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1. 发明申请

WO2005019300A2 METHOD FOR PREPARING COPOLYESTERCARBONATES 审中-公开
标题翻译：制备共聚碳酸酯的方法
公开(公告)号：WO2005019300A2
公开(公告)日：2005-03-03
申请号：PCT/US2004/020892
申请日：2004-06-30
申请人： GENERAL ELECTRIC COMPANY , O'NEIL, Gregory, Allen , ACAR, Ali, Ersin , SYBERT, Paul, Dean , RANGARAJAN, Pratima (NMN) , ZHOU, Hongyi (NMN) , SURIANO, Joseph, Anthony
发明人： O'NEIL, Gregory, Allen , ACAR, Ali, Ersin , SYBERT, Paul, Dean , RANGARAJAN, Pratima (NMN) , ZHOU, Hongyi (NMN) , SURIANO, Joseph, Anthony
IPC分类号： C08G63/64
CPC分类号： C08G63/64
摘要： A method of preparing block copolyestercarbonates wherein at least one dihydroxysubstituted aromatic hydrocarbon moiety and at least one aromatic diacid chloride are reacted under interfacial conditions to give a hydroxy-terminated polyester intermediate. The dihydroxy-substituted aromatic compound is used in about 10 mole to about 125 mole percent excess relative to the diacid chloride. Enhanced control of hydroxy-terminated polyester intermediate molecular weight is achieved by limiting the amount of water present to provide a final salt level of greater than 30 percent. The final salt level is a theoretical value but is readily calculable. The hydroxyterminated polyester intermediate is then converted to a block copolyestercarbonate by reaction with a carbonate precursor such as phosgene.
摘要翻译：制备嵌段共聚酯碳酸酯的方法，其中在界面条件下使至少一种二羟基＆shy;取代的芳烃部分和至少一种芳族二酰氯反应，得到羟基封端的聚酯中间体。二羟基取代的芳族化合物以相对于二酰氯约10摩尔％至约125摩尔％的过量使用。通过限制存在的水量以提供大于30％的最终盐含量来实现对羟基封端的聚酯中间体分子量的增强控制。最终的盐水平是一个理论值，但很容易计算。然后通过与碳酸酯前体如光气反应将羟基封端的聚酯中间体转化为嵌段共聚酯碳酸酯。

2. 发明申请

WO2006012161A1 POLYARYLATE COMPOSITIONS 审中-公开
标题翻译：聚氨酯组合物
公开(公告)号：WO2006012161A1
公开(公告)日：2006-02-02
申请号：PCT/US2005/022138
申请日：2005-06-22
申请人： GENERAL ELECTRIC COMPANY , ACAR, Ali, Ersin , SYBERT, Paul, Dean , LI, Xianayang , BALAKRISHNAN, Karthik , O'NEIL, Gregory, Allen
发明人： ACAR, Ali, Ersin , SYBERT, Paul, Dean , LI, Xianayang , BALAKRISHNAN, Karthik , O'NEIL, Gregory, Allen
IPC分类号： C08L67/03
CPC分类号： C08L67/03 , C08L69/00 , C08L69/005 , C08L101/00 , Y10T428/31507 , C08L2666/02 , C08L2666/18
摘要： The present invention relates to a polymer composition comprising a transparent polymer blend. The polymer blend comprises a first resin and a second resin. The first resin comprises polyarylate structural units of formula (I), wherein R 1 is independently at each occurrence a C 1 -C 12 alkyl group, or a halogen atom, and p is 0 to 3. The second resin is selected from the group consisting of polycarbonates, polyarylates and copolyestercarbonates. The first resin and the second resin are further characterized by a difference in polyarylate structural unit conte
摘要翻译：本发明涉及包含透明聚合物共混物的聚合物组合物。聚合物共混物包括第一树脂和第二树脂。第一树脂包括式（I）的多芳基化合物结构单元，其中R 1在每次出现时独立地为C 1 -C 12烷基或卤素原子，p为0-3。第二树脂选自聚碳酸酯，聚芳酯和共聚酯碳酸酯。第一树脂和第二树脂的特征还在于聚芳酯结构单元的差异

3. 发明申请

WO2005118731A2 COATING COMPOSITIONS, THEIR PREPARATION, AND COATED ARTICLES MADE THEREFROM 审中-公开
标题翻译：涂料组合物，其制备和涂覆制品
公开(公告)号：WO2005118731A2
公开(公告)日：2005-12-15
申请号：PCT/US2004/025652
申请日：2004-08-06
申请人： GENERAL ELECTRIC COMPANY , MERFELD, Glen, David , KOENIGER, Rainer , ACAR, Ali, Ersin , SYBERT, Paul, Dean , SU, Zhaohui
发明人： MERFELD, Glen, David , KOENIGER, Rainer , ACAR, Ali, Ersin , SYBERT, Paul, Dean , SU, Zhaohui
IPC分类号： C09D167/00
CPC分类号： C08G63/78 , C08K5/09 , C08K5/10 , C08K5/1515 , C08K5/17 , C08K5/29 , C08L61/24 , C08L61/28 , C08L101/00 , C09D167/03 , Y10T428/31507 , Y10T428/31786 , Y10T428/31942 , C08L2666/16
摘要： A coating composition comprising components A, B and optionally C, wherein component A comprises at least one hydroxy-terminated polyarylate. Component B is an organic species which can react with the hydroxy terminal groups of component A, and component C is a catalyst or mixture of catalysts. The hydroxy-terminated polyarylates are prepared by a solution polymerization method.
摘要翻译：包含组分A，B和任选C的涂料组合物，其中组分A包含至少一种羟基封端的多芳基化合物。组分B是可以与组分A的羟基端基反应的有机物，组分C是催化剂或催化剂的混合物。羟基封端的聚芳酯通过溶液聚合法制备。

4. 发明申请

WO2007108867A1 THERMOPLASTIC COMPOSITION, METHOD OF MAKING, AND ARTICLES FORMED THEREFROM 审中-公开
标题翻译：热塑性组合物，制备方法和形成的制品
公开(公告)号：WO2007108867A1
公开(公告)日：2007-09-27
申请号：PCT/US2007/003317
申请日：2007-02-07
申请人： GENERAL ELECTRIC COMPANY , DI, Jianbo , MULLEN, Brian , SYBERT, Paul, Dean
发明人： DI, Jianbo , MULLEN, Brian , SYBERT, Paul, Dean
IPC分类号： C08G64/18
CPC分类号： C08G64/18 , C08F293/005 , C08L53/00 , C08L69/00 , Y10T428/31504 , Y10T428/31507 , C08L2666/14 , C08L2666/02 , C08L2666/18
摘要： A polyacrylate-polycarbonate copolymer comprises a polycarbonate block comprising aromatic carbonate units, and a polyacrylate block derived from a difunctional polyacrylate polymer having the formula: Z 1 -(M) x -Z 2 , wherein M is an acrylate block unit comprising a reaction residue of a (meth)acrylate monomer, a non-(meth)acrylate monomer, or a. combination comprising a (meth)acrylate and a non-(meth)acrylate monomer, at least one acrylate block unit is a (meth)acrylate monomer; x is greater than one; and Z 1 and Z 2 are each independently functionalized terminal groups of the formula: -(A 3 ) y -B, wherein B is a reactive group comprising a hydroxy or non-hydroxy group, A 3 an aliphatic group, an aromatic group, or an aliphatic-aromatic group, y is 0 or 1, A 3 is free of hydrogen atoms beta to B when B is a hydroxy group, and B and A 3 are each free of sulfur atoms. A method of making, a thermoplastic composition, and articles are also disclosed.
摘要翻译：聚丙烯酸酯 - 聚碳酸酯共聚物包括含有芳族碳酸酯单元的聚碳酸酯嵌段和衍生自具有下式的双官能聚丙烯酸酯聚合物的聚丙烯酸酯嵌段：（Z） - （M） Z 2，其中M是包含（甲基）丙烯酸酯单体，非（甲基）丙烯酸酯单体，或（甲基）丙烯酸酯单体的反应残基的丙烯酸酯嵌段单元。包含（甲基）丙烯酸酯和非（甲基）丙烯酸酯单体的组合物，至少一种丙烯酸酯嵌段单元是（甲基）丙烯酸酯单体; x大于1; 和Z 1和Z 2各自独立地是下式的官能化的末端基团： - （A 3 S 3） -B，其中B是包含羟基或非羟基的反应性基团，脂族基团，芳族基团或脂族 - 芳族基团，y为0或1，A < 当B是羟基时，SUP 3不含有B的氢原子，B和A 3都不含硫原子。还公开了制备方法，热塑性组合物和制品。

5. 发明申请

WO2018049365A1 SACRIFICIAL HIGH HEAT SUPPORT MATERIALS FOR ADDITIVE MANUFACTURING PROCESSES 审中-公开
标题翻译：用于添加剂制造过程的牺牲性高热载体材料
公开(公告)号：WO2018049365A1
公开(公告)日：2018-03-15
申请号：PCT/US2017/051068
申请日：2017-09-12
申请人： SABIC GLOBAL TECHNOLOGIES B.V. , SYBERT, Paul, Dean
发明人： SYBERT, Paul, Dean , BIHARI, Malvika , GALLUCCI, Robert, Russell , COX, Keith, E.
IPC分类号： B29C64/118 , B29C64/40 , B33Y10/00 , B33Y70/00
摘要： Disclosed herein are methods that includes using a water-degradable (e.g., autoclavable) support material together with a high-heat build material (e.g., polyetherimide or PEI). When the support material is autoclaved for a period of time, the support material becomes brittle and then disintegrates into powder and therefore can be removed from the model or build material, leaving behind a part formed from the model material that includes features (e.g., cavities, channels, etc.) formerly occupied by the support material.
摘要翻译：本文公开的方法包括使用可水降解（例如可高压灭菌）的载体材料以及高生热材料（例如聚醚酰亚胺或PEI）。当支撑材料高压灭菌一段时间时，支撑材料变脆，然后分解成粉末，因此可以从模型或构建材料中移除，留下由模型材料形成的部件，其包括特征（例如腔，通道等）以前由支撑材料占据。

6. 发明申请

WO2013130809A1 THERMOPLASTIC COMPOSITIONS HAVING LOW SMOKE, METHODS OF THEIR MANUFACTURE, AND USES THEREOF 审中-公开
标题翻译：具有低烟雾的热塑性组合物，其制造方法及其用途
公开(公告)号：WO2013130809A1
公开(公告)日：2013-09-06
申请号：PCT/US2013/028325
申请日：2013-02-28
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul, Dean
发明人： SYBERT, Paul, Dean , VAN DER MEE, Mark, Adrianus Johannes , VAN DER GRAMPEL, Robert, Dirk , ASSINK, Roland, Sebastian
IPC分类号： C08L67/00 , C08L69/00 , C08L79/08
CPC分类号： C08L69/005 , B32B5/00 , B32B27/365 , C08G73/1046 , C08G77/448 , C08K5/49 , C08L69/00 , C08L79/04 , C08L79/08 , C08L83/10 , C08L2201/02 , C09K21/14
摘要： A low smoke density thermoplastic composition comprising, based on the total weight of the thermoplastic composition, 70 to 95 wt% of a polycarbonate copolymer comprising first repeating units and second repeating units, wherein the first repeating units are not the same as the second repeating units, and wherein the first repeating units are bisphenol carbonate units of the formula and the second repeating units comprise bisphenol carbonate units that are not the same as the first repeating bisphenol carbonate units, siloxane units, arylate ester units, or a combination of arylate ester units and siloxane units; and 5 to 30 wt% of a polyetherimide based on the weight of the composition, wherein an article molded from the composition has a smoke density (Ds-4) value of equal to or less than 300 as measured by ISO 5659-2 on a 3 mm thick plaque.
摘要翻译：一种低烟密度热塑性组合物，其包含基于所述热塑性组合物的总重量为70至95重量％的包含第一重复单元和第二重复单元的聚碳酸酯共聚物，其中所述第一重复单元与所述第二重复单元不相同并且其中第一重复单元是下式的双酚碳酸酯单元，第二重复单元包括与第一重复双酚碳酸酯单元，硅氧烷单元，芳基酯单元或芳基酯单元的组合不同的双酚碳酸酯单元和硅氧烷单元; 和5至30重量％的基于组合物重量的聚醚酰亚胺，其中由组合物模制的制品的烟浓度（Ds-4）值等于或小于300，如通过ISO 5659-2测量的 3毫米厚的斑块。

7. 发明申请

WO2014100745A1 PROCESSES FOR ENHANCING FLAME RETARDANCE AND CHEMICAL RESISTANCE OF POLYMERS 审中-公开
标题翻译：提高聚合物阻燃性和耐化学性的方法
公开(公告)号：WO2014100745A1
公开(公告)日：2014-06-26
申请号：PCT/US2013/077272
申请日：2013-12-20
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul, Dean
发明人： SYBERT, Paul, Dean , FLORES, Amanda , JOHNSON, Peter
IPC分类号： C08G64/14 , C08G64/24 , C08L69/00
CPC分类号： C08G64/14 , C08K5/42 , C08L69/00
摘要： Processes for increasing the chemical resistance of a surface of a formed article are disclosed. The formed article is produced from a polymeric composition comprising a photoactive additive containing photoactive groups derived from a monofunctional benzophenone. The surface of the formed article is then exposed to ultraviolet light to cause crosslinking of the photoactive additive and produce a crosslinked surface. The crosslinking enhances the chemical resistance of the surface. Various means for controlling the depth of the crosslinking are also discussed.
摘要翻译：公开了用于提高成型体的表面的耐化学性的方法。成型制品由包含含有衍生自单官能二苯甲酮的光活性基团的光活性添加剂的聚合物组合物制备。然后将成形制品的表面暴露于紫外线以引起光活性添加剂的交联并产生交联表面。交联增强了表面的耐化学性。还讨论了用于控制交联深度的各种手段。

8. 发明申请

WO2014100341A1 POLYCARBONATE COMPOSITIONS, ARTICLES FORMED THEREFROM, AND METHODS OF MANUFACTURE THEREOF 审中-公开
标题翻译：聚碳酸酯组合物，其形成的制品及其制造方法
公开(公告)号：WO2014100341A1
公开(公告)日：2014-06-26
申请号：PCT/US2013/076408
申请日：2013-12-19
申请人： SABIC INNOVATIVE PLASTICS IP B.V. , SYBERT, Paul, Dean
发明人： SYBERT, Paul, Dean , VAN DER MEE, Mark Adrianus Johannes , ASSINK, Roland Sebastian , VAN DE GRAMPEL, Robert Dirk , LAVERGNE, Guillaume Philippe Colette
IPC分类号： C08L69/00
CPC分类号： C08L69/005 , C08G73/1053 , C08G73/1071 , C08G77/04 , C08G77/442 , C08G77/448 , C08K3/016 , C08K5/49 , C08K5/523 , C08K2003/2241 , C08L51/085 , C08L69/00 , C08L79/08 , C08L83/04 , C08L83/10 , C08L2201/02
摘要： A composition comprises a first polycarbonate having a limited oxygen index of greater than 26%, wherein an article molded from the first polycarbonate has a smoke density after 4 minutes (DS-4) of greater than 600; and a second polymer different from the first polycarbonate, the second polymer comprising a poly(carbonate-siloxane) copolymer, a silicone graft copolymer, a polydialkylsiloxane, or a combination comprising at least one of the foregoing; wherein an article molded from the second polymer has a DS-4 value of greater than 600; wherein an article molded from the composition has a DS-4 value of smaller than 480.
摘要翻译：组合物包含具有大于26％有限氧指数的第一聚碳酸酯，其中由第一聚碳酸酯模制的制品在4分钟后具有烟密度（DS-4）大于600; 和与第一聚碳酸酯不同的第二聚合物，所述第二聚合物包含聚（碳酸酯 - 硅氧烷）共聚物，硅氧烷接枝共聚物，聚二烷基硅氧烷或包含前述的至少一种的组合; 其中由所述第二聚合物模制的制品的DS-4值大于600; 其中由所述组合物模制的制品的DS-4值小于480。

9. 发明申请

WO1987007286A1 EPOXIDE-FUNCTIONALIZED POLYPHENYLENE ETHERS AND METHOD OF PREPARATION 审中-公开
标题翻译：环氧化物官能化聚苯乙烯及其制备方法
公开(公告)号：WO1987007286A1
公开(公告)日：1987-12-03
申请号：PCT/US1987001125
申请日：1987-05-20
申请人： GENERAL ELECTRIC COMPANY
发明人： GENERAL ELECTRIC COMPANY , SYBERT, Paul, Dean
IPC分类号： C08L71/04
CPC分类号： C08L71/126 , C08G18/4018 , C08G59/02 , C08G63/66 , C08G65/485 , C08G81/00 , C08L63/00 , C08L67/00 , C08L71/12 , C08L77/00 , C08L2666/02 , C08L2666/14 , C08L71/00
摘要： Epoxide-functionalized polyphenylene ethers, which may be prepared by the reaction of various acid-functionalized polyphenylene ethers with functionalized epoxides, are useful in the preparation of polyphenylene ether copolymers. These copolymers are, in turn, useful for the compatibilization of blends of polyphenylene ethers with such other polymers as polyesters and polyamides.

10. 发明申请

WO2003082949A1 METHOD FOR COPOLYESTERCARBONATE SYNTHESIS 审中-公开
标题翻译：苯乙烯碳酸酯合成方法
公开(公告)号：WO2003082949A1
公开(公告)日：2003-10-09
申请号：PCT/US2003/007203
申请日：2003-03-11
申请人： GENERAL ELECTRIC COMPANY
发明人： SILVA, James, Manio , DARDARIS, David, Michel , O'NEIL, Gregory, Allen , SYBERT, Paul, Dean , SU, Zhaohui
IPC分类号： C08G63/64
CPC分类号： C08G63/64
摘要： Thermally stable block copolyestercarbonates comprising chain members derived from at least one dihydroxy-substituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety, said polymer being substantially free of anhydride linkages linking at least two mers of the polyester chain segments, are prepared by a method comprising the steps of: (a) preparing a hydroxy-terminated polyester intermediate comprising structural units derived from at least one dihydroxysubstituted aromatic hydrocarbon moiety and at least one aromatic dicarboxylic acid moiety; and (b) conducting a reaction of the polyester intermediate with phosgene in a reaction mixture comprising water, a substantially water-immiscible organic solvent, and a base, wherein base and phosgene are added simultaneously to the reaction mixture at a substantially constant molar ratio of base to phosgene for a time period of at least about 60 % of the total amount of phosgene added.
摘要翻译：包含衍生自至少一个二羟基取代的芳族烃部分和至少一个芳族二羧酸部分的链成员的热稳定的嵌段共聚酯碳酸酯，所述聚合物基本上不含连接至少两个聚酯链段的酸酐键，通过方法包括以下步骤：（a）制备包含衍生自至少一个二羟基取代的芳族烃部分和至少一个芳族二羧酸部分的结构单元的羟基封端的聚酯中间体; 和（b）将聚酯中间体与光气反应在包含水，基本上与水不混溶的有机溶剂和碱的反应混合物中，其中碱和光气以基本恒定的摩尔比同时加入到反应混合物中基于光气持续至少约60％的光气加入的光气。

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