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    • 3. 发明申请
    • CORROSION PROTECTION OF STEEL IN CONCRETE
    • 混凝土中钢的腐蚀保护
    • WO2010146388A1
    • 2010-12-23
    • PCT/GB2010/050986
    • 2010-06-13
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • C23F13/06
    • C23F13/06
    • The use of an electric field modifier to boost the current output of a discrete sacrificial anode to enhance its protective effect and to direct the current output in a preferred direction to improve current distribution in the galvanic protection of steel in hardened reinforced concrete elements exposed to the air is disclosed. In one method a combination comprising a sacrificial anode (21) and an electric field modifier (25) and an ionically conductive filler (28) is embedded in a cavity formed in a concrete element and the sacrificial anode is directly connected to the steel (22). The modifier comprises an element with a side that is an anode (27) supporting an oxidation reaction in electronic contact with a side that is a cathode (26) supporting a reduction reaction. The cathode of the modifier faces the sacrificial anode and is separated from it by the filler (28). The filler contains an electrolyte that connects the sacrificial anode to the cathode of the modifier. The anode of the modifier faces away from the sacrificial anode. The reduction reaction on the cathode of the modifier may substantially comprise the reduction of oxygen from the air.
    • 使用电场调节器来增加离散的牺牲阳极的电流输出以增强其保护效果并且在优选的方向上引导电流输出以改善暴露于所述电场的硬化的钢筋混凝土元件中钢的电保护中的电流分布 空气被公开。 在一种方法中,包括牺牲阳极(21)和电场调节剂(25)和离子导电填料(28)的组合被嵌入形成在混凝土元件中的空腔中,牺牲阳极直接连接到钢(22 )。 改性剂包括具有侧面的元件,该元件是负载与负载还原反应的阴极(26)的一侧电子接触的氧化反应的阳极(27)。 改性剂的阴极面向牺牲阳极,并通过填料(28)与阴极分离。 填料含有将牺牲阳极连接到改性剂阴极的电解质。 改性剂的阳极背离牺牲阳极。 改性剂阴极上的还原反应基本上可以包括从空气中减少氧气。
    • 4. 发明申请
    • TREATMENT PROCESS FOR CONCRETE
    • 混凝土处理工艺
    • WO2006097770A2
    • 2006-09-21
    • PCT/GB2006/050054
    • 2006-03-14
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • C23F13/10
    • C23F13/02C23F13/16C23F2201/02C23F2213/21E04C5/015
    • A single anode system used in multiple electrochemical treatments to control steel corrosion in concrete comprises a sacrificial metal that is capable of supporting high impressed anode current densities with an impressed current anode connection detail and a porous embedding material containing an electrolyte. Initially current is driven from the sacrificial metal [1] to the steel [10] using a power source [5] converting oxygen and water [14] into hydroxyl ions [15] on the steel and drawing chloride ions [16] into the porous material [2] around the anode such that corroding sites are moved from the steel to the anode restoring steel passivity and activating the anode. Cathodic prevention is then applied. This is preferably sacrificial cathodic prevention that is applied by disconnecting the power source and connecting the activated sacrificial anode directly to the steel.
    • 用于多个电化学处理以控制混凝土中的钢腐蚀的单阳极系统包括牺牲金属,其能够利用外加电流阳极连接细节和含有电解质的多孔嵌入材料来支持高的外加的阳极电流密度。 最初,电流从牺牲金属[1]驱动到钢[10],使用电源[5]将氧和水[14]转化为羟基离子[15]并将氯离子[16]转化为多孔 材料[2],使得腐蚀部位从钢移动到阳极,恢复钢的钝性并激活阳极。 然后应用阴极预防。 这优选是通过断开电源并将激活的牺牲阳极直接连接到钢来施加的牺牲阴极防止。
    • 5. 发明申请
    • MONITORING METHOD
    • 监测方法
    • WO2007096668A1
    • 2007-08-30
    • PCT/GB2007/050072
    • 2007-02-19
    • GLASS, GarethDAVISON, NigelROBERTS, Adrian
    • GLASS, GarethDAVISON, NigelROBERTS, Adrian
    • G01N17/02
    • G01N17/02C23F13/04C23F13/22G01N33/383
    • A method of monitoring the protection delivered to steel bars (1) in concrete construction protected by a discrete sacrificial anode cathodic protection system comprising measuring potentials at potential measurement points located at close intervals in a representative area while the installed sacrificial anodes (2) are operating wherein the potential measurement points include at least three points (3) all located between but away from the same nearby installed anodes (2) and are all preferably located between the same pair of adjacent parallel steel bars. The results are used to identify the position of local anodes. The identification of anodes at locations where none are installed indicates that the steel may not be protected and the discrete sacrificial anode cathodic protection system is not operating effectively.
    • 一种监测交付给具有混凝土结构的钢筋(1)的保护装置的方法,其由离散的牺牲阳极阴极保护系统保护,该系统包括在安装的牺牲阳极(2)正在运行时在代表性区域中以紧密间隔位置的潜在测量点测量电位 其中所述潜在测量点包括至少三个点(3),所述至少三个点(3)全部位于相同的附近安装的阳极(2)之间但远离所述相邻的安装的阳极 结果用于识别局部阳极的位置。 在没有安装的位置识别阳极表明钢可能不受保护,并且分立的牺牲阳极阴极保护系统不能有效地运行。
    • 7. 发明申请
    • METHOD AND APPARATUS FOR REINFORCEMENT PROTECTION
    • 加固保护方法与装置
    • WO2015132587A1
    • 2015-09-11
    • PCT/GB2015/050623
    • 2015-03-04
    • E-CHEM TECHNOLOGIES LTDGLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • C23F13/06
    • C23F13/06C04B28/02C04B2111/265C23F2201/02C23F2213/22C04B22/04C04B22/06C04B40/0641
    • A method of using an activator in a compact discrete sacrificial anode assembly that is assembled within an anode cavity in concrete is described. The method includes providing a sacrificial anode, and an activator to activate the sacrificial anode, and a backfill to embed the sacrificial anode and the activator in an anode cavity in the concrete. The activator is provided as a discrete contained unit for dispersion through the backfill to surfaces of the sacrificial anode, and the unit at least in part separates the activator from any electrolyte in contact with the sacrificial anode. The activator is separated from the backfill prior to use. The advantages of this invention include limiting corrosion of the sacrificial metal element prior to use, containment of the health and safety risk presented by an activator, and providing a facility to control the quantity of activator installed in a sacrificial anode assembly. A surprising benefit results from a transient increase in the temperature of the assembly.
    • 描述了在混凝土中的阳极腔内组装的紧凑离散牺牲阳极组件中使用活化剂的方法。 该方法包括提供牺牲阳极和激活牺牲阳极的活化剂,以及将牺牲阳极和活化剂嵌入混凝土中的阳极腔中的回填。 提供活化剂作为离散包含的单元,用于通过回填到牺牲阳极的表面分散,并且该单元至少部分地将活化剂与与牺牲阳极接触的任何电解质分离。 使用前,活化剂与回填填料分离。 本发明的优点包括在使用之前限制牺牲金属元件的腐蚀,抑制由活化剂呈现的健康和安全风险,以及提供控制安装在牺牲阳极组件中的活化剂的量的设备。 由于组件的温度的瞬时增加,令人惊奇的好处是。
    • 9. 发明申请
    • DISCRETE SACRIFICIAL ANODE ASSEMBLY
    • 离散阳极阳极组件
    • WO2009112857A1
    • 2009-09-17
    • PCT/GB2009/050232
    • 2009-03-09
    • DAVISON, NigelGLASS, GarethROBERTS, Adrian
    • DAVISON, NigelGLASS, GarethROBERTS, Adrian
    • C23F13/06
    • C23F13/06C23F13/18C23F2201/02C23F2213/21
    • Sacrificial anode assemblies have the advantage that they can provide galvanic protection to steel in concrete and do not require long term maintenance of a DC power supply. However sacrificial anode assemblies attached to the concrete surface tend to lose adhesion to the concrete. The use of a discrete sacrificial anode (4) and a backfill (3) and a tape (5) and an adhesive to protect steel in concrete. The backfill is preferably placed in a shallow cavity in the concrete surface and the sacrificial anode is inserted into the backfill. The cavity is covered with a tape that extends over the adjacent concrete surfaces on opposite sides of the sacrificial anode and backfill and the tape is attached to the concrete surface with the adhesive. The tape and the adhesive holds the anode in place and prevents a weathering environment from damaging the backfill.
    • 牺牲阳极组件的优点在于它们可以为混凝土中的钢提供电流保护,并且不需要长期维护直流电源。 然而,连接到混凝土表面的牺牲阳极组件往往会失去对混凝土的粘附。 使用离散的牺牲阳极(4)和回填(3)和胶带(5)和粘合剂来保护混凝土中的钢。 回填物优选放置在混凝土表面的浅空腔中,并将牺牲阳极插入回填料。 空腔被覆盖着在牺牲阳极和回填物的相对侧上相邻的混凝土表面上延伸的带,并且带用粘合剂附接到混凝土表面。 胶带和粘合剂将阳极保持在适当位置,并防止风化环境损坏回填。
    • 10. 发明申请
    • SACRIFICIAL ANODES IN CONCRETE PATCH REPAIR
    • 混凝土修补修复中的阳光阳光
    • WO2010043908A1
    • 2010-04-22
    • PCT/GB2009/051386
    • 2009-10-16
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • GLASS, GarethROBERTS, AdrianDAVISON, Nigel
    • E04G23/02C23F13/02
    • C23F13/02C23F2201/02E04G23/02
    • High performance cementitious concretes or mortars and bonding agents developed for use as patch repair materials for corrosion damaged concrete often have high resistivities that inhibit the performance of sacrificial anodes located within patch repair areas. A method of repair is disclosed that comprises removing the corrosion damaged concrete to expose steel and form a cavity to receive high performance concrete repair materials and forming within the parent concrete exposed in this cavity a smaller distinct cavity for assembling a sacrificial anode assembly and placing within this anode cavity a pliable viscous ionically conductive backfill and a sacrificial anode and an activating agent to form a sacrificial anode assembly and connecting the anode to the steel and covering the anode assembly in the anode cavity with a repair material to restore the profile of the concrete structure. In this arrangement a high resistivity repair material promotes the flow of protection current to steel in adjacent contaminated concrete that is at risk of corrosion
    • 开发用作腐蚀损坏的混凝土的修补材料的高性能水泥混凝土或砂浆和粘结剂通常具有高电阻率,其抑制位于修补区域内的牺牲阳极的性能。 公开了一种修复方法,其包括去除腐蚀损坏的混凝土以暴露钢并形成空腔以接收高性能混凝土修复材料,并在暴露在该空腔内的母体混凝土内形成较小的不同的空腔,用于组装牺牲阳极组件并放置在 该阳极腔是柔性粘性离子导电回填和牺牲阳极和活化剂,以形成牺牲阳极组件,并将阳极连接到钢上,并用修复材料覆盖阳极腔中的阳极组件,以恢复混凝土的轮廓 结构体。 在这种布置中,高电阻率修复材料促进了在具有腐蚀危险的相邻污染混凝土中对钢的保护电流的流动