002480
申请日：1995-06-26
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , EICKEN, Ulrich , SCHENKER, Gilbert , ZAUNS-HUBER, Rudolf
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/00
CPC分类号： C14C9/02 , C08G63/6884
摘要： The invention concerns oligoesters and/or polyesters with terminal carboxyl groups, characterized in that a) the acid component consists of a1) 10 to 90 % by wt. of dimeric or trimeric fatty acid, a2) 10 to 90 % by wt. of sulphosucinnic acid and a3) 0 to 80 % by wt. of dicarboxylic acids with 2 to 24 C-atoms and containing no sulphonic groups and b) the alcohol component consists of b1) 50 to 100 % by wt. of alkane diols with 2 to 18 C-atoms, b2) 0 to 50 % by wt. of polyalkylene glycols and b3) 0 to 50 % by wt. of dimeric diol and/or trimeric triol, the sulphonic-acid and carboxylic-acid groups being present in the ester as the free acid or as the alkali-metal, alkaline-earth, ammonium, alkylammonium or alkanolammonium salt. Such esters are suitable for the oiling off of leather. Particular properties of leather with such esters are that it is resistant to washing and cleaning, to fogging and to water. In addition, the esters used have "self-fixing" properties, thus making an additional mineral-salt fixing stage unnecessary.
摘要翻译：羧基封端的低聚物和/或聚酯，其特征在于：a）酸组分a1）中的存在量为10到二聚体和/或三聚脂肪酸的90％，A2）的存在量为10至90％的磺基琥珀酸和A3的）存在于的具有碳原子数2〜24磺自由基的二羧酸的0〜80％，和b）醇成分B1）50〜100碳原子数2〜18的链烷二醇的重量％，b2）的0至50 重量的聚亚烷基二醇的％和b3）中0到二聚二醇和/或三聚体的50％（重量），是其中酯存在于以游离形式或它们的碱金属，碱土金属，铵，烷基铵形式的磺酸基和羧基 - 或者可以是链烷醇适用于皮革的注油。与之皮革处理通过洗涤和清洁牢度，雾化牢度和耐水性良好的特征特别。另外，这些酯的“自固定”的属性可以是，使得不需要额外的矿物盐的固定。

9. 发明申请

WO1995019451A1 FATTY TREATMENT AGENT FOR LEATHER 审中-公开
标题翻译：用于皮革加油
公开(公告)号：WO1995019451A1
公开(公告)日：1995-07-20
申请号：PCT/EP1995000011
申请日：1995-01-03
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , WOLTER, Fredi , UPHUES, Günter , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/00
CPC分类号： C14C9/00
摘要： Aqueous dispersions containing special aminopropionic acid derivatives and co-oligomers based on fatty crotonates are suitable for the fatty treatment of leather. The leathers thus treated exhibit good washing and cleaning resistance and waterproofness.
摘要翻译：用的基于脂肪酸的巴豆酸酯特殊氨基丙和共低聚物含量的水性分散体适合用于皮革的注油。与之皮革处理是由良好的洗涤和清洁牢度和耐水性的表征。

10. 发明申请

WO1995025817A1 USE OF DIMERIC AND/OR TRIMERIC AMINOPROPIONIC ACIDS FOR OILING OFF OF LEATHERS 审中-公开
标题翻译：二聚体和/或TRIMERAMINPROPIONSÄUREN对皮革的注油使用
公开(公告)号：WO1995025817A1
公开(公告)日：1995-09-28
申请号：PCT/EP1995000945
申请日：1995-03-14
申请人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN , ZAUNS-HUBER, Rudolf , WOLTER, Fredi , UPHUES, Günter , PRINZ, Wolfgang , SCHENKER, Gilbert
发明人： HENKEL KOMMANDITGESELLSCHAFT AUF AKTIEN
IPC分类号： C14C09/02
CPC分类号： C14C9/02 , C07C229/16
摘要： Dimeric and/or trimeric aminopropionic acids obtainable by the conversion of at least one of the carboxyl groups in the corresponding dimeric or trimeric fatty acids into -CH2N[CH2-CH2-CO2H]2- and/or -CH2N[CH2-CH(CH3)-CO2H]2- groups. The compounds (I) are used in acid form or in the form of their alkaline metal, alkaline earth metal, ammonium, alkyl ammonium or alkanol ammonium salts. These aminopropionic acids are suitable for oiling off of leathers. The leathers thus treated are particularly distinguished by their good washing and cleaning, fogging and water resistance.
摘要翻译：二聚体和/或Trimeraminpropionsäuren通过转换存在于相应的二聚体或三聚体脂肪酸的羧基基团中的至少一个成获得-CH 2 N [CH 2 CH 2 CO 2 H] 2和/或-CH 2 N [CH 2 CH（CH 3）-CO 2 H] 2组，被使用，在酸性形式或它们的碱金属，碱土金属，铵，烷基铵或烷醇铵盐形式的化合物（I），是适用于皮革的注油。在此，与其皮革处理通过洗涤和清洁牢度，雾化牢度和耐水性良好的特征特别。

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