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1. 发明申请

WO2010056432A2 PHOTOVOLTAIC DEVICE USING LOW IRON HIGH TRANSMISSION CLASS WITH ANTIMONY AND REDUCED ALKALI CONTENT AND CORRESPONDING METHOD 审中-公开
标题翻译：使用低铁高传输类的光电器件，具有抗反射和降低的碱性内容和相关方法
公开(公告)号：WO2010056432A2
公开(公告)日：2010-05-20
申请号：PCT/US2009059484
申请日：2009-10-05
申请人： GUARDIAN INDUSTRIES , FULTON KEVIN R , HULME RICHARD , THOMSEN SCOTT V
发明人： FULTON KEVIN R , HULME RICHARD , THOMSEN SCOTT V
IPC分类号： C03C3/087 , H01L31/048
CPC分类号： C03C3/087 , C03B13/08 , H01L31/0392 , H01L31/048 , H01L31/0488 , Y02E10/50
摘要： A high transmission low iron glass includes antimony, has reduced total alkali content, and increased silica content, and is suitable for use in photovoltaic devices (e.g., solar cells) or the like. A method of making the glass is also provided. In certain example embodiments, the glass composition may be made on a pattern line with a highly positive batch redox.
摘要翻译：高透射率低铁玻璃包括锑，具有降低的总碱含量和增加的二氧化硅含量，并且适用于光伏器件（例如太阳能电池）等。还提供了制造玻璃的方法。在某些示例性实施方案中，玻璃组合物可以在具有高度正批次氧化还原的图案线上制备。

2. 发明申请

WO2010114588A8 LOW IRON HIGH TRANSMISSION GLASS WITH BORON OXIDE FOR IMPROVED OPTICS, DURABILITY AND REFINING, AND CORRESPONDING METHOD 审中-公开
标题翻译：具有改善光学性，耐久性和精炼性的氧化硼的低铁高透射率玻璃和相应的方法
公开(公告)号：WO2010114588A8
公开(公告)日：2011-08-11
申请号：PCT/US2010000804
申请日：2010-03-18
申请人： GUARDIAN INDUSTRIES , PHOENICIA AMERICA ISRAEL FLAT GLASS LTD , FULTON KEVIN R , MICHAELIS ABRAHAM W , RESCH MARIO , BIRD DAVID , HULME RICHARD , THOMSEN SCOTT V
发明人： FULTON KEVIN R , MICHAELIS ABRAHAM W , RESCH MARIO , BIRD DAVID , HULME RICHARD , THOMSEN SCOTT V
IPC分类号： C03C3/089 , C03C3/091
CPC分类号： C03C3/091 , C03C1/00 , C03C3/087 , C03C4/0092
摘要： This invention relates to a high transmission low iron glass that includes boron oxide. The boron oxide, added to this low iron glass, has the effect of improving glass refining, homogeneity and quality (lower seed count) through its flux action and improves glass optical parameters of green and clear glass through the change in refractive index and surface tension. Boron oxide lends to broader and weaker absorption band of such transition element(s) as iron which additionally improves the transmittance of low iron clear glass in certain example embodiments of this invention. In certain example embodiments, the addition of boron oxide in certain quantities in advantageous in that it improves the chemical durability of the glass by decreasing the USPX (or USPXIII) value of the glass via suppression of the silica, sodium ions in the glass structure.
摘要翻译：本发明涉及包含氧化硼的高透光低铁玻璃。添加到该低铁玻璃中的氧化硼通过其助焊剂作用具有改善玻璃精炼，均匀性和质量（较低种子计数）的效果，并通过折射率和表面张力的变化改善绿色和透明玻璃的玻璃光学参数。硼氧化物适合于铁的这种过渡元素的更宽和更弱的吸收带，其在本发明的某些示例性实施方案中另外提高了低铁透明玻璃的透射率。在某些示例性实施方案中，加入一定量的氧化硼是有利的，因为通过玻璃结构中的二氧化硅钠离子的降低来降低玻璃的USPX（或USPXIII）值，从而提高了玻璃的化学耐久性。

3. 发明申请

WO2005082799A3 CLEAR GLASS COMPOSITION 审中-公开
标题翻译：清洁玻璃组合物
公开(公告)号：WO2005082799A3
公开(公告)日：2006-05-26
申请号：PCT/US2005002692
申请日：2005-01-28
申请人： GUARDIAN INDUSTRIES , LANDA LEONID , LANDA KSENIA A , THOMSEN SCOTT V , HULME RICHARD
发明人： LANDA LEONID , LANDA KSENIA A , THOMSEN SCOTT V , HULME RICHARD
IPC分类号： C03C3/095
CPC分类号： C03C3/095
摘要： Glass is provided so as to have high visible transmission and/or fairly clear or neutral color. In certain example embodiments, the glass may include a base glass (e.g., soda lime silica base glass) and, in addition, by weight percentage: total iron (expressed as Fe 2 0 3 ): 0.01 to 0.30 %, erbium oxide (e.g., Er 2 0 3 ): 0.01 to 0.30 %.
摘要翻译：提供玻璃以具有高可见透射和/或相当清晰或中性的颜色。在某些示例性实施方案中，玻璃可以包括基础玻璃（例如，钠钙二氧化硅基底玻璃），另外，按重量百分比计：总铁（表示为Fe 2 O 3， / 0.01）：0.01〜0.30％，0.01〜0.30％的氧化铒（例如，Er 2 O 3 3）。

4. 发明申请

WO2007106274A3 METHOD OF MAKING GLASS INCLUDING USE OF BORON OXIDE FOR REDUCING GLASS REFITING TIME 审中-公开
标题翻译：制造玻璃的方法，包括使用氧化硼以减少玻璃反射时间
公开(公告)号：WO2007106274A3
公开(公告)日：2008-05-15
申请号：PCT/US2007003753
申请日：2007-02-12
申请人： GUARDIAN INDUSTRIES , HULME RICHARD , THOMSEN SCOTT V , PLATT KARL P , LANDA LEONID M
发明人： HULME RICHARD , THOMSEN SCOTT V , PLATT KARL P , LANDA LEONID M , LANDA KSENIA A
IPC分类号： C03C3/078
CPC分类号： C03C1/004 , C03C3/091
摘要： This invention relates to a method of making soda-lime-silica based glass. In certain example embodiments, boron oxide (e.g., B 2 O 3 ) is used in the glass for reducing the refining time (or increasing the refining rate) thereof. The boron oxide may be introduced into the glass batch or melt in the form of boric acid, sodium tetraborate pentahydrate, sodium tetraborate decahydrate, sodium pentahydrate, or in any other suitable form. In certain example embodiments, the resulting soda-lime-silica based glass ends up including from about 0.1 to 3%, more preferably from about 0.1 to 2.5%, and most preferably from about 0.5 to 2.0% (e.g., about 1%), boron oxide. It has been found that the use of boron oxide, and/or the form in which the same is introduced into the glass, is advantageous in that it permits the refining time of the glass to be substantially reduced.
摘要翻译：本发明涉及一种制造钠钙二氧化硅基玻璃的方法。在某些示例性实施方案中，在玻璃中使用氧化硼（例如B 2 O 3 O 3）以减少精炼时间（或提高其提炼速度）。或者以硼酸，四硼酸钠五水合物，四硼酸钠十水合物，五水合钠或任何其它合适形式的形式将硼氧化物引入玻璃批料或熔融。在某些示例性实施方案中，所得到的钠钙二氧化硅基玻璃最终包括约0.1至3％，更优选约0.1至2.5％，最优选约0.5至2.0％（例如约1％），氧化硼。已经发现，使用氧化硼和/或将其引入玻璃中的形式是有利的，因为其允许玻璃的精炼时间显着降低。

5. 发明申请

WO2005009915A3 GREY GLASS COMPOSITION 审中-公开
标题翻译：灰色玻璃组合物
公开(公告)号：WO2005009915A3
公开(公告)日：2005-07-07
申请号：PCT/US2004023337
申请日：2004-07-21
申请人： GUARDIAN INDUSTRIES , THOMSEN SCOTT V , HULME RICHARD , LANDA LEONID , LANDA KSENIA A
发明人： THOMSEN SCOTT V , HULME RICHARD , LANDA LEONID , LANDA KSENIA A
IPC分类号： C03C3/095 , C03C4/02 , C03C4/08 , C03C3/087
CPC分类号： C03C4/02 , C03C3/095 , C03C4/082 , C03C4/085 , Y10S501/904 , Y10S501/905
摘要： A grey glass composition employing in its colorant portion at least iron (Fe2O3/FeO), cerium, cobalt and selenium is provided. The glass allows high visible transmission, and satisfactory IR and UV absorption, while at the same time achieving desired grey color. In certain example embodiments, the colorant portion includes, or may consist essentially of: total iron (expressed as Fe2O3): 0.25 to 0.70 % cerium oxide: 0.01 to 1.0 % selenium: 0.0001 to 0.05 % cobalt oxide: 0.0001 to 0.05 % titanium oxide: 0 to 1.0 % glass redox: >= 0.30.
摘要翻译：提供在其着色剂部分中至少使用铁（Fe 2 O 3 / FeO），铈，钴和硒的灰色玻璃组合物。玻璃允许高可见透射率，令人满意的红外和紫外线吸收，同时实现所需的灰色。在某些示例性实施方案中，着色剂部分包括或可以基本上由以下组成：总铁（以Fe 2 O 3表示）：0.25至0.70％氧化铈：0.01至1.0％硒：0.0001至0.05％氧化钴：0.0001至0.05％氧化钛：0〜1.0％玻璃氧化还原：> = 0.30。

6. 发明申请

WO2007021432A8 GREY GLASS COMPOSITION INCLUDING ERBIUM, NEODYMIUM AND/OR PRASEODYMIUM 审中-公开
标题翻译：灰色玻璃组成包括铒，钕和/或镨
公开(公告)号：WO2007021432A8
公开(公告)日：2007-10-25
申请号：PCT/US2006028057
申请日：2006-07-20
申请人： GUARDIAN INDUSTRIES , THOMSEN SCOTT V , LONGOBARDO ANTHONY V , LANDA LEONID M , LANDA KSENIA A
发明人： THOMSEN SCOTT V , LONGOBARDO ANTHONY V , LANDA LEONID M , LANDA KSENIA A
IPC分类号： C03C3/095 , C03C4/02
CPC分类号： C03C3/095 , C03C4/02
摘要： A grey glass composition is suitable for architectural and/or vehicle window Applications, The Grey glass may achieve a combination of good visible transmission, A low SHAG, and desirable coloration. In certain example embodiments, .tfie/grey glass includes iron, erbium (Er), neodymium (Nd) and/or praseodymium (PiJ)' in the colorant portion of the glass.
摘要翻译：灰色玻璃组合物适用于建筑和/或车窗应用。灰色玻璃可以实现良好的可见光透射，低SHAG和理想的着色的组合。在某些示例性实施例中，在玻璃的着色剂部分中，所述/灰色玻璃包括铁，铒（Er），钕（Nd）和/或镨（PiJ）'。

7. 发明申请

WO2006058020A2 COATED ARTICLE WITH COLOR SUPPRESSION COATING INCLUDING FLAME PYROLYSIS DEPOSITED LAYER(S) 审中-公开
标题翻译：具有颜色抑制涂层的涂层物品，包括火焰热解沉积层（S）
公开(公告)号：WO2006058020A2
公开(公告)日：2006-06-01
申请号：PCT/US2005042359
申请日：2005-11-21
申请人： GUARDIAN INDUSTRIES , THOMSEN SCOTT V
发明人： THOMSEN SCOTT V
IPC分类号： C23C4/00 , B32B15/00 , B32B17/06
CPC分类号： C03C17/3417 , C03C2218/15 , C03C2218/365 , C23C4/02 , C23C4/123 , C23C28/04
摘要： A coated article is provided with a color suppression coating on a substrate such as a glass substrate. Flame pyrolysis (or combustion CVD) is used in depositing at least part of a color suppression coating. For example, in an example embodiment of this invention, flame pyrolysis can be used to deposit a single SnO 2 layer from suitable Sn inclusive precursor(s), or alternatively a multi-layer coating may be formed at least partially using flame pyrolysis. In another example embodiment, the coating may include a base layer of silicon oxide foijiied using flame pyrolysis, and another layer of tin oxide formed in any suitable manner over the base layer of silicon oxide.
摘要翻译：涂布制品在诸如玻璃基板的基板上设置有抑色涂层。火焰热解（或燃烧CVD）用于沉积至少一部分抑色涂层。例如，在本发明的一个示例性实施例中，火焰热解可用于从合适的包含Sn的前体沉积单个SnO 2层，或者可以形成多层涂层最少部分地使用火焰热解。在另一个示例性实施例中，涂层可以包括使用火焰热解制备的氧化硅的基底层，以及以任何合适的方式在氧化硅的基底层上形成的另一层氧化锡层。

8. 发明申请

WO2006020641A3 COATED ARTICLE WITH LOW-E COATING INCLUDING TIN OXIDE INTERLAYER FOR HIGH BEND APPLICATIONS 审中-公开
标题翻译：带有低辐射涂层的涂层物品，包括用于高弯曲应用的氧化锡夹层
公开(公告)号：WO2006020641A3
公开(公告)日：2006-05-26
申请号：PCT/US2005028275
申请日：2005-08-09
申请人： CT LUXEMBOURGEOIS RECH VERRE , GUARDIAN INDUSTRIES , LEMMER JEAN-MARC , THOMSEN SCOTT V , MULLER JENS-PETER , LINGLE PHILIP J , FERREIRA JOSE
发明人： LEMMER JEAN-MARC , THOMSEN SCOTT V , MULLER JENS-PETER , LINGLE PHILIP J , FERREIRA JOSE
IPC分类号： B32B17/06 , C03C17/36
CPC分类号： C03C17/36 , B32B17/10036 , B32B17/10174 , B32B17/10761 , C03C17/3618 , C03C17/3626 , C03C17/3639 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C2217/78
摘要： A coated article is provided which may be heat treated (e.g., thermally tempered) and/or heat bent in certain example instances. In certain example embodiments, an interlayer of or including a metal oxide such as tin oxide is provided under an infrared (IR) reflecting layer so as to be located between respective layers of or including silicon nitride and zinc oxide. It has been found that the use of such a tin oxide inclusive interlayer results in significantly improved bendability of the coated article in applications such as vehicle windshields with deep bends. In certain example instances, an overcoat of a material such as zirconium oxide may also provided.
摘要翻译：提供了涂层制品，其可以在某些示例情况下进行热处理（例如，热回火）和/或热弯曲。在某些示例性实施例中，在红外（IR）反射层之下提供金属氧化物例如氧化锡的中间层或包括金属氧化物，以便位于氮化硅和氧化锌的相应层之间或包括氮化硅和氧化锌。已经发现，使用这种包含氧化锡的中间层导致涂覆制品在诸如具有深弯曲的车辆挡风玻璃的应用中显着改善的弯曲性。在某些示例情况下，还可以提供诸如氧化锆的材料的外涂层。

9. 发明申请

WO0238515A2 SOLAR MANAGEMENT COATING SYSTEM INCLUDING PROTECTIVE DLC 审中-公开
标题翻译：太阳能管理涂层系统，包括防护性DLC
公开(公告)号：WO0238515A2
公开(公告)日：2002-05-16
申请号：PCT/US0142793
申请日：2001-10-29
申请人： GUARDIAN INDUSTRIES , VEERASAMY VIJAYEN S , PETRMICHL RUDOLPH H , THOMSEN SCOTT V
发明人： VEERASAMY VIJAYEN S , PETRMICHL RUDOLPH H , THOMSEN SCOTT V
IPC分类号： B05D5/08 , B08B17/06 , B32B17/10 , B60S1/54 , B60S1/58 , C03C3/076 , C03C17/22 , C03C17/34 , C03C17/36 , C03C17/42 , C03C23/00 , C23C16/26 , G02B5/20
CPC分类号： C03C17/3618 , B05D5/083 , B08B17/06 , B08B17/065 , B32B17/1033 , B60S1/54 , B60S1/58 , C03C3/076 , C03C17/22 , C03C17/3441 , C03C17/3482 , C03C17/36 , C03C17/3621 , C03C17/3626 , C03C17/3634 , C03C17/3636 , C03C17/3644 , C03C17/3649 , C03C17/3652 , C03C17/3655 , C03C17/366 , C03C17/3681 , C03C17/42 , C03C23/0075 , C03C2217/282 , C03C2217/75 , C03C2217/76 , C03C2217/78 , C03C2218/151 , C03C2218/31 , C23C16/26 , G02B5/208 , Y10T428/30 , Y10T428/31504
摘要： A substrate is coated with a solar management coating system including at least one infrared (IR) reflective layer. A diamond-like carbon (DLC) inclusive protective coating system (e.g., including at least one highly tetrahedral amorphous carbon (ta-C) inclusive layer having sp carbon-carbon bonds) is provided on the substrate over at least the IR reflective layer in order to make the coating system scartch resistant, abrasion resistant, and generally mechanically durable. The DLC inclusive protective coating system may be hydrophobic, hydrophillic, or neutral in different embodiments of the invention. Optionally, at least one fluoro-alkyl silane (FAS) compound inclusive layer may be provided on the substrate over at least one of the DLC inclusive layer'(s) in hydrophobic embodiments in order to increase contact angle theta of the coated article.
摘要翻译：基材涂覆有包括至少一个红外（IR）反射层的太阳能管理涂层系统。包含类金刚石碳（DLC）的保护性涂层体系（例如，包括至少一个具有sp 3碳 - 碳键的高度四面体无定形碳（ta-C）包含层）至少在IR 为了使涂层体系抗擦伤，耐磨，并且通常机械耐用。在本发明的不同实施方式中，包含DLC的保护性涂层体系可以是疏水性的，亲水性的或中性的。任选地，可以在疏水性实施方案中在至少一个包含DLC的层（一个或多个）上在基材上提供至少一个氟代烷基硅烷（FAS）化合物包含层，以增加涂覆制品的接触角θ。

10. 发明申请

WO2010045041A2 METHOD OF MAKING FRONT ELECTRODE OF PHOTOVOLTAIC DEVICE HAVING ETCHED SURFACE AND CORRESPONDING PHOTOVOLTAIC DEVICE 审中-公开
标题翻译：具有蚀刻表面和相应光伏器件的光电器件的正面电极的制造方法
公开(公告)号：WO2010045041A2
公开(公告)日：2010-04-22
申请号：PCT/US2009059478
申请日：2009-10-05
申请人： GUARDIAN INDUSTRIES , KRASNOV ALEXEY , LU YIWEI , THOMSEN SCOTT V
发明人： KRASNOV ALEXEY , LU YIWEI , THOMSEN SCOTT V
IPC分类号： H01L31/18 , H01L31/0224 , H01L31/0236
CPC分类号： H01L31/1884 , H01L31/022466 , H01L31/0236 , Y02E10/50
摘要： Certain example embodiments of this invention relate to a photovoltaic (PV) device including an electrode such as a front electrode/contact, and a method of making the same. In certain example embodiments, the front electrode has a textured (e.g., etched) surface that faces the photovoltaic semiconductor film of the PV device. The front electrode has a transparent conductive oxide (TCO) film having first and second layers (continuous or discontinuous) of the same material (e.g., zinc oxide, zinc aluminum oxide, indium-tin-oxide, or tin oxide), where the first TCO layer is sputter-deposited using a ceramic sputtering target(s) and the second TCO layer of the same material is sputter-deposited using a metallic or substantially metallic sputtering target(s). This allows the better quality TCO of the film, deposited more slowly via the ceramic target(s), to be formed using the ceramic target and the lesser quality TCO of the film to be deposited more quickly and cost effectively via the metallic target(s). After the etching, most or all of the better quality ceramic-deposited TCO remains whereas much of the lesser quality metallic-deposited TCO of the film was removed during the etching process.
摘要翻译：本发明的某些示例性实施例涉及包括诸如前电极/触点的电极的光伏（PV）装置及其制造方法。在某些示例性实施例中，前电极具有面向PV器件的光电半导体膜的有纹理（例如蚀刻）的表面。前电极具有透明导电氧化物（TCO）膜，其具有相同材料（例如氧化锌，氧化锌铝，氧化铟锡或氧化锡）的第一和第二层（连续或不连续），其中第一使用陶瓷溅射靶溅射沉积TCO层，并且使用金属或基本上金属的溅射靶溅射沉积相同材料的第二TCO层。这允许通过使用陶瓷靶材形成的通过陶瓷靶材更缓慢地沉积的膜的更好的质量TCO，并且通过金属靶材更快速且成本有效地沉积的膜的质量较差的TCO（s ）。在蚀刻之后，大部分或全部较好质量的陶瓷沉积的TCO保留，而在蚀刻过程中除去较薄质量的金属沉积的TCO。

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