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    • 2. 发明申请
    • COMPOSITIONS COMPRISING A FIBER MATERIAL AND A THERMOPLASTIC BINDER
    • 包含纤维材料和热塑性粘合剂的组合物
    • WO2016050531A1
    • 2016-04-07
    • PCT/EP2015/071417
    • 2015-09-18
    • HENKEL AG & CO. KGAA
    • FERENCZ, AndreasLAMMERSCHOP, OlafSCHMIDT, TamaraSLARK, AndrewKASPER, Dirk
    • C08J5/04C08J5/24C08G18/42C08G18/76C08G18/40
    • C08J5/043C08G18/4018C08G18/4202C08G18/4211C08G18/4216C08G18/4829C08G18/664C08G18/6674C08G18/7671C08J5/04C08J5/24C08J2375/06C08J2375/08
    • The invention relates to compositions comprising a fiber material and a specific thermoplastic binder. The thermoplastic binder comprises at least one thermoplastic polyurethane polymer (A), wherein said thermoplastic polyurethane polymer (A) comprises a reaction product of (i) at least one polyester polyol and (ii) at least one polyisocyanate, optionally at least one diol (iii) which is different from the polyester polyol (i) is contained. The molar ratio of the NCO groups of said polyisocyanate (ii) to the sum of OH groups of said polyester polyol (i) and said optionally containing diol (iii) is less than 1.00:1. Said polyester polyol (i) comprises (a) at least one semi-crystalline polyester polyol having a melting point (T m ) of from 40 to 180 °C, and (b) at least one non-crystalline polyester polyol. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermosetting polyurethane polymer matrix reinforced by the composition according to the present invention. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
    • 本发明涉及包含纤维材料和特定热塑性粘合剂的组合物。 热塑性粘合剂包括至少一种热塑性聚氨酯聚合物(A),其中所述热塑性聚氨酯聚合物(A)包含(i)至少一种聚酯多元醇和(ii)至少一种多异氰酸酯,任选至少一种二醇( iii)与聚酯多元醇(i)不同。 所述多异氰酸酯(ii)的NCO基团与所述聚酯多元醇(i)和所述任选含有的二醇(iii)的OH基团之和的摩尔比小于1.00:1。 所述聚酯多元醇(i)包含(a)至少一种熔点(Tm)为40-180℃的半结晶聚酯多元醇,和(b)至少一种非结晶聚酯多元醇。 此外,本发明涉及一种纤维增强复合材料,其包含通过根据本发明的组合物增强的固化的热固性聚氨酯聚合物基体。 此外,本发明的纤维增强复合体的制造方法以及铁路车辆,机动车辆,飞机车辆,船舶,太空车辆,摩托车,自行车,运动用品中的组合物或纤维增强复合材料的使用 ,头盔,功能性服装,鞋子,桥梁和建筑物中的建筑部件或风力涡轮机叶片。
    • 6. 发明申请
    • THERMOPLASTIC PUR WITH HIGH TG FOR REACTION TRANSFER MOLDING (RTM)
    • 具有高TG的热塑性塑料用于反应转移成型(RTM)
    • WO2018050433A1
    • 2018-03-22
    • PCT/EP2017/071701
    • 2017-08-30
    • HENKEL AG & CO. KGAA
    • FERENCZ, AndreasSCHMIDT, TamaraNIEGEMEIER, AndreasLAMMERSCHOP, Olaf
    • C08G18/32C08G18/76C08J5/04
    • The invention relates to a thermoplastic polyurethane matrix resin composition, comprising (i) at least one bridged and/or fused and/or spiro polycyclic alcohol compound; (ii) at least one polyisocyanate; and (iii) at least one diol, which is different from the at least one bridged and/or fused and/or spiro polycyclic alcohol compound (i). The at least one bridged and/or fused and/or spiro polycyclic alcohol compound (i) is present in the thermoplastic polyurethane matrix resin composition in an amount of at least 10 wt.-% by weight, preferably at least 20 wt.-%, most preferably at least 25 wt.-%. Furthermore, the present invention relates to a fiber-reinforced composite comprising a cured thermoplastic polyurethane polymer matrix according to the present invention and a fiber material. Moreover, a method for the manufacture of the fiber-reinforced composite according to the present invention and use of the composition or the fiber-reinforced composite in railway vehicles, automotive vehicles, aircraft vehicles, boats, space vehicles, motorbikes, bicycles, sporting goods, e.g., skis, snowboards, rackets, golf clubs, fishing rods, baseball bats, hockey sticks, arrows, archery bows, surfboards, javelins, exercise equipment, cell phone and laptop housings, helmets, functional clothing, shoes, construction parts in bridges and buildings or wind turbine blades are described.
    • 本发明涉及一种热塑性聚氨酯基质树脂组合物,其包含(i)至少一种桥连和/或稠合的和/或螺多环醇化合物; (ii)至少一种多异氰酸酯; 和(iii)至少一种不同于所述至少一种桥连和/或稠合的和/或螺多环醇化合物(i)的二醇。 该至少一个桥联和/或稠合的和/或螺多醇化合物(i)存在于所述热塑性聚氨酯基质树脂组合物中按重量计的至少10重量%,优选至少20重量% ,最优选至少25重量%。 此外,本发明涉及包含根据本发明的固化热塑性聚氨酯聚合物基体和纤维材料的纤维增强复合材料。 此外,对于纤维增强复合材料的制造方法根据本发明和使用该组合物或在铁路车辆,汽车,飞机车辆,船只,空间飞行器,摩托车,自行车,体育用品的纤维增强复合材料的 例如,雪橇,滑雪板,球拍,高尔夫球杆,钓鱼竿,棒球棒,曲棍球棍,箭,弓箭,冲浪板,标枪,运动器材,手机和笔记本电脑外壳,安全帽,功能性服装,鞋,在桥梁结构件 描述建筑物或风力涡轮机叶片。