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    • 1. 发明申请
    • AQUEOUS NON-GELLING, ANIONIC POLYURETHANE DISPERSIONS AND PROCESSFOR THEIR MANUFACTURE
    • 水性非凝胶,阴离子聚氨酯分散体及其制造方法
    • WO1996040811A1
    • 1996-12-19
    • PCT/US1996009523
    • 1996-06-07
    • H.B. FULLER LICENSING & FINANCING, INC.
    • H.B. FULLER LICENSING & FINANCING, INC.DUAN, YouluSTAMMLER, SonjaRHEIN, ScottLINDQUIST, LowellMO, Lincoln
    • C08G18/08
    • C09J175/06C08G18/0819C08G18/12C08G18/6659C08G18/722C08G18/833C08G18/838C08G2170/80C08G18/72C08G18/302
    • Aqueous dispersion adhesives of anionic polyurethanes which have high heat resistance and low activation temperature, even when employed without addition of a cross-linker. The polyurethane is the reaction product of an isocyanate terminated polyurethane prepolymer, and water. The polyurethane prepolymer is the reaction product of a polyol component and a diisocyanate component, the polyolcomponent including: a sulfonated polyester polyol, a hydroxy carboxylic acid of the formula: (HO)xR (COOH)y wherein (R) represents a straight or branched, hydrocarbon radical containing 1 to 12 carbon atoms, and x and y represent values from 1 to 3, and optionally, a low molecular weight aliphatic diol having a molecular weight of from 60 to 400, a non-sulfonated polyol, and the diisocyanate component being selected from the group consisting of aromatic diisocyanates, isopherone diisocyanate, hexamethylene diisocyanate and mixtures thereof. The dispersions are prepared by mixing prepolymer and water at a temperature of at least 60 DEG C for sufficient time to fully react the isocyanate groups in a prepolymer self-extension reaction with water, typically at least 0.5 hour. The dispersions of the invention provide higher strength adhesive bonds than identical prepolymer dispersions extended with diamine chain extender, instead of water, after dispersion. The adhesive composition may also be modified to include a dispersed polymer or copolymer of an ethylenically unsaturated monomer. Such compositions may be obtained by preparing the sulfonated polyurethane in the presence of an ethylenically unsaturated monomer and subsequently subjecting the mixture to free-radical polymerization.
    • 具有高耐热性和低活化温度的阴离子聚氨酯的水性分散粘合剂,即使在不加入交联剂的情况下使用。 聚氨酯是异氰酸酯封端的聚氨酯预聚物和水的反应产物。 聚氨酯预聚物是多元醇组分和二异氰酸酯组分的反应产物,多元醇组分包括:磺化聚酯多元醇,下式的羟基羧酸:(HO)xR(COOH)y,其中(R)表示直链或支链 ,含有1至12个碳原子的烃基,x和y表示1至3的数值,任选地,分子量为60至400的低分子量脂族二醇,非磺化多元醇和二异氰酸酯组分 选自芳族二异氰酸酯,异角骨二异氰酸酯,六亚甲基二异氰酸酯及其混合物。 通过将预聚物和水在至少60℃的温度下混合足够的时间以将预聚物自身延伸反应中的异氰酸酯基团与水,通常至少0.5小时完全反应来制备分散体。 在分散后,本发明的分散体提供比用二胺扩链剂代替水延伸的相同的预聚物分散体更高的强度粘合剂粘合。 粘合剂组合物也可以被改性为包括分散的烯属不饱和单体的聚合物或共聚物。 可以通过在烯属不饱和单体的存在下制备磺化聚氨酯并随后使混合物进行自由基聚合来获得这种组合物。