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1. 发明申请

WO2009062742A3 POROUS SOLID ACID CATALYSTS, METHODS OF MANUFACTURING THE SAME, AND METHODS OF MANUFACTURING ORGANICS MOLECULES USING THE SAME 审中-公开
标题翻译：多孔固体催化剂及其制造方法以及使用该方法制造有机分子的方法
公开(公告)号：WO2009062742A3
公开(公告)日：2009-08-06
申请号：PCT/EP2008009669
申请日：2008-11-14
申请人： GRACE GMBH & CO KG , UNIV BONN , BOHNEN FRANK MICHAEL , GANSAEUER ANDREAS
发明人： BOHNEN FRANK MICHAEL , GANSAEUER ANDREAS
IPC分类号： B01J29/06 , B01J29/08 , B01J29/40 , B01J29/70 , B01J35/10 , B01J37/10 , C07C41/03 , C07C45/61 , C07C209/60 , C07C213/04
CPC分类号： C07C227/08 , B01J29/06 , B01J29/084 , B01J29/40 , B01J29/7007 , B01J35/1061 , B01J35/109 , B01J37/10 , B01J2229/22 , B01J2229/36 , C07C41/03 , C07C67/29 , C07C213/04 , C07C253/30 , C07C2601/08 , C07C2601/14 , C07D209/12 , C07D243/38 , C07D309/12 , Y02P20/584 , C07C69/007 , C07C215/44 , C07C217/84 , C07C229/12 , C07C255/24 , C07C69/18 , C07C43/196
摘要： This invention relates to a process for synthesizing organic molecules utilizing a novel porous acid catalyst. The inventive processes are generally nucleophilic reactions employing a solid acid catalyst that has a pore size distribution having at least two different modes. The properties of the catalysts allow for relatively high product yields while at the same time provide the benefits of other solid catalysts, these benefits being manageable catalyst recycle and reduction and/or elimination of environmentally unfriendly solvents. The novel catalyst can be prepared by steam treating conventional crystalline zeolites under conditions sufficient to produce tailored pore size distributions having two or more modes of average of pore sizes, and optionally forming them into catalyst forms and/or particles. Accordingly, this invention also relates to the manufacture of the catalyst.
摘要翻译：本发明涉及利用新型多孔酸催化剂合成有机分子的方法。本发明的方法通常是使用具有至少两种不同模式的孔径分布的固体酸催化剂的亲核反应。催化剂的性质允许相对高的产物产率，同时提供其它固体催化剂的益处，这些优点是可管理的催化剂循环和还原和/或消除环境不友好的溶剂。新型催化剂可以通过在足以产生具有两种或更多种平均孔径模式的定制孔径分布的条件下蒸汽处理常规结晶沸石，并且任选地将它们形成催化剂形式和/或颗粒来制备。因此，本发明还涉及催化剂的制造。

2. 发明申请

WO2008059068A3 CARBONYL-SUBSTITUTED TITANOCENES 审中-公开
标题翻译：羰基取代茂钛
公开(公告)号：WO2008059068A3
公开(公告)日：2008-07-31
申请号：PCT/EP2007062511
申请日：2007-11-19
申请人： CHARITE UNIVERSITAETSMEDIZIN , UNIV BONN , PROKOP ARAM , SELIG ANJA , GANSAEUER ANDREAS , FRANKE DIETER
发明人： PROKOP ARAM , SELIG ANJA , GANSAEUER ANDREAS , FRANKE DIETER
IPC分类号： A61K31/28 , A61K31/7008 , A61P31/04 , A61P31/10 , A61P31/12 , A61P33/02 , A61P33/10 , A61P35/00 , A61P35/02 , C07F17/00
CPC分类号： A61K31/28 , A61K31/7008 , C07F17/00 , A61K2300/00
摘要： Disclosed is a medicament containing a compound of formula (Ia) or (Ib), wherein Z is selected from among a group comprising a covalent bond, at least one at least bivalent heteroatom, a saturated, unsaturated, branched, linear and/or cyclic, substituted or unsubstituted hydrocarbon chain, a saturated or unsaturated, branched, linear and/or cyclic, substituted or unsubstituted hydrocarbon chain containing heteroatoms, or combinations thereof, R `1 to R `4 and R ``1 to R ``5 each independently represents H, at least one heteroatom, a saturated, unsaturated, branched, linear and/or cyclic, substituted or unsubstituted hydrocarbon chain, a saturated or unsaturated, branched, linear and/or cyclic, substituted or unsubstituted hydrocarbon chain containing heteroatoms, or combinations thereof, the cyclopentadienyl rings are optionally linked by means of any of the radicals R ``1 to R ``5 , R 1 and R 2 independently represent H, a heteroatom, a saturated, unsaturated, branched, linear and/or cyclic, substituted or unsubstituted hydrocarbon chain, a saturated or unsaturated, branched, linear and/or cyclic, substituted or unsubstituted hydrocarbon chain containing heteroatoms, or combinations thereof, A`, A`` independently represent F, Cl, BR, I, and/or a physically acceptable acid radical of an organic or inorganic acid, n represents a positive integer, particularly 1, 2, 3, X = O, S, NH, NR 3 , NR 4 R 5 , wherein R 3 , R 4 , and R 5 independently have the meanings indicated for R` 1 to R` 4 , Y = a covalent bond, O, S, or NR 6 , wherein R 6 has the meaning indicated for R `1 to R `4 .
摘要翻译：含有其中Z选自共价键组成的组中的下式（Ia）或（Ib）的化合物的药物，至少一种至少二价的杂原子，饱和的，不饱和的，支链的，无支链和/或环状的，取代或未取代的烃链在链中或提供的一个具有杂原子的，饱和或不饱和的，支链的，无支链和/或环状的，取代或未取代的烃链，或它们的组合，R ^{`1 至R ^{`4 ，和 [R ^{``1 至R ^{``5 各自独立地为H，至少一个杂原子，饱和的，不饱和的，支链的，无支链和/或环状的，取代或未取代的烃链，设置有在链中杂原子，饱和或不饱和的，支链的，无支链和/或环状的，取代或未取代的平均烃链，或它们的组合，这两个环戊二烯基环`5 是任选的任何的R ^{``1 至R ^{`联，R ^{1 和 [R ^{2 各自独立地是H，杂原子，饱和的，不饱和的，支链的，无支链和/或环状的，取代或未取代的烃链，设置有在链中的杂原子的，饱和或不饱和的，支链的，无支链和意味着/或环状的，取代或未取代的烃链或它们的组合，A`，A``，F，氯，溴，I，和/或有机或无机酸的生理学可接受的酸残基是在每一情况下彼此独立地，n是一个正整数，尤其是1，2，3，X = O，S，NH，NR ^{3 ，NR ^{4 - [R ^{5 ，其中R < SUP> 3 ，R ^{4 和R ^{5 各自独立于R ^{1 至R ^{`4 ，Y =共价键，O，S，或NR ^{6 ，其中R ^{6 的 [R ^{`1 至R ^{`4 如上所定义。}}}}}}}}}}}}}}}}}}}

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